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Volumn 312, Issue , 1998, Pages 263-283

The reactions of sulfilimines with TCNQ and their characteristic charger-transfer complexes as products

Author keywords

Charge transfer complex; Sulfilimine; TCNQ

Indexed keywords

BOND STRENGTH (CHEMICAL); CHARGE TRANSFER; CHEMICAL BONDS; ELECTRIC CONDUCTIVITY MEASUREMENT; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; THERMOANALYSIS;

EID: 0031619103     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259808042446     Document Type: Article
Times cited : (2)

References (55)
  • 31
    • 33645014486 scopus 로고    scopus 로고
    • note
    • When the reaction of sulfilimine with TCNQ was performed at room temparature, the stable charge-transfer complex was obtained. However, when this reaction was conducted at higher temperature, the reaction proceeded moreover and the different products were obtained. For example, when the acetonitrile solution containing the sulfilimine and TCNQ was refiuxed for 6 h under air, the reaction products except the charge-transfer complex were obtained. However, since the products were unstable under air, their structures were not assigned.
  • 40
    • 33644993109 scopus 로고    scopus 로고
    • note
    • The degree of electron transfer (ρ = 0.53) in complex 7 was determined from the result of Raman spectra of complex 7 and LiTCNQ. Therefore, it is considered from the result of complex 7 that the electron transfer in complex 2 is incomplete and TCNQ molecules are partially reduced.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.