Asymmetric polymerization of 1-(3-pyridyl)dibenzosuberyl methacrylate and chiral recognition by the obtained optically active polymer having single-handed helical conformation

Polymer Journal

Volumn 30, Issue 8, 1998, Pages 635-640

  Nakano, Tamaki ^a   Satoh, Yoichi ^a   Okamoto, Yoshio ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

1 (3 Pyridyl)dibenzosuberyl Methacrylate; 1 Phenyldibenzosuberyl Methacrylale; Anionic Polymerization; Chiral Recognition; Free Radical Polymerization; Helix; Triphenyhnelhyl Methacrylate

Indexed keywords

ANIONIC POLYMERIZATION; CONFORMATIONS; FREE RADICAL POLYMERIZATION; OPTICAL PROPERTIES; SYNTHESIS (CHEMICAL); TOLUENE;

ASYMMETRIC POLYMERIZATION; CHIRAL RECOGNITION; PHENYLDIBENZOSUBERYL METHACRYLATE; PYRIDYLDIBENZOSUBERYL METHACRYLATE; TRIPHENYLMETHYL METHACRYLATE;

AROMATIC POLYMERS;

EID: 0031631631     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.30.635     Document Type: Article

References (18)

1. Y. Okamoto, K. Suzuki, K. Obta, K. Hatada, and H. Yuki, J-Am. Chem. Soc., 101, 4763 (1979).
2. T. Nakano, Y. Okamoto, and K. Hatada, J. Am. Chem. Soc., 114, 1318 (1992).
3. Y. Okamoto, H. Mohri, and K. Hatada, Chem. Lett., 1988, 1879.
4. Y. Okamoto, H. Mohri, T. Nakano, and K. Hatada, Chirality, 3, 277 (1991).
5. (a) Y. Okamoto and T. Nakano, Chem. Rev., 94, 349 (1994).
6. (b) T. Nakano and Y. Okamoto, in "Catalysis in Precision Polymerization," S. Kobayashi, Ed., Wiley, New York, N.Y., 1997, pp 293-309.
7. (a) Y. Okamoto, CHEMTECH, 1987, 144.
8. (b) Y. Okamoto and K. Hatada, J. Liq. Chromatogr., 9, 369 (1986).
9. T. Nakano, M. Mori, and Y. Okamoto, Macromolecules, 26, 867 (1993).
10. T. Nakano, A. Matsuda, M. Mori, and Y. Okamoto, Polym. J., 28, 330 (1996).
11. T. Nakano, Y. Shikisai, and Y. Okamoto, Polym J. 28, 51 (1996).
12. T. Nakano, A. Matsuda, and Y. Okamoto, Polym. J., 28, 556 (1996).
13. T. Nakano, K. Taniguchi, and Y. Okamoto, Polym. J., 29, 540 (1997).
14. Y. Okamoto, H. Mohri, and K. Hatada, Polym. J., 21, 439 (1989).
15. T. Nakano, A. Matsuda, and Y. Okamoto, manuscript in preparation.
16. Y. Okamoto, H. Mohri, T. Nakano, and K. Hatada, J. Am. Chem. Soc., 111, 5952 (1989).
17. Sample concentration was originally determined based on the sample volume at room temp 25°C but the concentration at 60°C has been corrected using a calculated volume increment of chloroform (4.8 %) with respect to the volume at 25°C. For the method of calculation, see: "Landoll Bömstein Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik," 6 Aufl., II Band, 1 Teil, Springer Verlag, 1971, S. 378-718.
18. Y. Okamoto, T. Nakano, Y. Shikisai, and M. Mori, Makromol. Chem. Symp., 89, 479 (1995).