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Volumn 119, Issue 50, 1997, Pages 12240-12250

Assignment of electronic transition moment directions of adenine from linear dichroism measurements

Author keywords

[No Author keywords available]

Indexed keywords

ADENINE DERIVATIVE;

EID: 0031576659     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9710262     Document Type: Article
Times cited : (85)

References (64)
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    • Adenine: (a) Clark, L. B J. Phys. Chem. 1989, 93, 5345. (b) Clark, L. B J. Phys. Chem 1990, 94, 2873. (c) Clark, L. B J. Phys. Chem. 1995, 99, 4466.
    • (1989) J. Phys. Chem. , vol.93 , pp. 5345
    • Clark, L.B.1
  • 6
    • 0000587814 scopus 로고
    • Adenine: (a) Clark, L. B J. Phys. Chem. 1989, 93, 5345. (b) Clark, L. B J. Phys. Chem 1990, 94, 2873. (c) Clark, L. B J. Phys. Chem. 1995, 99, 4466.
    • (1990) J. Phys. Chem , vol.94 , pp. 2873
    • Clark, L.B.1
  • 7
    • 0011142516 scopus 로고
    • Adenine: (a) Clark, L. B J. Phys. Chem. 1989, 93, 5345. (b) Clark, L. B J. Phys. Chem 1990, 94, 2873. (c) Clark, L. B J. Phys. Chem. 1995, 99, 4466.
    • (1995) J. Phys. Chem. , vol.99 , pp. 4466
    • Clark, L.B.1
  • 32
    • 25044451014 scopus 로고
    • Ph.D. Thesis, University of Gothenburg
    • Löfroth, J. E. Ph.D. Thesis, University of Gothenburg, 1982.
    • (1982)
    • Löfroth, J.E.1
  • 43
    • 0014427741 scopus 로고
    • Numerous examples are found in the literature where two isolated overlapping electronic transitions give rise to a bisignate MCD spectrum. See for example: Voelter, W.; Records, R.; Bunnenberg, E.; Djerassi, C. J. Am. Chem. Soc. 1968, 90, 6163. Nordén, B.; Håkansson, R.; Pedersen, P. B.; Thulstrup, E. W. Chem. Phys. 1978, 33, 355. Albinsson, B.; Eriksson, S.; Lyng, R.; Kubista, M. Chem. Phys. 1991, 151, 149.
    • (1968) J. Am. Chem. Soc. , vol.90 , pp. 6163
    • Voelter, W.1    Records, R.2    Bunnenberg, E.3    Djerassi, C.4
  • 44
    • 0001192852 scopus 로고
    • Numerous examples are found in the literature where two isolated overlapping electronic transitions give rise to a bisignate MCD spectrum. See for example: Voelter, W.; Records, R.; Bunnenberg, E.; Djerassi, C. J. Am. Chem. Soc. 1968, 90, 6163. Nordén, B.; Håkansson, R.; Pedersen, P. B.; Thulstrup, E. W. Chem. Phys. 1978, 33, 355. Albinsson, B.; Eriksson, S.; Lyng, R.; Kubista, M. Chem. Phys. 1991, 151, 149.
    • (1978) Chem. Phys. , vol.33 , pp. 355
    • Nordén, B.1    Håkansson, R.2    Pedersen, P.B.3    Thulstrup, E.W.4
  • 45
    • 0039540468 scopus 로고
    • Numerous examples are found in the literature where two isolated overlapping electronic transitions give rise to a bisignate MCD spectrum. See for example: Voelter, W.; Records, R.; Bunnenberg, E.; Djerassi, C. J. Am. Chem. Soc. 1968, 90, 6163. Nordén, B.; Håkansson, R.; Pedersen, P. B.; Thulstrup, E. W. Chem. Phys. 1978, 33, 355. Albinsson, B.; Eriksson, S.; Lyng, R.; Kubista, M. Chem. Phys. 1991, 151, 149.
    • (1991) Chem. Phys. , vol.151 , pp. 149
    • Albinsson, B.1    Eriksson, S.2    Lyng, R.3    Kubista, M.4
  • 47
    • 0001688829 scopus 로고
    • Albinsson, B.; Kubista, M.; Nordén, B.; Thulstrup, E. W. J. Phys. Chem. 1989, 93, 6646. Albinsson, B.; Nordén, B. J. Phys. Chem. 1992, 96, 6204.
    • (1992) J. Phys. Chem. , vol.96 , pp. 6204
    • Albinsson, B.1    Nordén, B.2
  • 55
    • 2642638577 scopus 로고    scopus 로고
    • note
    • 11 No attempt was made to optimize the fit between simulation and experiments since the individual orientation parameters of 7-H-adenine and 9-H-adenine probably deviate from those determined for the mixture of the 7-H and 9-H tautomers.
  • 59
    • 0000177002 scopus 로고
    • Morrison, H, Ed.; Wiley: New York, Chapter 1
    • Cadet, J.; Vigny, P. In Bioorganic Photochemistry; Morrison, H, Ed.; Wiley: New York, 1990, Vol. 1, Chapter 1.
    • (1990) Bioorganic Photochemistry , vol.1
    • Cadet, J.1    Vigny, P.2
  • 60
    • 2642670152 scopus 로고    scopus 로고
    • note
    • ) For both transitions I and II, the dominating excited configurations are common to the methods (7-H-adenine: I (HOMO → LUMO) and II (HOMO → LUMO + 1); and 9-H-adenine I (HOMO → LUMO + 1) and II (HOMO → LUMO)). However, other configurations also contribute significantly.


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