A conformational toolbox of oxazoline ligands

Tetrahedron Letters

Volumn 38, Issue 7, 1997, Pages 1145-1148

  Davies, Ian W ^a   Gerena, Linda ^a   Cai, Dongwei ^a   Larsen, Robert D ^a   Verhoeven, Thomas R ^a   Reider, Paul J ^a  

^a MERCK RESEARCH LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPROPANE DERIVATIVE; OXAZOLIDINONE DERIVATIVE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; IN VITRO STUDY; METHODOLOGY; MOLECULAR MODEL; REACTION ANALYSIS; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 0031575566     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00010-5     Document Type: Article

References (25)

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8. 8. The ligand is a bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole.
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12. 11. Nishiyama, H.; Kondo, M.; Nakamura, T.; Itoh, K. Organometallics 1991, 10, 500. Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, S-B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. Nishiyama, H.; Itoh, Y.; Sugawara, Y; Matsumoto, H.; Aoki, K; Itoh, K. Bull. Chem. Soc., Jpn. 1995, 68, 1247.
13. 11. Nishiyama, H.; Kondo, M.; Nakamura, T.; Itoh, K. Organometallics 1991, 10, 500. Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, S-B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. Nishiyama, H.; Itoh, Y.; Sugawara, Y; Matsumoto, H.; Aoki, K; Itoh, K. Bull. Chem. Soc., Jpn. 1995, 68, 1247.
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16. 14. For a very recent example of ligand effects in cyclopropanation and aziridination that may be clarified using this toolbox see: Harm, A. M.; Knight, J. G.; Stemp, G. Tetrahedron Lett. 1996, 37, 6189; Harm, A. M.; Knight, J. G.; Stemp, G. Synlett 1996, 677.
17. 14. For a very recent example of ligand effects in cyclopropanation and aziridination that may be clarified using this toolbox see: Harm, A. M.; Knight, J. G.; Stemp, G. Tetrahedron Lett. 1996, 37, 6189; Harm, A. M.; Knight, J. G.; Stemp, G. Synlett 1996, 677.
18. 4) the CO and ethylene are trans, the sterically demanding in-pybox may override this electronic preference.
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