Mathematical modeling of solid-liquid phase-transfer catalysis

Chemical Engineering Science

Volumn 52, Issue 24, 1997, Pages 4533-4546

  Naik, Sanjeev D ^a   Doraiswamy, L K ^a  

^a Iowa State University of Science and Technology   (United States)

Author keywords

Mathematical modeling; Phase transfer catalysis; Solid liquid systems

Indexed keywords

MATHEMATICAL MODELS; PHASE TRANSITIONS; REACTION KINETICS;

PHASE TRANSFER CATALYSIS;

CATALYSIS;

EID: 0031553380     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(97)00297-2     Document Type: Article

References (29)

1. Asai, S., Nakamura, H. and Furuichi, Y. (1992) Alkaline hydrolysis of n-butyl acetate with phase transfer catalyst Aliquat 336. A.I.Ch.E. J. 38, 397-404.
2. Bram, G., Loupy, A and Sansoulet, J. (1985) Anionic activation by solid-liquid PTC without solvents: improvements in organic synthesis. Israel J. Chem. 26, 291-298.
3. Dehmlow, E. V. and Dehmlow, S. S. (1993) Phase Transfer Catalysis, 3rd Edn. Verlag Chemie, Weinheim.
4. Doraiswamy, L. K. and Sharma, M. M. (1984) Heterogeneous Reactions, Analysis, Examples and Reactor Design, Vol. II. Wiley, New York, U.S.A.
5. Esikova, I. A. and Yufit, S. S. (1991) Formation of adsorption complexes in phase-transfer nucleophilic substitution. Kinetic analysis of solid-phase system. J. Phys. Org. Chem. 4, 149-157.
6. Evans, K. J. and Palmer, H. J. (1981) The importance of interphase transport resistances on phase transfer catalyzed reaction. A.I.Ch.E. Symp. Ser. 77, (202) 104-113.
7. Freedman, H. H. (1986) Industrial applications of phase transfer catalysis (PTC): past, present and future. Pure Appl. Chem. 58, 857-868.
8. Goldberg, Y. (1992) Phase Transfer Catalysis, Selected Problems and Applications. Gordon and Breach Science Publishers, Philadelphia.
9. Hagenson, L. C., Naik, S. D. and Doraiswamy, L. K. (1994) Rate enhancements in a solid-liquid reaction using PTC, microphase, ultrasound and combinations thereof. Chem. Engng Sci. 49, 4787-4800.
10. Landini, D., Maia, A. M. and Podda, G. (1982) Non-hydrated anion transfer from the aqueous to the organic phase: enhancement of nucleophilic reactivity in phase-transfer catalysis. J. Org. Chem 47, 2264-2268.
11. Lele, S. S., Bhave, R. R. and Sharma, M. M. (1983) Fast and very slow liquid-liquid reaction: phase transfer catalysis. Chem. Engng Sci 38, 765-773.
12. Liotta, C. L., Burgess, E. M., Ray, C. C., Black, E. D. and Fair, B. E. (1987) Mechanism of phase transfer catalysis: the omega phase. ACS Symp. Ser. 326, 15-23.
13. Lindman, N. and Simonsson, D. (1979) On the application of the shrinking core model to liquid-solid reactions. Chem. Engng Sci. 34, 31-35.
14. Melville, J. B. and Goddard, J. D. (1985) Mass-transfer enhancement and reaction-rate limitations in solid-liquid phase-transfer catalysis. Chem. Engng Sci. 40, 2207-2215.
15. Melville, J. B. and Goddard, J. D. (1988) A solid-liquid phase transfer catalysis in rotating-disk flow. Ind. Engng Chem. Res 27, 551-555.
16. Melville, J. B. and Goddard, J. D. (1990) Phase transfer catalysis: technology and transport phenomona. In Handbook of Heat And Mass Transfer, Vol. 4., Advances in Reactor Design and Combustion Science, ed. N. Cheremisinoff, pp. 345-371. Gulf Publishing, Houston.
17. Phadtare, P. G. and Doraiswamy, L. K. (1965) Mass transfer model for Kolbe-Schmitt carbonation of 2-naphthol. Ind. Engng Chem. Proc. Des. Dev, 4, 274-280.
18. Reuben, B. and Sjoberg, K. (1981) Phase transfer catalysis in industry. CHEMTECH 315-320.
19. Starks, C. M. (1990) Quaternary ammonium salts as phase transfer catalysts. In Industrial Applications of Surfactants II, ed. D. R. Karsa, pp. 165-194. Royal Society of Chemistry. Cambridge, England.
20. Starks, C. M., Liotta, C. L. and Halpern, M. (1994) Phase-transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives. Chapman & Hall, New York.
21. Wang, M. W. and Wu, H. S. (1991) Kinetic and mass transfer studies of a sequential reaction by phase transfer catalysis. Chem. Engng Sci. 46, 509-517.
22. Wang, M. W. and Yang, H. M. (1991) Dynamics of phase transfer catalyzed reaction for the allylation of 2,4,6-tribromophenol. Chem. Engng Sci. 46, 619-627.
23. Wong, K. H. and Wai, A.P.W. (1983) Solid-liquid phase transfer kinetics of p-nitrobenzoate esterification catalyzed by crown ethers; a comparison of the catalytic efficiency of various crown ethers. J. Chem. Soc. Perkin Trans. II 317-321.
24. Wu, H. S. (1993) Phase plane modeling of a liquid-liquid phase-transfer-catalyzed reaction. Ind. Engng Chem. Res. 32, 1323-1327.
25. Yadav, G. D. and Sharma, M. M. (1981) Kinetics of reaction of benzyl chloride with sodium acetate/benzoate: phase transfer catalysis in solid-liquid system. Ind. Engng Chem. Proc. Des. Dev. 20, 385-390.
26. Yee, H. A., Palmer, H. J. and Chen, S. H. (1987) Solid-liquid phase transfer catalysis. Chem. Engng Progr. 83, 33-39.
27. Yufit, S. S. (1995) Some problems in PTC theory: solvation, crystalline lattice strength and topology. Russian Chem. Bull. 44 (1989-1997).
28. Zahalka, H. A. and Sasson, Y. (1989) Esterification of 1,4-dichlorobutane with sodium formate under solid-liquid phase transfer catalysis. A kinetic study. Can. J. Chem. 67, 245-249.
29. Zubrick, S. W., Dunbar, B. I. and Durst, H. D. (1975) Crown ether catalysis II: cyanide and nitrite as "naked" anions. Tetr. Lett. 71-74.