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4243058620
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note
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After the PEI-coated crystal was rinsed with water and DMF, the frequency became stable, and further rinsing with DMF caused negligible frequency changes (±5 Hz). The PEI film is thus stable after one DMF rinse.
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24
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4243138597
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note
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Exposure of bare gold to succinic anhydride in DMF followed by rinsing with DMF produced a negligible frequency change. This demonstrates that the much larger frequency changes resulting from immersion of PEI-coated crystals in succinic anhydride/DMF are due to irreversible attachment of mass to the polymer support.
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25
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4243083500
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note
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The XPS data support the conclusion that, under the completely anhydrous conditions employed, most of this frequency decrease is due to attachment of dopamine via amide bond formation. We note however that subsequent rinsing with water causes TSM sensor frequency increases which may be due to hydrolysis of small amounts of the remaining ester-linked O-acylisourea intermediate and/or some removal of the polymer support.
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28
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85088620668
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note
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-8 Torr) present in the instrument.
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29
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4243124382
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note
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Although we might expect an increase in the peak at 285.8 eV from the methylene carbons of the attached anhydride, its decrease is likely simply a reflection of a lower absolute amount of polymer present in the PEI + SA samples vs the PEI sample. This is consistent with the fact that the latter sample was not rinsed with DMF and therefore contains an excess of polymer which is normally removed with this rinse.
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0028465806
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