Arylalkylcarbenes from triplet arylalkyldiazoalkanes

Tetrahedron Letters

Volumn 38, Issue 6, 1997, Pages 949-952

  Motschiedler, Krista R ^a   Toscano, John P ^b   Garcia Garibay, Miguel A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b JOHNS HOPKINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHER DERIVATIVE; STILBENE DERIVATIVE;

ARTICLE; DRUG STABILITY; DRUG SYNTHESIS; ELECTRON SPIN RESONANCE; GAS LIQUID CHROMATOGRAPHY; IN VITRO STUDY; MOLECULAR DYNAMICS; PHOTOCHEMISTRY; REACTION ANALYSIS; STEREOCHEMISTRY; ULTRAVIOLET SPECTROPHOTOMETRY;

EID: 0031562045     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(96)02487-2     Document Type: Article

References (21)

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21. (18) Let x be the fraction of products formed via Path 1 and 1-x the fraction of products via Path 2. The yields of 1,2-H shifts and MeO-H insertion from the "true carbene" (sensitized experiments) labeled "a" and "b", respectively, can be used to describes the ratio (y) of 1,2-H and insertion products obtained upon direct irradiation: y = 1,2-H / Insertion = [x + (1-x) a] / [(1-x) b].