Preparation and reactivity of functionalized aryl and alkenylmanganese halides

Tetrahedron Letters

Volumn 38, Issue 11, 1997, Pages 1927-1930

  Klement, Ingo ^a,b   Stadtmüller, Heinz ^a   Knochel, Paul ^b   Cahiez, Gérard ^a  

^a l'Electronique et de ses   (France)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FUNCTIONAL GROUP; MANGANESE DERIVATIVE;

ACYLATION; ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS; TEMPERATURE;

EID: 0031575785     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00248-7     Document Type: Article

References (16)

1. 1. Organomanganese Reagents Part XXXIII. For part XXXII see ref. 3b.
2. 2. For reviews, see: a/ Cahiez, G. Butyl Manganese Chloride and Related Reagents in "Encyclopedia of Reagents for Organic Synthesis", L. Paquette Ed., Wiley, Chichester 1995, 925-928.
3. b/ Cahiez, G. Manganese (II) Chloride in "Encyclopedia of Reagents for Organic Synthesis", L. Paquette Ed., Wiley, Chichester 1995, 3227-3228.
4. c/ Cahiez, G. Anales de Química 1995, 91, 561-578.
5. 3. a/ Cahiez, G. and Marquais, S. Synlett 1993, 45-47.
6. b/ Cahiez, G. and Marquais, S. Pure & Appl. Chem. 1996, 65, 53-60.
7. c/ Cahiez, G. and Marquais, S. Tetrahedron Lett. 1996, 37, 1773-1776.
8. 4. For instance, see: Knochel, P. Synlett 1995, 393-403 and references cited therein.
9. 5. a/ Parham, W. E.; Bradsher, C. K. Acc. Chem. Res. 1982, 15, 300-305.
10. b/ Cahiez, G.; Bernard, D. and Normant, J. Synthesis 1976, 245-248.
11. c/Tuker, C.E.; Majid, T.N.; Knochel, P. J. Am. Chem. Soc. 1992, 114, 3983-3985.
12. 6. MnI2 is slighly soluble in ether at 20°C. When the Li-Mn transmetallation reaction is performed under classical conditions (-10°C to 0°C) the presence of LiX facilitates the solubilisation of MnI2 in the reaction mixture.
13. 7. Cahiez, G.; Chavant, P.-Y. and Metais, E. Tetrahedron Lett. 1992, 33, 5245-5248 and note 12 therein.
14. 8. Köbrich, G. Angew. Chem. Int. Ed. Engl. 1967, 6, 41-52.
15. 9. Cahiez, G. and Laboue, B. Tetrahedron Lett. 1989, 30, 7369-7372.
16. 10. Cahiez, G. and Alami, M. Tetrahedron Lett. 1990, 31, 7423-7424.