Electric fields in and around ion-exchange membranes

Journal of Membrane Science

Volumn 125, Issue 1, 1997, Pages 17-21

  Rubinstein, I ^a   Zaltzman, B ^a   Kedem, O ^a  

^a BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

Author keywords

Concentration polarization; Electro convection; Electrodialysis; Electroosmosis; Ion exchange membranes; Limiting current

Indexed keywords

CALCULATIONS; CURRENT DENSITY; ELECTRIC FIELD EFFECTS; ELECTRIC FIELDS; IONS; MATHEMATICAL MODELS; PHASE INTERFACES; POLYELECTROLYTES; STABILITY; SURFACES;

BULK VELOCITY DISTRIBUTIONS; CHARGE MEMBRANE; CHARGED PORES; DONNAN POTENTIALS; EQUILIBRIUM DISTRIBUTIONS; PHASE BOUNDARIES; POLYELECTROLYTE CHAINS;

ION EXCHANGE MEMBRANES;

ARTICLE; ARTIFICIAL MEMBRANE; ELECTRIC FIELD; ELECTRODIALYSIS; ELECTROOSMOSIS; ION EXCHANGE; MATHEMATICAL ANALYSIS; PRIORITY JOURNAL;

EID: 0031553841     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(96)00194-9     Document Type: Article

References (26)

1. T. Teorell, An attempt to formulate a quantitative theory of membrane permeability, Proc. Soc. Expt. Biol. Med., 33 (1935) 282.
2. K.H. Meyer and J.F. Sievers, La perméabilité des membranes, I. Theorie de la perméabilité ionique, II. Essais avec de-s membranes selectives artificielles, Helv. Chem. Acta, 19 (1936) 649-664, 665-680.
3. E. Hof fer and O. Kedem, Hyperfiltration in charged membranes: prediction of salt rejection from equilibrium measurements, J. Phys. Chem., 76 (1972) 36-38.
4. L. Dresner, Some remarks on the integration of the extended Nernst-Planck equations in the hyperfiltration of multicomponent solutions, Desalination, 10 (1972) 27.
5. R. Simons, Strong electric field effects on proton transfer between membrane-bound amines and water, Nature, 280(30) (1979) 824.
6. O. Kedem and A. Katchalsky, Permeability of composite membranes, I, II, III, Trans. Faraday Soc., 59 (1963) 1918, 1931, 1941.
7. R. Neihof and K. Sollner, A. quantitative electrochemical theory of the electrolyte permeability of mosaic membranes composed of selectively anion-permeable and selectively cation-permeable parts and its experimental verification, I., J. Phys. Colloid Chem., 54 (1950) 157.
8. J.N. Weinstein, B.J. Bunow and S.R. Caplan, Transport properties of charge-mosaic membranes, I. Theoretical models, Desalination, 11 (1972) 341.
9. I. Rubinstein and L. Shtilman, Voltage against current curves of cation exchange membranes, J. Chem. Soc., Faraday Trans. II, 75 (1979) 231.
10. I. Rubinstein, Electro-Diffusion of Ions, SIAM, Philadelphia, 1990, p. 170.
11. V.V. Nikonenko, V.I. Zabolotsky and N.P. Gnusin, Electrotransfer of ions across a diffusion layer with violated electroneutrality, Elektrokhimia, 25 (1989) 301 (Russ.)
12. A.V. Listovichny, Passage of currents higher than the limiting one through the system electrode-electrolyte solution, Electrokhimia, 25 (1989) 1651 (Russ.).
13. S.S. Dukhin, Electrokinetic phenomena of the second kind and their applications, Adv. Coll. Interf. Sci., 5 (1991) 173
14. I. Rubinstein and B. Zaltzman, Electrodiffusional free boundary problem in concentration polarization in electrodialysis, J. Math. Mod. Methods Appl. Sci., in press.
15. R. Simons, The origin and elimination of water splitting in ion-exchange membranes during water demineralization by electrodialysis, Desalination, 28 (1979) 41.
16. I. Rubinstein, A. Warsawsky, L. Schechtman and O. Kedem, Elimination of acid-base generation ('water splitting') in electrodialysis, Desalination, 51 (1984) 55.
17. I. Rubinstein, E. Staude and O. Kedem, Role of the membrane surface in concentration polarization at ion-exchange membrane, Desalination, 69 (1988) 101.
18. F. Maletzki. H.W. Rossler and E. Staude, Ion transfer across electrodialysis membranes in the overlimiting current range: stationary voltage current characteristics and current noise power spectra under different conditions of free convection. J. Membrane Sci., 71 (1992) 105.
19. I. Rubinstein and F. Maletzki, Electroconvection at an electrically inhomogeneous permselective membrane surface, J. Chem. Soc., Faraday Trans., 87 (1991) 2079.
20. I. Rubinstein, Electroconvection at an electrically inhomogeneous permselective interface, Phys. Fluids A, 3 (1991) 2301.
21. A.P. Grigin, Coulomb convective instability of a binary electrolyte in a cell with plain-parallel electrodes, Electrokhimia 21 (1985) 52 (Russ.).
22. A.P. Grigin, Coulomb convection in electro-chemical systems, Electrokhimia, 28 (1992) 307 (Russ.).
23. R. Bruinsma and S. Alexander, Theory of electrohydrodynamic instability in electrolytic cells. J. Chem. Phys., 92 (1990) 3074.
24. I. Rubinstein, T. Zaltzman and B. Zaltzman, Electroconvection in a layer and in a loop, Phys. Fluids, 7 (1995) 1467.
25. T. Zaltzman, Electroconvection in a layer and in a loop in potentiostatic conditions, Phys. Fluids, in press.
26. V.K. Indusekhar and P. Meares, The effect of the diffusion layer on the ionic current from a solution into an ion-exchange membrane, in Physicochemical Hydrodynamics II, D.B. Spalding, ed., Advance Publications Limited, London, 1977, p. 1031.