Excitation function and reaction threshold studies of isotope exchange reactions: H + D2 → D + HD and H + D2O → D + HOD

Journal of Physical Chemistry A

Volumn 101, Issue 36, 1997, Pages 6448-6454

  Brownsword, Richard A ^a   Hillenkamp, Matthias ^a   Laurent, Thomas ^a   Volpp, Hans Robert ^a   Wolfrum, Jürgen ^a   Vatsa, Rajesh K ^b   Yoo, Hee Soo ^c  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b BHABHA ATOMIC RESEARCH CENTRE   (India)

^c Chungbuk National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

DEUTERIUM; FLUORESCENCE; LASER BEAM EFFECTS; PHOTOLYSIS; PULSED LASER APPLICATIONS;

COLLISION ENERGY; ISOTOPE EXCHANGE REACTION; LASER INDUCED FLUORESCENCE; PULSED LASER PHOTOLYSIS;

HYDROGEN;

EID: 0031553039     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970816v     Document Type: Article

References (88)

1. Born, M.; Oppenheimer, J. R. Ann. Phys. 1927, 84, 451.
2. London, F. Sommerfeldfestschrift; Hirzel: Leipzig, 1928.
3. London, F. Z. Elektrochem. 1929, 35, 552.
4. Eyring, H.; Polanyi, M. Z. Phys. Chem. 1931, B12, 279.
5. Hirschfelder, J. O.; Eyring, H.; Topley, B. J. Chem. Phys. 1936, 4, 170.
6. Scherer, N. F.; Khundkar, L. R.; Bernstein, R. B.; Zewail, A. H. J. Chem. Phys. 1987, 82, 1451.
7. See, e.g.: (a) Truhlar, D. G.; Wyatt, R. E. Annu. Rev. Phys. Chem. 1976, 27, 1. (b) Baer, M. Theory of Chemical Reaction Dynamics, Vol I-IV; CRC Press: Boca Raton, 1985. (d) Schatz, G. C. In The Theory of Chemical Reaction Dynamics; Clary, D. C., Ed.; Reidel: Dordrecht, 1986.
8. See, e.g.: (a) Truhlar, D. G.; Wyatt, R. E. Annu. Rev. Phys. Chem. 1976, 27, 1. (b) Baer, M. Theory of Chemical Reaction Dynamics, Vol I-IV; CRC Press: Boca Raton, 1985. (d) Schatz, G. C. In The Theory of Chemical Reaction Dynamics; Clary, D. C., Ed.; Reidel: Dordrecht, 1986.
9. See, e.g.: (a) Truhlar, D. G.; Wyatt, R. E. Annu. Rev. Phys. Chem. 1976, 27, 1. (b) Baer, M. Theory of Chemical Reaction Dynamics, Vol I-IV; CRC Press: Boca Raton, 1985. (d) Schatz, G. C. In The Theory of Chemical Reaction Dynamics; Clary, D. C., Ed.; Reidel: Dordrecht, 1986.
10. For a recent review see: Schatz, G. C. J. Phys. Chem. 1996, 100, 12839.
11. Liu, B. J. Chem. Phys. 1973, 58, 1925. Siegbahn, P.; Liu, B. J. Chem. Phys. 1978, 68, 2457. Truhlar, D. G.; Horowitz, C. J. J. Chem. Phys. 1978, 68, 2466. J. Chem. Phys. 1979, 71, 1514.
12. Liu, B. J. Chem. Phys. 1973, 58, 1925. Siegbahn, P.; Liu, B. J. Chem. Phys. 1978, 68, 2457. Truhlar, D. G.; Horowitz, C. J. J. Chem. Phys. 1978, 68, 2466. J. Chem. Phys. 1979, 71, 1514.
13. Liu, B. J. Chem. Phys. 1973, 58, 1925. Siegbahn, P.; Liu, B. J. Chem. Phys. 1978, 68, 2457. Truhlar, D. G.; Horowitz, C. J. J. Chem. Phys. 1978, 68, 2466. J. Chem. Phys. 1979, 71, 1514.
14. Liu, B. J. Chem. Phys. 1973, 58, 1925. Siegbahn, P.; Liu, B. J. Chem. Phys. 1978, 68, 2457. Truhlar, D. G.; Horowitz, C. J. J. Chem. Phys. 1978, 68, 2466. J. Chem. Phys. 1979, 71, 1514.
15. Farkas, A. Z. Phys. Chem. 1930, B10, 419.
16. 2 Kinetics. Int. J. Chem. Kinet. 1986, 18, 9.
17. Valentini, J. J.; Phillips, D. L. In Advances in Gas Phase Photochemistry and Kinetics, Vol. 2; Ashfold, M. N. R., Baggott, J. E., Eds.; Royal Society of Chemistry: London, 1989.
18. Buchenau, H.; Toennies, J. P.; Arnold, J.; Wolfrum, J. Ber. Bunsenges. Phys. Chem. 1990, 94, 1231.
19. Michael, J. V. In Advances in Chemical Kinetics and Dynamics, Vol. 1; Barker, R., Ed.; JAI Press: Greenwich, 1992.
20. Continetti, R. E.; Balko, B. A.; Lee, Y. T. J. Chem. Phys. 1990, 93, 5719.
21. Kitsopoulos, T. N.; Buntine, M. A.; Baldwin, D. P.; Zare, R. N.; Chandler, D. W. Science 1993, 262, 1852.
22. Schnieder, L.; Seekamp-Rahn, K.; Liedeke, F.; Steuwe, H.; Welge, K. H. Faraday Discuss. Chem. Soc. 1991, 9, 259. Schnieder, L.; Seekamp-Rahn, K.; Borkowski, J.; Wrede, E.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; D'Mello, M. J.; Herrero, V. J.; Sáez Rábanos, V.; Wyatt, R. E. Science 1995, 269, 207. Wrede, E.; Schnieder, L.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; Herrero, V. J. Chem. Phys. Lett. 1997, 265, 129.
23. Schnieder, L.; Seekamp-Rahn, K.; Liedeke, F.; Steuwe, H.; Welge, K. H. Faraday Discuss. Chem. Soc. 1991, 9, 259. Schnieder, L.; Seekamp-Rahn, K.; Borkowski, J.; Wrede, E.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; D'Mello, M. J.; Herrero, V. J.; Sáez Rábanos, V.; Wyatt, R. E. Science 1995, 269, 207. Wrede, E.; Schnieder, L.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; Herrero, V. J. Chem. Phys. Lett. 1997, 265, 129.
24. Schnieder, L.; Seekamp-Rahn, K.; Liedeke, F.; Steuwe, H.; Welge, K. H. Faraday Discuss. Chem. Soc. 1991, 9, 259. Schnieder, L.; Seekamp-Rahn, K.; Borkowski, J.; Wrede, E.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; D'Mello, M. J.; Herrero, V. J.; Sáez Rábanos, V.; Wyatt, R. E. Science 1995, 269, 207. Wrede, E.; Schnieder, L.; Welge, K. H.; Aoiz, F. J.; Bañares, L.; Herrero, V. J. Chem. Phys. Lett. 1997, 265, 129.
25. D'Mello, M. J.; Manolopoulos, D. E.; Wyatt, R. E. Science 1994, 263, 102.
26. Wu, Y.-S.; Kuppermann, A. Chem. Phys. Lett. 1993, 205, 577; 1993, 213, 636; 1995, 255, 105.
27. Wu, Y.-S.; Kuppermann, A. Chem. Phys. Lett. 1993, 205, 577; 1993, 213, 636; 1995, 255, 105.
28. Wu, Y.-S.; Kuppermann, A. Chem. Phys. Lett. 1993, 205, 577; 1993, 213, 636; 1995, 255, 105.
29. (a) Miller, W. H. Annu. Rev. Phys. Chem. 1990, 41, 245; Acc. Chem. Res. 1993, 26, 174.
30. (a) Miller, W. H. Annu. Rev. Phys. Chem. 1990, 41, 245; Acc. Chem. Res. 1993, 26, 174.
31. (b) Sun, Q.; Bowman, J. M. J. Chem. Phys. 1990, 92, 5201.
32. (c) Clary, D. C. J. Chem. Phys. 1991, 95, 7298.
33. (d) Zhang, D. H.; Zhang, J. Z. H. J. Chem. Phys. 1993, 99, 5615; 1994, 100, 2679; 1994, 101, 5615.
34. (d) Zhang, D. H.; Zhang, J. Z. H. J. Chem. Phys. 1993, 99, 5615; 1994, 100, 2679; 1994, 101, 5615.
35. (d) Zhang, D. H.; Zhang, J. Z. H. J. Chem. Phys. 1993, 99, 5615; 1994, 100, 2679; 1994, 101, 5615.
36. (e) Manthe, U.; Seideman, T.; Miller, W. H. J. Chem. Phys. 1993, 99, 10078; 1994, 101, 4759.
37. (e) Manthe, U.; Seideman, T.; Miller, W. H. J. Chem. Phys. 1993, 99, 10078; 1994, 101, 4759.
38. (f) Neuhauser, D. J. Chem. Phys. 1994, 100, 9272.
39. (g) Balakrishnan, N.; Billing, G. D. Chem. Phys. 1994 101, 2785; 1995, 102, 1102.
40. (g) Balakrishnan, N.; Billing, G. D. Chem. Phys. 1994 101, 2785; 1995, 102, 1102.
41. (h) Szichman, H.; Baer, M. Chem. Phys. Lett. 1995, 242, 285.
42. Kleinermanns, K.; Wolfrum, J. Appl. Phys. B 1984, 34, 5. Kessler, K.; Kleinermanns, K. Chem. Phys. Lett. 1992, 190, 145.
43. Kleinermanns, K.; Wolfrum, J. Appl. Phys. B 1984, 34, 5. Kessler, K.; Kleinermanns, K. Chem. Phys. Lett. 1992, 190, 145.
44. Jacobs, A.; Volpp, H.-R.; Wolfrum, J. 24th Symp. (Int.) on Combustion; The Combustion Institute: Pittsburgh, PA, 1992; p 605; Chem. Phys. Lett. 1992, 196, 249; 1994, 218, 51; J. Chem. Phys. 1994, 100, 1936.
45. Jacobs, A.; Volpp, H.-R.; Wolfrum, J. 24th Symp. (Int.) on Combustion; The Combustion Institute: Pittsburgh, PA, 1992; p 605; Chem. Phys. Lett. 1992, 196, 249; 1994, 218, 51; J. Chem. Phys. 1994, 100, 1936.
46. Jacobs, A.; Volpp, H.-R.; Wolfrum, J. 24th Symp. (Int.) on Combustion; The Combustion Institute: Pittsburgh, PA, 1992; p 605; Chem. Phys. Lett. 1992, 196, 249; 1994, 218, 51; J. Chem. Phys. 1994, 100, 1936.
47. Jacobs, A.; Volpp, H.-R.; Wolfrum, J. 24th Symp. (Int.) on Combustion; The Combustion Institute: Pittsburgh, PA, 1992; p 605; Chem. Phys. Lett. 1992, 196, 249; 1994, 218, 51; J. Chem. Phys. 1994, 100, 1936.
48. (a) Schatz, G. C.; Colton, J. L.; Grant, M. C. J. Phys. Chem. 1984, 88, 2971.
49. (b) Kudla, K.; Schatz, G. C. J. Chem. Phys. 1993, 98, 4644.
50. Nyman, G.; Clary, D. C. J. Chem. Phys. 1994, 100, 3556.
51. Baer, M.; Szichman, H.; Rosenman, E.; Hochman-Kowal, S.; Persky, A. In Gas Phase Chemical Reaction Systems: Experiments and Models 100 Years after Max Bodenstein; Wolfrum, J., Volpp, H.-R., Rannacher, R., Warnatz, J., Eds.; Springer Series in Chemical Physics Vol. 61; Springer-Verlag: Heidelberg, 1996.
52. Zhang, D. H.; Light, J. C. J. Chem. Phys. 1996, 104, 4544.
53. Schatz, G. C.; Elgersma, H. Chem. Phys. Lett. 1980, 73, 21.
54. Crim, F. F. J. Phys. Chem. 1996, 100, 12725.
55. (a) Schatz, G. C.; Bowman, J. M. Annu. Rev. Phys. Chem. 1995, 46, 169.
56. (b) Alagia, M.; Balucani, N.; Casavecchia, P.; Stranges, D.; Volpi, G. G.; Clary, D. C.; Kliesch, A.; Werner, H.-J. Chem. Phys. 1996, 207, 389.
57. (a) Jacobs, A.; Volpp, H.-R.; Wolfrum, J. Chem. Phys. Lett. 1992, 196, 249.
58. (b) Koppe, S.; Laurent, T.; Naik, P. D.; Volpp, H.-R.; Wolfrum, J. Can. J. Chem. 1994, 72, 614 Paper dedicated to Professor J. C. Polanyi on the occasion of his 65th birthday.
59. Talbi, D.; Saxon, R. J. Chem. Phys. 1989, 91, 2376.
60. Brownsword, R. A.; Hillenkamp, M.; Laurent, T.; Vatsa, R. K.; Volpp, H.-R.; Wolfrum, J. Chem. Phys. Lett. 1996, 259, 375.
61. Kuppermann, A. Isr. J. Chem. 1969, 7, 303.
62. (a) Johnston, G. W.; Katz, B.; Tsukiyama, K.; Bersohn, R. J. Phys. Chem. 1987, 97, 5445.
63. (b) Park, J.; Shafer, N.; Bersohn, R. J. Chem. Phys. 1989, 91, 7861.
64. Charutz, D. M.; Last, I.; Baer, M. J. Chem. Phys. 1997, 106, 7654.
65. Laurent, T.; Naik, P. D.; Volpp, H.-R.; Wolfrum, J.; Arusi-Parpar, T.; Bar, I.; Rosenwaks, S. Chem. Phys. Lett. 1995, 236, 343. Brownsword, R. A.; Hillenkamp, M.; Laurent, T.; Vatsa, R. K.; Volpp, H.-R. J. Chem. Phys. 1997, 106, 4436.
66. Laurent, T.; Naik, P. D.; Volpp, H.-R.; Wolfrum, J.; Arusi-Parpar, T.; Bar, I.; Rosenwaks, S. Chem. Phys. Lett. 1995, 236, 343. Brownsword, R. A.; Hillenkamp, M.; Laurent, T.; Vatsa, R. K.; Volpp, H.-R. J. Chem. Phys. 1997, 106, 4436.
67. Brownsword, R. A.; Hillenkamp, M.; Laurent, T.; Vatsa, R. K.; Volpp, H.-R.; Wolfrum, J. J. Phys. Chem. 1997, 101, 995.
68. Continetti, R. E.; Balko, B. A.; Lee, Y. T. Chem. Phys. Lett. 1991, 182, 400.
69. Hilber, G.; Lago, A.; Wallenstein, R. J. Opt. Soc. Am. B 1987, 4, 1753.
70. Zande, W. J. v. d.; Zhang, R.; Zare, R. N.; McKendrick, K. G.; Valentini, J. J. J. Phys. Chem. 1991, 95, 8205.
71. van Veen, G. N. A.; Mohamed, K. A.; Baller, T.; de Vries, A. E. Chem. Phys. 1983, 74, 261.
72. Levine, R. D.; Bernstein, R. B. J. Chem. Phys. 1972, 56, 2281.
73. Press, C. W. H.; Flannery, B. P.; Teukolsky, S. A.; Vetterling, W. T. Numerical Recipes in C; Cambridge University Press; Cambridge, 1988.
74. Schechter, I.; Kosloff, R.; Levine, R. D. J. Phys. Chem. 1986, 90, 1006.
75. Tsukiyama, K.; Katz, B.; Bersohn, R. J. Chem. Phys. 1986, 84, 1934. Gerlach-Meyer, U.; Kleinermanns, K.; Linnebach, E.; Wolfrum, J. J. Chem. Phys. 1987, 86, 3047.
76. Tsukiyama, K.; Katz, B.; Bersohn, R. J. Chem. Phys. 1986, 84, 1934. Gerlach-Meyer, U.; Kleinermanns, K.; Linnebach, E.; Wolfrum, J. J. Chem. Phys. 1987, 86, 3047.
77. Mladenovic, M.; Zhao, M.; Truhlar, D. G.; Schenke, D. W.; Sun, Y.; Kouri, D. J. Chem. Phys. Lett. 1988, 146, 358. Truhlar, D. G. Resonances; ACS Symp. Ser. 263; American Chemical Society: Washington, DC, 1984.
78. Mladenovic, M.; Zhao, M.; Truhlar, D. G.; Schenke, D. W.; Sun, Y.; Kouri, D. J. Chem. Phys. Lett. 1988, 146, 358. Truhlar, D. G. Resonances; ACS Symp. Ser. 263; American Chemical Society: Washington, DC, 1984.
79. Zande, W. J. v. d.; Zhang, R.; Zare, R. N. Spectral Line Shapes; American Institute of Physics: New York, 1990; Vol. 6.
80. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
81. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
82. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
83. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
84. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
85. Gerrity, D. P.; Valentini, J. J. J. Chem. Phys. 1983, 81, 1298. Veirs, D. K.; Rosenblatt, G. M.; Valentini, J. J. J. Chem. Phys. 1985, 83, 1605. J. Chem. Phys. 1985, 83, 1605. Phillips, D. L.; Levene, H. B.; Valentini, J. J. J. Chem. Phys. 1989, 90, 1600. Marinero, E.; Rettner, C. T.; Zare, R. N. J. Chem. Phys. 1984, 80, 4142. Rinnen, K. D.; Kliner, D. A. V.; Zare, R. N. J. Chem. Phys. 1989, 90, 7514.
86. Blais, N. C.; Truhlar, D. G. Chem. Phys. Lett. 1983, 102, 120; J. Chem. Phys. 1985, 83, 2201.
87. Blais, N. C.; Truhlar, D. G. Chem. Phys. Lett. 1983, 102, 120; J. Chem. Phys. 1985, 83, 2201.
88. Bibler, N. E.; Firestone, R. F. J. Phys. Chem. 1972, 76, 621.