Reactive surfactants in heterophase polymerization. 7. Emulsion copolymerization mechanism involving three anionic polymerizable surfactants (surfmers) with styrene-butyl acrylate-acrylic acid

Macromolecules

Volumn 30, Issue 20, 1997, Pages 6024-6033

  Schoonbrood, Harold A S ^a,c   Unzué, Maria J ^a   Beck, Ole Jacob ^a,d   Asua, José M ^a   Goñi, Amaia Montoya ^b   Sherrington, David C ^b  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF STRATHCLYDE   (United Kingdom)

^c SANOFI   (France)

^d NORWEGIAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Norway)

Author keywords

[No Author keywords available]

Indexed keywords

COAGULATION; COPOLYMERIZATION; ESTERS; MICELLES; MONOMERS; SOLIDS; STYRENE; SURFACE ACTIVE AGENTS;

ANIONIC POLYMERIZABLE SURFACTANT; HETEROPHASE POLYMERIZATION; STYRENE BUTYL ACRYLATE ACRYLIC ACID;

EMULSION POLYMERIZATION;

EID: 0031556506     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9701447     Document Type: Article

References (62)

1. Greene, B. W.; Sheetz, D. P. J. Colloid Interface Sci. 1970, 32, 96.
2. Digioia, F. A.; Nelson, R. E. Ind. Eng. Chem. 1953, 45, 745.
3. Holmberg, K. Prog. Org. Coat. 1992, 20, 325.
4. Guyot, A.; Tauer, K. Adv. Polym. Sci. 1994, 111, 43.
5. Tauer, K.; Goebel, K.-H.; Kosmella, S.; Neelsen, J.; Stähler, K. Plaste Kautsch. 1988, 35, 373.
6. Tauer, K.; Goebel, K.-H.; Kosmella, S.; Stähler, K.; Neelsen, J. Makromol. Chem., Macromol. Symp. 1990, 31, 107.
7. Kusters, J. M. H.; Napper, D. H.; Gilbert, R. G.; German, A. L. Macromolecules 1992, 25, 7043.
8. Tauer, K.; Kosmella, S. Polym. Int. 1993, 30, 253.
9. Kusters, J. M. H. Inisurfs: Surface-active initiators. Ph.D. Thesis, Eindhoven University of Technology, Eindhoven, The Netherlands, 1994.
10. Vidai, F.; Hamaide, T. Polym. Bull. 1995, 35, 1.
11. Vidai, F.; Guillot, J.; Guyot, A. J. Colloid Polym. Sci., submitted for publication.
12. Vidal, F.; Guillot, J.; Guyot, A. Polym. Adv. Technol. 1994, 6, 473.
13. Guyot, A.; Vidal, F. Polym. Bull. 1995, 34, 569.
14. Larrabee, C. E., Jr.; Sprague, E. D. J. Polym. Sci., Polym. Lett. 1979, 17, 749.
15. Denton, J. M.; Duecker, D. C.; Sprague, E. D. J. Phys. Chem. 1993, 97, 756.
16. Salamone, J. C.; Israel, S. C.; Taylor, P.; Snider, B. Polymer 1973, 14, 639.
17. Mielke, I.; Ringsdorf, H. Makromol. Chem. 1971, 142, 319.
18. Cochin, D.; Candau, F.; Zana, R. Macromolecules 1993, 26, 5755.
19. Cochin, D.; Zana, R.; Candau, F. Macromolecules 1993, 26, 5765.
20. Hamid, S. M.; Sherrington, D. C. Polymer 1987, 28, 325 and 332.
21. Nagai, K.; Ohishi, Y.; Inaba, H.; Kudo, S. J. Polym. Sci., Polym. Chem. 1985, 23, 1221.
22. Nagai, K.; Ohishi, Y. J. Polym. Sci., Polym. Chem. 1994, 32, 445.
23. Hamid, S. M.; Sherrington, D. C. J. Chem. Soc., Chem. Commun. 1986, 936.
24. Vaskova, V.; Renoux, D.; Bernard, M.; Selb, J.; Candau, F. Polym. Adv. Technol. 1994, 6, 441.
25. Paleos, C. M.; Malliaris, A. J. Macromol. Sci., Rev. Macromol. Chem. Phys. 1988, C28, 403.
26. Candau, F.; Zana, R. Encyclopedia: Salamone; submitted for publication.
27. Nagai, K.; Fujii, I.; Kuramoto, N. Polymer 1992, 33, 3061.
28. Greene, B. W.; Sheetz, D. P.; Filer, T. D. J. Colloid Interface Sci. 1970, 32, 90.
29. Greene, B. W.; Saunders, F. L. J. Colloid Interface Sci. 1970, 33, 393.
30. Tsaur, S.-L.; Fitch, R. M. J. Colloid Interface Sci. 1987, 115, 450.
31. Watanabe, S.; Ozaki, H.; Mitsuhashi, K.-I.; Nakahama, S. Makromol. Chem. 1992, 193, 2781.
32. Kozuka, K.; Kobayashi, S.; Watanabe, A.; Iki, Y.; Yokoe, M. U.S. Patent 3,980,622, 1976.
33. Tang, R. H.; Chakrabarti, P. M. WO 89/12618, 1989.
34. Guillaume, J. L.; Pichot, C.; Guillot, J. J. Polym. Sci., Polym. Chem. 1990, 28, 137.
35. Urquiola, M. B.; Dimonie, V. L.; Sudol, E. D.; El-Aasser, M. S. J. Polym. Sci., Polym. Chem. 1992, 30, 2619.
36. Urquiola, M. B.; Dimonie, V. L.; Sudol, E. D.; El-Aasser, M. S. J. Polym. Sci., Polym. Chem. 1992, 30, 2631.
37. Urquiola, M. B.; Sudol, E. D.; Dimonie, V. L.; El-Aasser, M. S. J. Polym. Sci., Polym. Chem. 1993, 31, 1403.
38. Montoya Goñi, A.; Sherrington, D. C.; Schoonbrood, H. A. S.; Asua, J. M., in preparation.
39. Ferguson, P.; Sherrington, D. C.; Gough, A. Polymer 1993, 34, 3281.
40. Filet, A.; Guillot, J.; Hamaide, T.; Guyot, A. Polym. Adv. Technol. 1994, 6, 465.
41. Westby, M. J. Colloid Polym. Sci. 1988, 266, 46.
42. Brown, R.; Stützel, B.; Sauer, T. Macromol. Chem. Phys. 1995, 196, 2047.
43. Akashi, M.; Yanagi, T.; Yashima, E.; Miyauchi, N. J. Polym. Sci., Polym. Chem. 1989, 27, 3521.
44. Paluel, A. L. L.; Westby, M. J.; Bromly, C. W. A.; Davies, S. P.; Backhouse, A. J. Makromol. Chem., Macromol. Symp. 1990, 35/36, 509.
45. Unzué, M. J.; Schoonbrood, H. A. S.; Asua, J. M.; Montoya, A.; Sherrington, D. C.; Stähler, K.; Goebel, K. H.; Tauer, K.; Sjöberg, M.; Holmberg, K. J. Appl. Polym. Sci., in press.
46. Goebel, K.-H.; Stähler, K.; von Berlepsch, H. Colloids Surf. A 1994, 87, 143.
47. Stähler, K. Einfluss von Monomer-Emulgatoren auf die AIBN-initiierte Emulsionspolymerisation von Styren, Ph.D. Thesis, University of Potsdam, 1994.
48. Goebel, K.-H.; Stähler, K. Polym. Adv. Technol. 1994, 6, 452.
49. Unzué, M. J. Uso de emusificantes polimerizables en polimerización en emulsión. Ph.D. Thesis, Universidad del País Vasco, San Sebastián, Spain, 1996.
50. Schoonbrood, H. A. S.; Unzué, M. J.; Amalvy, J. I.; Asua, J. M. J. Polym. Sci., Part A: Polym. Chem. 1997, accepted for publication.
51. Ahmed, S. M. Ph.D. Thesis, Lehigh University, Bethlehem, PA, 1979.
52. Ahmed, S. M.; El-Aasser, M. S.; Micale, F. J.; Poehlein, G. W.; Vanderhoff, J. W. Org. Coat. Plast. Chem. 1980, 43, 120.
53. Reid, V. W.; Longman, G. F.; Heinert, E. Tenside 1967, 4, 292.
54. Polymer Handbook, 3rd ed.; Brandrup, J., Immergut, E. H., Eds.; John Wiley & Sons: New York, 1989.
55. Schoonbrood, H. A. S.; van Eijnatten, R. C. P. M.; van den Reijen, B.; van Herk, A. M.; German, A. L. J. Polym. Sci., Part A: Polym. Chem. 1996, 34, 935.
56. Minoura, Y.; Tadokoro, T.; Suzuki, Y. J. Polym. Sci., Polym. Chem. Ed. 1967, 5, 2641.
57. Urquiola, M. B. Ph.D. Thesis, Lehigh University, Bethlehem, PA, 1992.
58. Otsu, T.; Matsumoto, A.; Shiraishi, K.; Amaya, N.; Koinuma, Y. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 1559.
59. Busfield, W. K.; Jenkins, I. D.; Heiland, K. Eur. Polym. J. 1994, 30, 1259.
60. Bengough, W. I.; Goldrich, D.; Young, R. A. Eur. Polym. J. 1967, 3, 117.
61. Otsu, T.; Shiraishi, K.; Matsumoto, A. J. Polym. Sci., Part A: Polym. Chem. 1993, 31, 2523.
62. Schoonbrood, H. A. S.; Asua, J. M. Macromolecules 1997, 30, 6034.