Energetically driven asymmetries in random copolymer miscibilities and their pressure dependence

Macromolecules

Volumn 30, Issue 18, 1997, Pages 5506-5519

  Dudowicz, Jacek ^a   Freed, Karl F ^a  

^a UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINARY MIXTURES; ENTROPY; FREE ENERGY; PHASE DIAGRAMS; POLYMER BLENDS; PRESSURE EFFECTS; SOLUBILITY;

FLORY HUGGINS THEORY; LATTICE CLUSTER THEORY;

COPOLYMERS;

EID: 0031559872     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9702105     Document Type: Article

References (46)

1. Kambour, R. P.; Bendler, J. T.; Bopp, R. C. Macromolecules 1983, 16, 753.
2. Roe, R. J.; Rigby, D. Adv. Pol. Sci. 1987, 82, 103.
3. Huh, W.; Karasz, F. E. Macromolecules 1992, 25, 1057.
4. ten Brinke, G.; Karasz, F. E.; MacKnight, W. J. Macromolecules 1983, 16, 1827.
5. Roe, R. J.; Zim, W. C. Macromolecules 1980, 13, 1221; Paul, D. R., Barlow, J. W. Polymer 1984, 25, 487.
6. Roe, R. J.; Zim, W. C. Macromolecules 1980, 13, 1221; Paul, D. R., Barlow, J. W. Polymer 1984, 25, 487.
7. Balazs, A. C.; Sanchez, I. R.; Epstein, I. R.; Karasz, F. E.; MacKnight, W. J. Macromolecules 1985, 18, 2188.
8. Dudowicz, J.; Freed, K. F. Macromolecules 1996, 29, 7826.
9. Dudowicz, J.; Freed, K. F. Macromolecules 1991, 24, 5076.
10. Freed, K. F.; Dudowicz, J. To be published.
11. Dudowicz, J.; Freed, K. F. Macromolecules 1990, 23, 1519.
12. Flory, P. J.; Orwoll, R. A.; Vrij, A. J. Am. Chem. Soc. 1964, 86, 3507, 3515.
13. Sanchez, I. C.; Lacombe, R. H. Macromolecules 1978, 11, 1145.
14. Paul, D. R. Pure & Appl. Chem. 1995, 67, 977. Kim, C. K.; Paul, D. R. Polymer 1992, 33, 1631, 2089, 4929, 4941. Callaghan, T. A.; Paul, D. R. J. Polym. Sci. B Polym. Phys. 1994, 32, 1813, 1847. Callaghan, T. A.; Takakuwa, K.; Paul, D. R.; Padwa, A. R. Polymer 1993, 34, 3797.
15. Paul, D. R. Pure & Appl. Chem. 1995, 67, 977. Kim, C. K.; Paul, D. R. Polymer 1992, 33, 1631, 2089, 4929, 4941. Callaghan, T. A.; Paul, D. R. J. Polym. Sci. B Polym. Phys. 1994, 32, 1813, 1847. Callaghan, T. A.; Takakuwa, K.; Paul, D. R.; Padwa, A. R. Polymer 1993, 34, 3797.
16. Paul, D. R. Pure & Appl. Chem. 1995, 67, 977. Kim, C. K.; Paul, D. R. Polymer 1992, 33, 1631, 2089, 4929, 4941. Callaghan, T. A.; Paul, D. R. J. Polym. Sci. B Polym. Phys. 1994, 32, 1813, 1847. Callaghan, T. A.; Takakuwa, K.; Paul, D. R.; Padwa, A. R. Polymer 1993, 34, 3797.
17. Paul, D. R. Pure & Appl. Chem. 1995, 67, 977. Kim, C. K.; Paul, D. R. Polymer 1992, 33, 1631, 2089, 4929, 4941. Callaghan, T. A.; Paul, D. R. J. Polym. Sci. B Polym. Phys. 1994, 32, 1813, 1847. Callaghan, T. A.; Takakuwa, K.; Paul, D. R.; Padwa, A. R. Polymer 1993, 34, 3797.
18. Gan, P. P.; Paul, D. R. Polymer 1994, 35, 3513; J. Appl. Polym. Sci. 1994, 54, 317. Gan, P. P.; Paul, D. R.; Padwa, A. R. Polymer 1994, 35, 1487.
19. Gan, P. P.; Paul, D. R. Polymer 1994, 35, 3513; J. Appl. Polym. Sci. 1994, 54, 317. Gan, P. P.; Paul, D. R.; Padwa, A. R. Polymer 1994, 35, 1487.
20. Gan, P. P.; Paul, D. R. Polymer 1994, 35, 3513; J. Appl. Polym. Sci. 1994, 54, 317. Gan, P. P.; Paul, D. R.; Padwa, A. R. Polymer 1994, 35, 1487.
21. Chai, Z.; Sun, R.; Karasz, F. E. Macromolecules 1992, 25, 6113; 1995, 28, 2297.
22. Chai, Z.; Sun, R.; Karasz, F. E. Macromolecules 1992, 25, 6113; 1995, 28, 2297.
23. Krishnamoorti, R.; Graessley, W. W.; Balsara, N. P.; Lohse, D. J. Macromolecules 1994, 27, 3073. Graessley, W. W.; Krishnamoorti, R.; Balsara, N. P.; Butera, R. J.; Fetters, L. J.; Lohse, D. J.; Schulz, D. N.; Sisano, J. A. Macromolecules 1994, 27, 2574, 3896. Graessley, W. W.; Krishnamoorti, R.; Reichart, G. C.; Balsara, N. P.; Fetters, L. J.; Lohse, D. J. Macromolecules 1995, 28, 1260.
24. Krishnamoorti, R.; Graessley, W. W.; Balsara, N. P.; Lohse, D. J. Macromolecules 1994, 27, 3073. Graessley, W. W.; Krishnamoorti, R.; Balsara, N. P.; Butera, R. J.; Fetters, L. J.; Lohse, D. J.; Schulz, D. N.; Sisano, J. A. Macromolecules 1994, 27, 2574, 3896. Graessley, W. W.; Krishnamoorti, R.; Reichart, G. C.; Balsara, N. P.; Fetters, L. J.; Lohse, D. J. Macromolecules 1995, 28, 1260.
25. Krishnamoorti, R.; Graessley, W. W.; Balsara, N. P.; Lohse, D. J. Macromolecules 1994, 27, 3073. Graessley, W. W.; Krishnamoorti, R.; Balsara, N. P.; Butera, R. J.; Fetters, L. J.; Lohse, D. J.; Schulz, D. N.; Sisano, J. A. Macromolecules 1994, 27, 2574, 3896. Graessley, W. W.; Krishnamoorti, R.; Reichart, G. C.; Balsara, N. P.; Fetters, L. J.; Lohse, D. J. Macromolecules 1995, 28, 1260.
26. Rhee, J.; Grist, B. Macromolecules 1991, 24, 5663. Nicholson, J. C.; Finerman, T, M.; Crist, B. Polymer 1990, 31, 2287.
27. Rhee, J.; Grist, B. Macromolecules 1991, 24, 5663. Nicholson, J. C.; Finerman, T, M.; Crist, B. Polymer 1990, 31, 2287.
28. Scheffold, F.; Eiser, E.; Butkowski, A.; Steiner, U.; Klein, J.; Fetters, L. J. J. Chem. Phys. 1996, 104, 8786.
29. Russell, T. P. Private communication. Kulasekere, R.; Kaiser, H.; Ankner, J. F.; Russell, T. P.; Brown, H. R.; Hawker, C. J.; Mayes, A. M. Macromolecules 1996, 29, 5493.
30. Russell, T. P. Private communication. Kulasekere, R.; Kaiser, H.; Ankner, J. F.; Russell, T. P.; Brown, H. R.; Hawker, C. J.; Mayes, A. M. Macromolecules 1996, 29, 5493.
31. Winey, K. I.; Berba, M. L.; Galvin, M. E. Macromolecules 1996, 29, 2868.
32. Patterson, D. Macromolecules 1969, 2, 672.
33. Dudowicz, J.; Freed, K. F. J. Chem. Phys. 1994, 100, 4653.
34. Lupis, C. H. P.; Chemical Thermodynamics of Materials; P T R Prentice Hall: Englewood Cliffs, NJ, 1983.
35. Rowlinson, J. S.; Swinton, F. L. Liquids and Liquid Mixtures; 3rd. ed.; Butterworths: London, 1982.
36. Dudowicz, J.; Freed, K. F. Macromolecules 1995, 28, 6625.
37. Freed, K. F.; Dudowicz, J. Trends Polym. Sci. 1995, 3, 248.
38. Dudowicz, J.; Freed, K. F. Macromolecules 1991, 24, 5112.
39. Dudowicz, J.; Freed, K. F. Macromolecules 1996, 29, 8960. Freed, K. F.; Dudowicz, J. Macromolecules 1996, 29, 625.
40. Dudowicz, J.; Freed, K. F. Macromolecules 1996, 29, 8960. Freed, K. F.; Dudowicz, J. Macromolecules 1996, 29, 625.
41. Hamada, F.; Shiomi, T.; Fujisawa, K.; Nakajima, A. Macromolecules 1980, 13, 729. Shiomi, T.; Fujisawa, K.; Hamada, F.; Nakajima, A. J. Chem. Soc., Faraday Trans. 1 1980, 76, 885. Fujisawa, K.; Shiomi, T.; Hamada, F.; Nakajima, A. Polym. Bull. 1980, 3, 261.
42. Hamada, F.; Shiomi, T.; Fujisawa, K.; Nakajima, A. Macromolecules 1980, 13, 729. Shiomi, T.; Fujisawa, K.; Hamada, F.; Nakajima, A. J. Chem. Soc., Faraday Trans. 1 1980, 76, 885. Fujisawa, K.; Shiomi, T.; Hamada, F.; Nakajima, A. Polym. Bull. 1980, 3, 261.
43. Hamada, F.; Shiomi, T.; Fujisawa, K.; Nakajima, A. Macromolecules 1980, 13, 729. Shiomi, T.; Fujisawa, K.; Hamada, F.; Nakajima, A. J. Chem. Soc., Faraday Trans. 1 1980, 76, 885. Fujisawa, K.; Shiomi, T.; Hamada, F.; Nakajima, A. Polym. Bull. 1980, 3, 261.
44. Callaghan, T. A.; Paul, D. R. Macromolecules 1993, 26, 2439.
45. Han, C. C.; Bauer, B. J.; Clark, J. C.; Muroga, Y.; Matsushita, Y.; Okada, M.; Tran-cong, Q.; Chang, T.; Sanchez, I. C. Polymer 1988, 29, 2002.
46. Sanchez-Lacombe theory accounts for a LCST phase behavior due to the presence of three parameters P*, T*, and v* for each binary blend component and due to the use of specific combining rules for P*, T*, and v* for mixtures. A similar type of argument applies to Flory-Orwoll-Vrij theory.