Ester functionalised alkene-extended cyclohexadienyliron complexes

Tetrahedron

Volumn 53, Issue 11, 1997, Pages 4095-4104

  Hudson, Richard D A ^a   Osborne, Simon A ^b   Stephenson, G Richard ^a  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^b NEUROSCIENCE RESEARCH CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX;

ARTICLE; CONJUGATION; CRYSTALLOGRAPHY; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

EID: 0031575865     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)00020-3     Document Type: Article

References (24)

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15. 2 used for the experiment.
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18. 2CuLi (Ref. 23). An unstable product was isolated in 61% yield. The n.m.r. spectrum of this complex indicated the introduction of an NHBn group in place of the methyl group in 14a. Although this formulation is supported by the presence of a correct molecular ion in the FAB mass spectrum of the product, this ion was too weak for high resolution measurement, and the complex was too unstable for characterisation by microanalysis. The generalisation of the use of 13 as a general precursor for β, γ, and δ amino acids awaits further work with a range of nitrogen-containing nucleophiles.
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