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1
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4
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85033084391
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S, Patai, Z. Rappoport (Eds.), and literature given there
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[4] Calculational studies indicate that nucleophilic substitution on silicon via pentacoordinate intermediates is always more favorable than a single-step reaction via a pentacoordinate transition state, e.g., Y. Apeloig, in: S, Patai, Z. Rappoport (Eds.), The Chemistry of Organic Silicon Compounds, 1989, p. 207, and literature given there.
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Apeloig, Y.1
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8
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37049092597
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Schulthess, A.H.3
Akinde, B.4
Walton, D.R.M.5
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12
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Ishikawa, M.1
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Sugisawa, H.3
Nishimura, K.4
Kumada, M.5
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14
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0025732068
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[14] N. Tokitoh, T. Matsumoto, H. Suzuki, R. Okazaki, Terahedron Lett. 32 (1991) 2049.
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Tokitoh, N.1
Matsumoto, T.2
Suzuki, H.3
Okazaki, R.4
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18
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[18] D. Seyferth, R. Damrauer, S.B. Andrews, S.S. Washburne, J. Am. Chem. Soc. 93 (1971) 3709;
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Seyferth, D.1
Damrauer, R.2
Andrews, S.B.3
Washburne, S.S.4
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19
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0027181938
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[19] K. Matsumoto, Y. Aoki, K. Oshina, K. Utimoto, N.A. Rahman, Tetrahedron 49 (1993) 8487.
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Matsumoto, K.1
Aoki, Y.2
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Utimoto, K.4
Rahman, N.A.5
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20
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0000912323
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[20] B.J. Helmer, R. West, R.J.P. Corriu, M. Poirier, G. Royo, A. De Saxce, J. Organomet. Chem. 51 (1983) 295.
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De Saxce, A.6
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21
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0010880202
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[21] A.H.J.F. de Keijzer, F.J.J. de Kanter, M. Schakel, R.F. Schmitz, G.W. Klumpp, Angew. Chem. 108 (1996) 1183; Angew. Chem., Int. Ed. Engl. 35 (1996) 1127.
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De Keijzer, A.H.J.F.1
De Kanter, F.J.J.2
Schakel, M.3
Schmitz, R.F.4
Klumpp, G.W.5
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22
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0029815989
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[21] A.H.J.F. de Keijzer, F.J.J. de Kanter, M. Schakel, R.F. Schmitz, G.W. Klumpp, Angew. Chem. 108 (1996) 1183; Angew. Chem., Int. Ed. Engl. 35 (1996) 1127.
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23
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0001400380
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[22] Recently, another silicate devoid of ligands more electronegative than carbon has been published: potassium 1,4-(1,2,3,4-tetraphenyl-1,3-butadienediyl)dihydridomethylsilicate. J.-H. Hong, P. Boudjouk, Organometallics 14 (1995) 574.
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Organometallics
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Hong, J.-H.1
Boudjouk, P.2
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24
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85033098025
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+ by HMPA was proven and tetracoordination by THF is highly probable [17]
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+ by HMPA was proven and tetracoordination by THF is highly probable [17].
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25
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85033073595
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6 was added
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6 was added.
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26
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85033088893
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note
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3 ).
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27
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0001220792
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note
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29Si) = 70.5 Hz.
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29
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85033085061
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29Si: - 1.26 ppm. A mixture of oligo-1,1-dimethyl-1-silabutanes seemed to be formed from 1,1 -dimethyl-1-silacyclobutane
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29Si: - 1.26 ppm. A mixture of oligo-1,1-dimethyl-1-silabutanes seemed to be formed from 1,1 -dimethyl-1-silacyclobutane.
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33
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0010863876
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4. M.S. Gordon, M.T. Carroll, L.P. Davis, L.W. Burggraf, J. Phys. Chem. 94 (1990) 8125.
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(1990)
J. Phys. Chem.
, vol.94
, pp. 8125
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Gordon, M.S.1
Carroll, M.T.2
Davis, L.P.3
Burggraf, L.W.4
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