Alkylrhenium oxides from perrhenates: A new, economical access to organometallic oxide catalysts

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 23, 1997, Pages 2652-2654

  Herrmann, Wolfgang A ^a   Kratzer, Roland M ^a   Fischer, Richard W ^b  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b SANOFI   (France)

Author keywords

Alkylations; Homogeneous catalysis; Oxidations; Rhenium; Synthetic methods

Indexed keywords

EID: 0031573958     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199726521     Document Type: Article

References (25)

1. Recent examples: a) L. L. Blosch, K. Abboud, J. M. Boncella, J. Am. Chem. Soc. 1991, 113, 7066-7068; b) J. H. Wengrovius, R. R. Schroek, Organo-melallics 1982, 1, 148-155; c) J. Kress, M. Wcsolek, J. P. Le Ny. J. A. Osborn,J. Chem. Soc. Chem. Commun. 1981, 1039-1040.
2. Recent examples: a) L. L. Blosch, K. Abboud, J. M. Boncella, J. Am. Chem. Soc. 1991, 113, 7066-7068; b) J. H. Wengrovius, R. R. Schroek, Organo-melallics 1982, 1, 148-155; c) J. Kress, M. Wcsolek, J. P. Le Ny. J. A. Osborn,J. Chem. Soc. Chem. Commun. 1981, 1039-1040.
3. Recent examples: a) L. L. Blosch, K. Abboud, J. M. Boncella, J. Am. Chem. Soc. 1991, 113, 7066-7068; b) J. H. Wengrovius, R. R. Schroek, Organo-melallics 1982, 1, 148-155; c) J. Kress, M. Wcsolek, J. P. Le Ny. J. A. Osborn,J. Chem. Soc. Chem. Commun. 1981, 1039-1040.
4. Reviews:a) W. A. Herrmann, F. E. Kühn, Acc. Chem. Res. 1997, 30, 169-180; b) W. A. Herrmann, J. Organomet. Chem. 1995, 500, 149-174.
5. Reviews:a) W. A. Herrmann, F. E. Kühn, Acc. Chem. Res. 1997, 30, 169-180; b) W. A. Herrmann, J. Organomet. Chem. 1995, 500, 149-174.
6. a) J. Rudolph, K. L. Reddy, J. P. Chiang, K. B. Sharpless, J. Am. Chem. Soc. 1997, 119, 6189-6190;
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10. e) R. W. Murray, K. lyanar, ibid. 1997, 38, 335-338.
11. The "base effect" [3 a, b] in MTO-catalyzed olefin epoxidations has already been known for some time and provides an enormous extension of this catalyst's variety of application: a) W. A. Herrmann, R. W. Fischer, D. W. Marz, Angew. Chem. 1991, 103, 1706-1709; Angew. Chem. Int. Ed. Engl. 1991, 30, 1638-1641; b) W. A. Hermann, R. W. Fischer, M. U Rauch, W. Schercr, J. Mol. Catal. 1994, 86, 243-266; c) W. A. Herrmann, J. D. G. Corrcia, M. U. Rauch, G. R. J. Artus, F. E. Kühn, ibid. 1997, 118, 33-45.
12. The "base effect" [3 a, b] in MTO-catalyzed olefin epoxidations has already been known for some time and provides an enormous extension of this catalyst's variety of application: a) W. A. Herrmann, R. W. Fischer, D. W. Marz, Angew. Chem. 1991, 103, 1706-1709; Angew. Chem. Int. Ed. Engl. 1991, 30, 1638-1641; b) W. A. Hermann, R. W. Fischer, M. U Rauch, W. Schercr, J. Mol. Catal. 1994, 86, 243-266; c) W. A. Herrmann, J. D. G. Corrcia, M. U. Rauch, G. R. J. Artus, F. E. Kühn, ibid. 1997, 118, 33-45.
13. The "base effect" [3 a, b] in MTO-catalyzed olefin epoxidations has already been known for some time and provides an enormous extension of this catalyst's variety of application: a) W. A. Herrmann, R. W. Fischer, D. W. Marz, Angew. Chem. 1991, 103, 1706-1709; Angew. Chem. Int. Ed. Engl. 1991, 30, 1638-1641; b) W. A. Hermann, R. W. Fischer, M. U Rauch, W. Schercr, J. Mol. Catal. 1994, 86, 243-266; c) W. A. Herrmann, J. D. G. Corrcia, M. U. Rauch, G. R. J. Artus, F. E. Kühn, ibid. 1997, 118, 33-45.
14. The "base effect" [3 a, b] in MTO-catalyzed olefin epoxidations has already been known for some time and provides an enormous extension of this catalyst's variety of application: a) W. A. Herrmann, R. W. Fischer, D. W. Marz, Angew. Chem. 1991, 103, 1706-1709; Angew. Chem. Int. Ed. Engl. 1991, 30, 1638-1641; b) W. A. Hermann, R. W. Fischer, M. U Rauch, W. Schercr, J. Mol. Catal. 1994, 86, 243-266; c) W. A. Herrmann, J. D. G. Corrcia, M. U. Rauch, G. R. J. Artus, F. E. Kühn, ibid. 1997, 118, 33-45.
15. I. A. Beattie, P. J. Jones, Inorg. Chem. 1979, 18, 2318-2319.
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20. W. A. Hermann, C. C. Romāo, R. W. Fischer, P. Kiprof, C. de Méric de Bellefon, Angew. Chem. 1991, 705, 183-185; Angew. Chem. Int. Ed. Engl. 1991, 50, 185-187.
21. [3-(Diethylamino)propyl]trioxorhenium cf. ref. [4b].
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23. Reactions with chlorotrimethylsilane have been described for some metal oxides and alkoxides (e.g., of Ti, Cr, Sm), cf. a) R. Nomura, T. Matsuno, T. Endo, J. Am. Chem. Soc. 1996, 118, 11666-11667; b) A. Fúrstner, A. Hupperts, ibid. 1995, 117, 4468-4475; c) A. Fürstner, N. Shi, ibid. 1996, 118, 2533-2534.
24. Reactions with chlorotrimethylsilane have been described for some metal oxides and alkoxides (e.g., of Ti, Cr, Sm), cf. a) R. Nomura, T. Matsuno, T. Endo, J. Am. Chem. Soc. 1996, 118, 11666-11667; b) A. Fúrstner, A. Hupperts, ibid. 1995, 117, 4468-4475; c) A. Fürstner, N. Shi, ibid. 1996, 118, 2533-2534.
25. Reactions with chlorotrimethylsilane have been described for some metal oxides and alkoxides (e.g., of Ti, Cr, Sm), cf. a) R. Nomura, T. Matsuno, T. Endo, J. Am. Chem. Soc. 1996, 118, 11666-11667; b) A. Fúrstner, A. Hupperts, ibid. 1995, 117, 4468-4475; c) A. Fürstner, N. Shi, ibid. 1996, 118, 2533-2534.