Reversible on/off switching of CH ⇀ Rh interactions in rhodathiaboranes with "anomalous" electron counts. Synthesis and molecular structure of [(Ph3P) 2N][1-dppe-1,2-closo-RhSB9H9]

Journal of Organometallic Chemistry

Volumn 527, Issue 1-2, 1997, Pages 283-285

  Adams, Kerry J ^a   McGrath, Thomas D ^a   Thomas, Rhodri Ll ^b   Weller, Andrew S ^b   Welch, Alan J ^a,b  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

^b HERIOT WATT UNIVERSITY   (United Kingdom)

Author keywords

CH ; Reversible switching; Rh interactions; Synthesis

Indexed keywords

EID: 0031564469     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(96)06419-4     Document Type: Article

References (12)

1. [1] For example, C.S. Jun, T.P. Fehlner and A.L. Rheingold, J. Am. Chem. Soc., 115 (1993) 4393.
2. [2] K. Wade, Adv. Inorg. Chem. Radiochem., 18 (1976) 1.
3. [3] G. Ferguson, M.C. Jennings, A.J. Lough, S. Coughlan, T.R. Spalding, J.D. Kennedy, X.L.R. Fontaine and B. Stibr, J. Chem. Soc., Chem. Commun., (1990) 891.
4. [4] M. Murphy, T.R. Spalding, G. Ferguson and J.F. Gallagher, Acta Crystallogr., C48 (1992) 638.
5. [5] K.J. Adams, T.D. McGrath and A.J. Welch, Acta Crystallogr., C51 (1995) 401.
6. [6] For method see S.A. Macgregor, A.J. Wynd, N. Moulden, R.O. Gould, P. Taylor, L.J. Yellowlees and A.J. Welch, J. Chem. Soc., Dalton Trans., (1991) 3317.
7. [7] S.J. LaPlaca and J.A. Ibers, Inorg. Chem., 1965, 4, 778; A.C. Skapski and P.G.H Troughton, J. Chem. Soc., Chem. Commun., (1968) 1230; R.-M. Catalá, D. Cruz-Garritz, P. Sosa, P. Terreros, H. Torrens, A. Hills, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 359 (1989) 219; S.D. Chappell, L.M. Engelhardt, A.H. White and C.L. Raston, J. Organomet. Chem., 462 (1993) 295; S.D. Perera and B.L. Shaw, J. Chem. Soc., Dalton Trans., (1995) 3861.
8. [7] S.J. LaPlaca and J.A. Ibers, Inorg. Chem., 1965, 4, 778; A.C. Skapski and P.G.H Troughton, J. Chem. Soc., Chem. Commun., (1968) 1230; R.-M. Catalá, D. Cruz-Garritz, P. Sosa, P. Terreros, H. Torrens, A. Hills, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 359 (1989) 219; S.D. Chappell, L.M. Engelhardt, A.H. White and C.L. Raston, J. Organomet. Chem., 462 (1993) 295; S.D. Perera and B.L. Shaw, J. Chem. Soc., Dalton Trans., (1995) 3861.
9. [7] S.J. LaPlaca and J.A. Ibers, Inorg. Chem., 1965, 4, 778; A.C. Skapski and P.G.H Troughton, J. Chem. Soc., Chem. Commun., (1968) 1230; R.-M. Catalá, D. Cruz-Garritz, P. Sosa, P. Terreros, H. Torrens, A. Hills, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 359 (1989) 219; S.D. Chappell, L.M. Engelhardt, A.H. White and C.L. Raston, J. Organomet. Chem., 462 (1993) 295; S.D. Perera and B.L. Shaw, J. Chem. Soc., Dalton Trans., (1995) 3861.
10. [7] S.J. LaPlaca and J.A. Ibers, Inorg. Chem., 1965, 4, 778; A.C. Skapski and P.G.H Troughton, J. Chem. Soc., Chem. Commun., (1968) 1230; R.-M. Catalá, D. Cruz-Garritz, P. Sosa, P. Terreros, H. Torrens, A. Hills, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 359 (1989) 219; S.D. Chappell, L.M. Engelhardt, A.H. White and C.L. Raston, J. Organomet. Chem., 462 (1993) 295; S.D. Perera and B.L. Shaw, J. Chem. Soc., Dalton Trans., (1995) 3861.
11. [7] S.J. LaPlaca and J.A. Ibers, Inorg. Chem., 1965, 4, 778; A.C. Skapski and P.G.H Troughton, J. Chem. Soc., Chem. Commun., (1968) 1230; R.-M. Catalá, D. Cruz-Garritz, P. Sosa, P. Terreros, H. Torrens, A. Hills, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 359 (1989) 219; S.D. Chappell, L.M. Engelhardt, A.H. White and C.L. Raston, J. Organomet. Chem., 462 (1993) 295; S.D. Perera and B.L. Shaw, J. Chem. Soc., Dalton Trans., (1995) 3861.
12. [8] See for example. Table 1 of S. Coughlan, T.R. Spalding, G. Ferguson, J.F. Gallagher, A.J. Lough, X.L.R. Fontaine, J.D. Kennedy and B. Stibr, J. Chem. Soc., Dalton Trans., (1992) 2865 for a recent compilation.