Lattice imaging of self-assembled monolayers of partially fluorinated disulfides and thiols on sputtered gold by atomic force microscopy

Langmuir

Volumn 13, Issue 14, 1997, Pages 3769-3774

  Schonherr H ^a   Vancso, G J ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC FORCE MICROSCOPY; CRYSTAL SYMMETRY; ETHANOL; GOLD; HYDROGEN BONDS; LATTICE CONSTANTS; MONOLAYERS; POLYCRYSTALLINE MATERIALS; SUBSTRATES;

FLUORINATED DISULFIDES; PERFLUOROALKYLAMIDE THIOLS; SELF ASSEMBLED MONOLAYERS;

SULFUR COMPOUNDS;

EID: 0031561054     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la960561x     Document Type: Article

References (68)

1. (a) Ulman, A. Introduction to Ultrathin Films, From Langmuir-Blodgett Films to Self-Assembly; Academic Press: Boston, 1991.
2. (b) Maoz, R.; Sagiv, J. J. Colloid Interface Sci. 1984, 1OO, 465.
3. (c) Dubois, L. H.; Nuzzo, R. G. Annu. Rev. Phys. Chem. 1992, 43, 437.
4. The first SAMs of disulfides on gold were reported by: Nuzzo, R. G.; Allara, D. L. J. Am. Chem. Soc. 1983, 105, 4481.
5. Recently, functional groups such as amide groups have been incorporated in the alkane chain; see: Tam-Chang, S.-W.; Biebuyck, H. A.; Whitesides, G. M.; Jeon, N.; Nuzzo, R. G. Langmuir 1995,11, 471.
6. (a) Turyan, I.; Mandler, D. Anal. Chem. 1994, 66, 58.
7. (b) Thoden van Velzen, E. U.; Engbersen, J. F. J.; Reinhoudt, D. N. J. Am. Chem. Soc. 1994, 116, 3597.
8. (c) Rojas, M. T.; Kaifer, A. E. J. Am. Chem. Soc. 1995, 117, 5883.
9. (d) Zhang, L.; Godinez, L. A.; Tianbao, L.; Gokel, G. W.; Kaifer, A. E. Angew. Chem. 1995, 107, 236.
10. Wilbur, J. L.; Biebuyck, H. A.; MacDonald, J. C.; Whitesides, G M. Langmuir 1995, 11, 825 and references therein.
11. (a) Frisbie, D.; Rozsnyai, L. F.; Noy, A.; Wrighton, M. S.; Lieber, C. M. Science 1994, 265, 2071.
12. (b) Noy, A.; Frisbie, D.; Rozsnyai, L. F.; Wrighton, M. S.; Lieber, C. M. J. Am. Chem. Soc. 1995, 117, 7943.
13. (a) Florin, E.-L.; Moy, V. T.; Gaub, H. E. Science 1994, 264, 415.
14. (b) Moy, V. T.; Florin, E.-L.; Gaub, H. E. Science 1994, 266, 257.
15. (c) Lee, G. W.; Kidwell, D. A.; Colton, R. J. Langmuir 1994, 10, 354.
16. Any commensurability of the adsorbate lattice with the underlying gold lattice implies an epitaxial relation.
17. Uosaki, K.; Shen, Y.; Kondo, T. J. Phys. Chem. 1995, 99, 14117. See also refs 11 and 12.
18. Camillone, N., III; Chidsey, C. E. D.; Liu, G.-Y.; Scoles, G. J. Chem. Phys. 1993, 98, 4234.
19. (a) Alves, C. A.; Smith, E. L.; Porter, M. D. J. Am. Chem. Soc. 1992, 114, 1222.
20. (b) Pan, J.; Tao, N.; Lindsay, S. M. Langmuir 1993, 9, 1556.
21. (a) Widrig, C. A.; Alves, C. A.; Porter, M. D. J. Am. Chem. Soc. 1991, 113, 2805.
22. (b) Kim, Y.-T.; McCarley, R. L.; Bard, A. J. J. Phys. Chem. 1992, 96, 7416.
23. (c) Delamarche, E.; Michel, B.; Kang, H.; Gerber, Ch. Langmuir 1994, 10, 4103.
24. Chidsey, C. E. D.; Loiacono, D. N. Langmuir 1990, 6, 682.
25. (a) Camillone, N., III; Chidsey, C. E. D.; Liu, G.-y.; Putvinski, T. M.; Scoles, G. J. Chem. Phys. 1991, 94, 8493.
26. (b) Camillone, N., III; Chidsey, C. E. D.; Liu, G.-y.; Scoles, G. J. Chem. Phys. 1993, 98, 3503.
27. (a) Poirier, G. E.; Tarlov, M. J. Langmuir 1994, 10, 2853.
28. (b) Delamarche, E.; Michel, B.; Gerber, Ch.; Anselmetti, D.; Güntherodt, H.-J.; Wolf, H.; Ringsdorf, H. Langmuir 1994, 10, 2869.
29. (a) Edinger, K.; Gölzhäuser, A.; Demota, K.; Wöll, Ch.; Grunze, M. Langmuir 1993, 9, 4.
30. (b) Sun, L.; Crooks, R. M. Langmuir 1993, 9, 1951.
31. (c) Schönenberger, C.; Sondag-Huethorst, J. A. M.; Jorritsma, J.; Fokkink, L. G. Langmuir 1994, 10, 611.
32. (d) McCarley, R. L.; Dunaway, O. J.; Willicut, R. J. Langmuir 1993, 9, 2775.
33. Liu, G.-Y.; Salmeron, M. Langmuir 1994, 10, 367.
34. Jaschke, M.; Schönherr, H.; Wolf, H.; Butt, H.-J.; Bamberg, E.; Besocke, M. K.; Ringsdorf, H. J. Phys. Chem. 1996, 100, 2290.
35. Alves, C. A.; Porter, M. D. Langmuir 1993, 9, 3507.
36. Liu, G.-Y.; Fenter, P.; Chidsey, C. E. D.; Ogletree, D. F.; Eisenberger, P.; Salmeron, M, J. Chem. Phys. 1994, 101, 4301.
37. Wolf, H.; Ringsdorf, H.; Delamarche, E.; Takami, T.; Rang, H.; Michel, B.; Gerber, Ch.; Jaschke, M.; Butt, H. J.; Bamberg, E. J. Phys. Chem. 1995, 99, 7102.
38. Schönherr, H.; Kremer, F. J. B.; Kumar, S.; Rego, J. A.; Wolf, H.; Ringsdorf, H.; Jaschke, M.; Butt, H.-J.; Bamberg, E. J. Am. Chem. Soc. 1996, 118, 13051.
39. (a) Evans, S. D.; Ulman, A.; Goppert-Berarducci, K. E.; Gerenser, L. J. J. Am. Chem. Soc. 1991, 113, 5866.
40. (b) Freeman, T. L.; Evans, S. D.; Ulman, A. Langmuir 1995, 11, 4411.
41. (c) Evans, S. D.; Flynn, T. M.; Ulman, A. Langmuir 1995, 11, 3811.
42. (a) Batchelder, D. N.; Evans, S. D.; Freeman, T. L.; Häussling, L.; Ringsdorf, H.; Wolf, H. J. Am. Chem. Soc. 1994, 116, 1050.
43. (b) Chan, K.; Kim, T.; Schoer, J. K.; Crooks, R. M. J. Am. Chem. Soc. 1995, 117, 5875.
44. Bader, H.; Dorn, K.; Hupfer, B.; Ringsdorf, H. Adv. Polym. Sci. 1985, 64, 1.
45. Bloor, D.; Chance, P. R. Polydiacetylenes; Martinas Nijhoff: Dordrecht, 1985; p 1.
46. Butt, H.-J.; Seifert, K.; Bamberg, E. J. Phys. Chem. 1993, 97, 7316.
47. Au(111) can be imaged with atomic resolution in air and under liquid; see; Manne, S.; Butt, H.-J.;Gould, C. A. C.; Hansma, P. K.Appl. Phys. Lett. 1990, 56, 1758.
48. Lenk, T. J.; Hallmark, V. M.; Hoffman, C. L.; Rabolt, J. F.; Castner, D. G.; Erdelen, C.; Ringsdorf, H. Langmuir 1994, 10, 4610.
49. Schönherr, H.; Ringsdorf, H. Langmuir 1996, 12, 3891.
50. Nelles, G,; Schönherr, H.; Jaschke, M.; Wolf, H.; Schaub, M.; Bamberg, E.; Ringsdorf, H.; Butt, H.-J. Submitted for publication.
51. Röthlisberger, U.; Klein, M. L.; Sprik, M. J. Mater. Chem. 1994, 4, 793.
52. Bain, C. D.; Troughton, E. B.; Tao, Y.-T.; Evall, J.; Whitesides, G. M.; Nuzzo, R. G. J. Am. Chem. Soc. 1989, 111, 321.
53. (a) Weisenhorn, A. L.; Hansma, P. K.; Albrecht, T. R.; Quate, C. F. Appl. Phys. Lett. 1989, 54, 2651.
54. (b) Weisenhorn, A. L.; Maivald, P.; Butt, H.-J.; Hansma, P. K. Phys. Rev. B 1992, 45, 11226.
55. Snétivy, D.; Vancso, G. J. Langmuir 1993, 9, 2253.
56. An AFM image of the granular structure of the sputtered gold surface, as well as an AFM image showing the Au( 111) lattice is included in the Supporting Information.
57. 28
58. Tsao, M. W.; Rabolt, J. F.; Ringsdorf, H.; Schönherr, H. Unpublished results.
59. Elbert, R.; Folda, T.; Ringsdorf, H. J. Am. Chem. Soc. 1984, 106, 7687.
60. Overney, R. M.; Meyer, E,; Frommer, J.; Brodbeck, D.; Lüthi, R.; Howald, L.; Güntherodt, H.-J.; Fujihira, M.; Takano, H.; Gotoh, Y. Nature 1992, 359, 133.
61. Schönherr, H.; Ringsdorf, H.; Jaschke, M.;Butt, H.-J.;Bamberg, E.; Allinson, H.; Evans, S. D. Langmuir 1996, 12, 3898.
62. SAMs of mixed methylhydroxyl-terminated disulfides were shown by STM to assemble without phase separation; see: Takami, T.; Delamarche, E.; Michel, B.; Gerber, Ch.; Wolf, H.; Ringsdorf, H. Langmuir 1995, 11, 3876.
63. We would expect α= 56°,β= 56°, and γ= 69° based on geometric considerations; we measured α= 54 ± 2°, β= 54 ± 2°, and γ = 71 ± 3°.
64. Polymer Handbook, 3rd ed.; Brandrup, J., Immergut, E. H., Eds.; Wiley: New York, 1989; p V/37.
65. Bernett, M. K.; Zisman, W. A. J. Phys. Chem. 1963, 67, 1534.
66. Nelles, G.; Schönherr, H.; Vancso, G. J.; Butt, H.-J. Submitted for publication.
67. Schönherr, H.; Vancso, G. J.; Huisman, B.-H.; van Veggel, F. C. J. M.; Reinhoudt, D. N. Langmuir 1997, 13, 1567.
68. The rotation of the scanning direction resulted in a rotation of the observed lattice, which excludes drift or slippage as the origin of the observed distortion.