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Volumn 101, Issue 36, 1997, Pages 6798-6806

A new aspect for the insertion of the 16-electron species (η5-C5H5)ML into saturated hydrocarbons. A (η5-C5H5)ML + CH4 (M = Rh, Ir; L = CO, SH2, PH3) case study

(2) Su, Ming Der a Chu, San Yan a

a NATIONAL TSING HUA UNIVERSITY (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; COMPOSITION EFFECTS; ELECTRONS; HYDROCARBONS; HYDROGEN BONDS; OXIDATION;

POTENTIAL ENERGY SURFACES;

ORGANOMETALLICS;

EID: 0031552982 PISSN: 10895639 EISSN: None Source Type: Journal
DOI: 10.1021/jp970021o Document Type: Article

Times cited : (24)

References (89)

1
- 0000418997
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1975) Acc. Chem. Res. , vol.8 , pp. 113
- Parshall, G.W.¹

2
- 0000058263
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1984) Science , vol.223 , pp. 902
- Bergman, R.G.¹

3
- 0020495095
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1984) Pure Appl. Chem. , vol.56 , pp. 13
- Janowicz, A.H.¹ Perima, R.A.² Buchanan, J.M.³ Kovac, C.A.⁴ Struker, J.M.⁵ Wax, M.J.⁶ Bergman, R.G.⁷

4
- 0004281404
- Wiley: New York
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1989) Activation and Functionalization of Alkanes
- Hill, C.L.¹

5
- 0002260973
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1985) Inorg. Chim. Acta , vol.100 , pp. 41
- Halpern, J.¹

6
- 0011672481
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1986) New J. Chem. , vol.10 , pp. 9
- Ephritikhine, M.¹

7
- 0002654739
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1989) Acc. Chem. Res. , vol.22 , pp. 91
- Jones, W.D.¹ Feher, F.J.²

8
- 0042728760
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1990) Chem. Rev. , vol.90 , pp. 403
- Ryabov, A.D.¹

9
- 0003548222
- VCH: New York
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1990) Selective Hydrocarbon Activation, Principles and Progress
- Davies, J.A.¹ Watson, P.L.² Liebman, J.F.³ Greenberg, A.⁴

10
- 0000798201
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1990) J. Organomet. Chem. , vol.400 , pp. 273
- Bergman, R.G.¹

11
- 0011682067
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1992) Adv. Chem. Ser. , vol.230 , pp. 211
- Bergman, R.G.¹

12
- 0000313458
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1992) Science , vol.255 , pp. 315
- Wasserman, E.P.¹ Moore, C.B.² Bergman, R.G.³

13
- 33745385639
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1993) Angew. Chem., Int. Ed. Engl. , vol.32 , pp. 789
- Crabtree, R.H.¹

14
- 0011564958
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1995) Angew. Chem., Int. Ed. Engl. , vol.34 , pp. 1937
- Schroder, D.¹ Schwarz, H.²

15
- 0040268573
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1994) Coord. Chem. Rev. , vol.132 , pp. 155
- Lees, A.J.¹ Purwoko, A.A.²

16
- 0000820085
- For reviews, see: (a) Parshall, G. W. Acc. Chem. Res. 1975, 8, 113. (b) Bergman, R. G. Science 1984, 223, 902. (c) Janowicz, A. H.; Perima, R. A.; Buchanan, J. M.; Kovac, C. A.; Struker, J. M.; Wax, M. J.; Bergman, R. G. Pure Appl. Chem. 1984, 56, 13. (d) Hill, C. L. Activation and Functionalization of Alkanes; Wiley: New York, 1989. (e) Halpern, J. Inorg. Chim. Acta 1985, 100, 41. (f) Ephritikhine, M. New J. Chem. 1986, 10, 9. (g) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91. (h) Ryabov, A. D. Chem. Rev. 1990, 90, 403. (i) Davies, J. A.; Watson, P. L.; Liebman, J. F.; Greenberg, A. Selective Hydrocarbon Activation, Principles and Progress; VCH: New York, 1990. (j) Bergman, R. G. J. Organomet. Chem. 1990, 400, 273. (k) Bergman, R. G. Adv. Chem. Ser. 1992, 230, 211. (l) Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Science 1992, 255, 315. (m) Crabtree, R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 789. (n) Schroder, D.; Schwarz, H. Ibid. 1995, 34, 1937. (o) Lees, A. J.; Purwoko, A. A. Coord. Chem. Rev. 1994, 132, 155. (p) Amdtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
- (1995) Acc. Chem. Res. , vol.28 , pp. 154
- Amdtsen, B.A.¹ Bergman, R.G.² Mobley, T.A.³ Peterson, T.H.⁴

17
- 0003307992
- (a) Oliver, A. J.; Graham, W. A. G. Inorg. Chem. 1971, 10, 1.
- (1971) Inorg. Chem. , vol.10 , pp. 1
- Oliver, A.J.¹ Graham, W.A.G.²

18
- 33845554568
- (b) Janowicz, A. H.; Bergman, R. G. J. Am. Chem. Soc. 1982, 104, 352.
- (1982) J. Am. Chem. Soc. , vol.104 , pp. 352
- Janowicz, A.H.¹ Bergman, R.G.²

19
- 0242524722
- (c) Hoyano, J. K.; Graham, W. A. G. Ibid. 1982, 104, 3723.
- (1982) J. Am. Chem. Soc. , vol.104 , pp. 3723
- Hoyano, J.K.¹ Graham, W.A.G.²

20
- 0001321140
- (d) Jones, W. D.; Feher, F. Ibid. 1982, 104, 4240.
- (1982) J. Am. Chem. Soc. , vol.104 , pp. 4240
- Jones, W.D.¹ Feher, F.²

21
- 0020766699
- (e) Janowicz, A. H.; Bergman, R. G. Ibid. 1983, 105, 3929.
- (1983) J. Am. Chem. Soc. , vol.105 , pp. 3929
- Janowicz, A.H.¹ Bergman, R.G.²

22
- 33845551136
- (f) Hoyano, J. K.; McMaster, A. D.; Graham, W. A. Ibid. 1983, 105, 7190.
- (1983) J. Am. Chem. Soc. , vol.105 , pp. 7190
- Hoyano, J.K.¹ McMaster, A.D.² Graham, W.A.³

23
- 0001024680
- (g) Jones, W. D.; Feher, F. J. Organometallics 1983, 2, 562.
- (1983) Organometallics , vol.2 , pp. 562
- Jones, W.D.¹ Feher, F.J.²

24
- 33845470366
- (h) Periana, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 7272.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 7272
- Periana, R.A.¹ Bergman, R.G.²

25
- 33845469339
- (i) Jones, W. D.; Feher, F. J. Ibid, 1984, 106, 1650.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 1650
- Jones, W.D.¹ Feher, F.J.²

26
- 37049102071
- (j) Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Hoyano, J. K.; McMaster, A. D. J. Chem. Soc., Chem. Commun. 1984, 624.
- (1984) J. Chem. Soc., Chem. Commun. , pp. 624
- Rest, A.J.¹ Whitwell, I.² Graham, W.A.G.³ Hoyano, J.K.⁴ McMaster, A.D.⁵

27
- 33845470463
- (k) Wax, M. J.; Stryker, J. M.; Buchanan, J. M.; Caroline, A. K.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 1121.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 1121
- Wax, M.J.¹ Stryker, J.M.² Buchanan, J.M.³ Caroline, A.K.⁴ Bergman, R.G.⁵

28
- 0000452534
- (l) Gilbert, T. M.; Bergman, R. G. Ibid, 1985, 107, 3502.
- (1985) J. Am. Chem. Soc. , vol.107 , pp. 3502
- Gilbert, T.M.¹ Bergman, R.G.²

29
- 0000276797
- (m) McGhee, W. D.; Bergman, R. G. Ibid. 1986, 108, 5621.
- (1986) J. Am. Chem. Soc. , vol.108 , pp. 5621
- McGhee, W.D.¹ Bergman, R.G.²

30
- 0039086000
- (n) Haddleton, D. M. J. Organomet. Chem. 1986, 311, C21.
- (1986) J. Organomet. Chem. , vol.311
- Haddleton, D.M.¹

31
- 33845282616
- (a) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. S. J. Am. Chem. Soc. 1987, 109, 3143.
- (1987) J. Am. Chem. Soc. , vol.109 , pp. 3143
- Nolan, S.P.¹ Hoff, C.D.² Stoutland, P.O.³ Newman, L.J.⁴ Buchanan, J.M.⁵ Bergman, R.G.⁶ Yang, G.K.⁷ Peters, K.S.⁸

32
- 0001648035
- (b) Marx, D. E.; Lees, A. J. Inorg. Chem. 1988, 27, 1121.
- (1988) Inorg. Chem. , vol.27 , pp. 1121
- Marx, D.E.¹ Lees, A.J.²

33
- 0000386909
- (c) Stoutland, P. O.; Bergman, R. G.; Nolan, S. P.; Hoff, C. D. Polyhedron 1988, 7, 1429.
- (1988) Polyhedron , vol.7 , pp. 1429
- Stoutland, P.O.¹ Bergman, R.G.² Nolan, S.P.³ Hoff, C.D.⁴

34
- 37049083582
- (d) Bloyce, P. E.; Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Holmes-Smith, R. Chem. Commun. 1988, 846.
- (1988) Chem. Commun. , pp. 846
- Bloyce, P.E.¹ Rest, A.J.² Whitwell, I.³ Graham, W.A.G.⁴ Holmes-Smith, R.⁵

35
- 0000530627
- (e) Bell, T. W.; Haddleton, D. M.; McCamley, A.; Partridge, M. G.; Perutz, R. N.; Willner, H. Ibid. 1990, 112, 9212.
- (1990) Chem. Commun. , vol.112 , pp. 9212
- Bell, T.W.¹ Haddleton, D.M.² McCamley, A.³ Partridge, M.G.⁴ Perutz, R.N.⁵ Willner, H.⁶

36
- 0002639090
- (f) Barrientos, C.; Ghosh, C. K.; Graham, W. A. G.; Thomas, M. J. J. Organomet. Chem. 1990, 394, C31.
- (1990) J. Organomet. Chem. , vol.394
- Barrientos, C.¹ Ghosh, C.K.² Graham, W.A.G.³ Thomas, M.J.⁴

37
- 0000532386
- (g) Weiller, B. H.; Wasserman, E. P.; Moore, C. B.; Bergman, R. G. Ibid. 1993, 115, 4326.
- (1993) J. Organomet. Chem. , vol.115 , pp. 4326
- Weiller, B.H.¹ Wasserman, E.P.² Moore, C.B.³ Bergman, R.G.⁴

38
- 3342954064
- (h) Burger, P.; Bergman, R. G. Ibid 1993, 115, 10462.
- (1993) J. Organomet. Chem. , vol.115 , pp. 10462
- Burger, P.¹ Bergman, R.G.²

39
- 0028493481
- (i) Schultz, R. H.; Bengali, A. A.; Tauber, M. J.; Weiller, B. H.; Wasserman, E. P.; Kyle, K. R.; Moore, C. B.; Bergman, R. G. Ibid. 1994, 116, 7369.
- (1994) J. Organomet. Chem. , vol.116 , pp. 7369
- Schultz, R.H.¹ Bengali, A.A.² Tauber, M.J.³ Weiller, B.H.⁴ Wasserman, E.P.⁵ Kyle, K.R.⁶ Moore, C.B.⁷ Bergman, R.G.⁸

40
- 0029556637
- (j) Veltheer, J. E.; Burger, P.; Bergman, R. G. Ibid. 1995, 117, 12478.
- (1995) J. Organomet. Chem. , vol.117 , pp. 12478
- Veltheer, J.E.¹ Burger, P.² Bergman, R.G.³

41
- 3342940245
- (k) Selmeczy, A. D.; Jones, W. D.; Osman, R.; Perutz, R. N. Organometallics 1995, 14, 5685.
- (1995) Organometallics , vol.14 , pp. 5685
- Selmeczy, A.D.¹ Jones, W.D.² Osman, R.³ Perutz, R.N.⁴

42
- 0000931719
- (l) Arndtsem, B. A.; Bergman, R. G. J. Organomet. Chem. 1995, 504, 143.
- (1995) J. Organomet. Chem. , vol.504 , pp. 143
- Arndtsem, B.A.¹ Bergman, R.G.²

43
- 0029985231
- (m) Bromberg, S. E.; Lian, T.; Bergmen, R. G.; Harris, C. B. J. Am. Chem. Soc. 1996, 118, 2069.
- (1996) J. Am. Chem. Soc. , vol.118 , pp. 2069
- Bromberg, S.E.¹ Lian, T.² Bergmen, R.G.³ Harris, C.B.⁴

44
- 0042540974
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1984) J. Am. Chem. Soc. , vol.106 , pp. 2006
- Saillard, J.-Y.¹ Hoffmann, R.²

45
- 0024784225
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1989) J. Am. Chem. Soc. , vol.111 , pp. 9177
- Ziegler, T.¹ Tschinke, V.² Fan, L.³ Becke, A.D.⁴

46
- 0000854022
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1993) Organometallics , vol.12 , pp. 3118
- Song, J.¹ Hall, M.B.²

47
- 0000100168
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 799
- Musaev, D.G.¹ Morokuma, K.²

48
- 0029962350
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1996) J. Am. Chem. Soc. , vol.118 , pp. 1487
- Siegbahn, P.E.M.¹

49
- 0001522219
- For theoretical works, see: (a) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. (b) Ziegler, T.; Tschinke, V.; Fan, L.; Becke, A. D. Ibid. 1989, 111, 9177. (c) Song, J.; Hall, M. B. Organometallics 1993, 12, 3118. (d) Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1995, 117, 799. (e) Siegbahn, P. E. M. Ibid. 1996, 118, 1487. (f) Jimenez-Catano, R.; Hall, M. B. Organometallics 1996, 15, 1889.
- (1996) Organometallics , vol.15 , pp. 1889
- Jimenez-Catano, R.¹ Hall, M.B.²

50
- 0001321318
- Hoffmann, P.; Padmanabhan, M. Organometallics 1983, 2, 1273.
- (1983) Organometallics , vol.2 , pp. 1273
- Hoffmann, P.¹ Padmanabhan, M.²

51
- 0000277903
- Silrestre, J.; Calhorda, M. J.; Hoffman, R.; Stoutland, P. O.; Bergman, R. G. Organometallics 1986, 5, 1841.
- (1986) Organometallics , vol.5 , pp. 1841
- Silrestre, J.¹ Calhorda, M.J.² Hoffman, R.³ Stoutland, P.O.⁴ Bergman, R.G.⁵

52
- 0001381215
- (a) Bach, R. D.; Andres, J. L.; Su, M.-D.; McDouall, J. J. W. J. Am. Chem. Soc. 1993, 115, 5768.
- (1993) J. Am. Chem. Soc. , vol.115 , pp. 5768
- Bach, R.D.¹ Andres, J.L.² Su, M.-D.³ McDouall, J.J.W.⁴

53
- 0000441850
- (b) Bach, R. D.; Su, M.-D.; Aldabagh, E.; Andres, J. L.; Schlegel, H. B. Ibid. 1993, 115, 10237.
- (1993) J. Am. Chem. Soc. , vol.115 , pp. 10237
- Bach, R.D.¹ Su, M.-D.² Aldabagh, E.³ Andres, J.L.⁴ Schlegel, H.B.⁵

54
- 0001732270
- (c) Bach, R. D.; Su, M.-D. Ibid. 1994, 116, 10103.
- (1994) J. Am. Chem. Soc. , vol.116 , pp. 10103
- Bach, R.D.¹ Su, M.-D.²

55
- 0003620473
- Academic: New York
- (a) For a discussion, see: Jorgensen, W. L.; Salem, L. The Organic Chemist's Book of Orbitals; Academic: New York, 1973.
- (1973) The Organic Chemist's Book of Orbitals
- Jorgensen, W.L.¹ Salem, L.²

56
- 0001361113
- (b) Meredith C.; Hamilton, T. P.; Schaefer, H. F., III. J. Phys. Chem. 1992, 96, 9250.
- (1992) J. Phys. Chem. , vol.96 , pp. 9250
- Meredith, C.¹ Hamilton, T.P.² Schaefer III, H.F.³

57
- 85086526395
- note
- 10) to describe the reaction trajectory and define the axis of attack of the valence orbital on the central metal.

58
- 84985520810
- Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1982, 21, 711.
- (1982) Angew. Chem., Int. Ed. Engl. , vol.21 , pp. 711
- Hoffmann, R.¹

59
- 33845282744
- (a) Sosa, C.; Schlegel, H. B. J. Am. Chem. Soc. 1987, 109, 4193.
- (1987) J. Am. Chem. Soc. , vol.109 , pp. 4193
- Sosa, C.¹ Schlegel, H.B.²

60
- 33845281259
- (b) Ibid. 1987, 109, 7007.
- (1987) J. Am. Chem. Soc. , vol.109 , pp. 7007

61
- 33745770836
- (a) Hay, J. P.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.
- (1985) J. Chem. Phys. , vol.82 , pp. 270
- Hay, J.P.¹ Wadt, W.R.²

62
- 0006073669
- (b) Ibid. 1985, 82, 284.
- (1985) J. Chem. Phys. , vol.82 , pp. 284

63
- 27344448074
- Hay, J. P.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299.
- (1985) J. Chem. Phys. , vol.82 , pp. 299
- Hay, J.P.¹ Wadt, W.R.²

64
- 0003568278
- Schafer, H. F., III, Ed.; Plenum: New York
- For the first row atoms: Dunning, T. H.; Hay, P. J. Modern Theoretical Chemistry; Schafer, H. F., III, Ed.; Plenum: New York, 1977; p 1.
- (1977) Modern Theoretical Chemistry , pp. 1
- Dunning, T.H.¹ Hay, P.J.²

65
- 36849140788
- For the hydrogen atom: Huzinaga, S. J. Chem. Phys. 1965, 42, 1293.
- (1965) J. Chem. Phys. , vol.42 , pp. 1293
- Huzinaga, S.¹

66
- 0004133516
- Gaussian, Inc., Pittsburgh, PA
- Molecular orbital calculations were carried out using the Gaussian 92 program system utilizing gradient geometry optimization. Gaussian 92, Revision C: M. J. Frisch, G. W. Trucks, M. Head-Gordon, P. M. W. Gill, M. W. Wong, J. B. Foresman, B. G. Johnson, H. B. Schlegel, M. A. Robb, E. S. Replogle, R. Gomperts, J. L. Andres, K. Raghavachari, J. S. Binkley, C. Gonzalez, R. L. Martin, D. J. Fox, D. J. Defrees, J. Baker, J. J. P. Stewart, and J. A. Pople, Gaussian, Inc., Pittsburgh, PA, 1992.
- (1992) Gaussian 92, Revision C
- Frisch, M.J.¹ Trucks, G.W.² Head-Gordon, M.³ Gill, P.M.W.⁴ Wong, M.W.⁵ Foresman, J.B.⁶ Johnson, B.G.⁷ Schlegel, H.B.⁸ Robb, M.A.⁹ Replogle, E.S.¹⁰ Gomperts, R.¹¹ Andres, J.L.¹² Raghavachari, K.¹³ Binkley, J.S.¹⁴ Gonzalez, C.¹⁵ Martin, R.L.¹⁶ Fox, D.J.¹⁷ Defrees, D.J.¹⁸ Baker, J.¹⁹ Stewart, J.J.P.²⁰ Pople, J.A.²¹ more..

67
- 3342877724
- in press
- A similar study, sees: Su, M.-D.; Chu, S.-Y. Organometallics, in press.
- Organometallics
- Su, M.-D.¹ Chu, S.-Y.²

68
- 0000585011
- (a) Su, M.-D. Chem. Phys. Lett. 1995, 237, 317.
- (1995) Chem. Phys. Lett. , vol.237 , pp. 317
- Su, M.-D.¹

69
- 33751155226
- (b) Su, M.-D. J. Org. Chem. 1995, 60, 6621.
- (1995) J. Org. Chem. , vol.60 , pp. 6621
- Su, M.-D.¹

70
- 0001492432
- (c) Su, M.-D. J. Phys. Chem. 1996, 100, 4339.
- (1996) J. Phys. Chem. , vol.100 , pp. 4339
- Su, M.-D.¹

71
- 0000180213
- (d) Su, M.-D. Chem. Phys. 1996, 205, 277.
- (1996) Chem. Phys. , vol.205 , pp. 277
- Su, M.-D.¹

72
- 0001122131
- (d) Su, M.-D. J. Org. Chem. 1996, 61, 3080.
- (1996) J. Org. Chem. , vol.61 , pp. 3080
- Su, M.-D.¹

73
- 37049084467
- However, this prediction cannot apply to the CpCoL systems. For theoretical works, see ref 4e. For experimental works, see: (a) Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Hoyano, J. K.; McMaster, A. D J. Chem. Soc., Dalton Trans. 1987, 1181. (b) Janowicz, A. H.; Bryndza, H. E.; Bergman, R. G. J. Am. Chem. Soc. 1981, 103, 1516. (c) Wasserman, E. P.; Bergman, R. G.; Moore, C. B. ibid. 1988, 110, 6076. (d) Bengali, A. A.; Bergman, R. G.; Moore, C. B. Ibid. 1995, 117, 3879. Also see ref 28.
- (1987) J. Chem. Soc., Dalton Trans. , pp. 1181
- Rest, A.J.¹ Whitwell, I.² Graham, W.A.G.³ Hoyano, J.K.⁴ McMaster, A.D.⁵

74
- 0001105229
- However, this prediction cannot apply to the CpCoL systems. For theoretical works, see ref 4e. For experimental works, see: (a) Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Hoyano, J. K.; McMaster, A. D J. Chem. Soc., Dalton Trans. 1987, 1181. (b) Janowicz, A. H.; Bryndza, H. E.; Bergman, R. G. J. Am. Chem. Soc. 1981, 103, 1516. (c) Wasserman, E. P.; Bergman, R. G.; Moore, C. B. ibid. 1988, 110, 6076. (d) Bengali, A. A.; Bergman, R. G.; Moore, C. B. Ibid. 1995, 117, 3879. Also see ref 28.
- (1981) J. Am. Chem. Soc. , vol.103 , pp. 1516
- Janowicz, A.H.¹ Bryndza, H.E.² Bergman, R.G.³

75
- 0344288159
- However, this prediction cannot apply to the CpCoL systems. For theoretical works, see ref 4e. For experimental works, see: (a) Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Hoyano, J. K.; McMaster, A. D J. Chem. Soc., Dalton Trans. 1987, 1181. (b) Janowicz, A. H.; Bryndza, H. E.; Bergman, R. G. J. Am. Chem. Soc. 1981, 103, 1516. (c) Wasserman, E. P.; Bergman, R. G.; Moore, C. B. ibid. 1988, 110, 6076. (d) Bengali, A. A.; Bergman, R. G.; Moore, C. B. Ibid. 1995, 117, 3879. Also see ref 28.
- (1988) J. Am. Chem. Soc. , vol.110 , pp. 6076
- Wasserman, E.P.¹ Bergman, R.G.² Moore, C.B.³

76
- 0029636407
- Also see ref 28
- However, this prediction cannot apply to the CpCoL systems. For theoretical works, see ref 4e. For experimental works, see: (a) Rest, A. J.; Whitwell, I.; Graham, W. A. G.; Hoyano, J. K.; McMaster, A. D J. Chem. Soc., Dalton Trans. 1987, 1181. (b) Janowicz, A. H.; Bryndza, H. E.; Bergman, R. G. J. Am. Chem. Soc. 1981, 103, 1516. (c) Wasserman, E. P.; Bergman, R. G.; Moore, C. B. ibid. 1988, 110, 6076. (d) Bengali, A. A.; Bergman, R. G.; Moore, C. B. Ibid. 1995, 117, 3879. Also see ref 28.
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 3879
- Bengali, A.A.¹ Bergman, R.G.² Moore, C.B.³

77
- 4043136650
- note
- It must be noted that for real ligands, of course, σ-donating power and π-accepting power are always interrelated.

78
- 0004009372
- Witey-Interscience: New York, and references therein
- Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 3rd ed.; Witey-Interscience: New York, 1972; pp 683-701 and references therein.
- (1972) Advanced Inorganic Chemistry, 3rd Ed. , pp. 683-701
- Cotton, F.A.¹ Wilkinson, G.²

79
- 0001103544
- Koga, N.; Morokuma, K. J. Am. Chem. Soc. 1993, 115, 6883.
- (1993) J. Am. Chem. Soc. , vol.115 , pp. 6883
- Koga, N.¹ Morokuma, K.²

80
- 0001152063
- Su, M.-D. Inorg. Chem. 1995, 34, 3829.
- (1995) Inorg. Chem. , vol.34 , pp. 3829
- Su, M.-D.¹

81
- 0004105855
- John Wiley & Sons: New York
- (a) Shaik, S.; Schlegel, H. B.; Wolfe, S. Theoretical Aspects of Physical Organic Chemistry; John Wiley & Sons: New York, 1992.
- (1992) Theoretical Aspects of Physical Organic Chemistry
- Shaik, S.¹ Schlegel, H.B.² Wolfe, S.³

82
- 0003471868
- John Wiley & Sons: New York
- (b) Pross, A. Theoretical and Physical principles of Organic Reactivity, John Wiley & Sons: New York, 1995.
- (1995) Theoretical and Physical Principles of Organic Reactivity
- Pross, A.¹

83
- 5244245983
- Hammond, G. S. J. Am. Chem. Soc. 1954, 77, 334.
- (1954) J. Am. Chem. Soc. , vol.77 , pp. 334
- Hammond, G.S.¹

84
- 4043097027
- note
- At the MP2/LANL1DZ level, the linear relationship is y = 0.226x + 7.47.

85
- 4043074280
- note
- At the MP2/LANL1DZ level, the linear relationship is y′ = 0.889x - 22.4.

86
- 4043122615
- note
- 2) involved in Figure 8, in the CpCoL case, there could be three predominant configurations contributed to the total wave function Ψ, i.e., a closed-shell singlet, two open-shell triplet (so overall singlet), and an open-shell singlet. This study, however, is beyond the scope of the present work and will not be discussed here.

87
- 4043101205
- note
- Conversely, since reductive elimination involves the charge transfer from methane to metal, the electron-withdrawing L should stabilize the CpML compound and then allow such a reaction to proceed readily.

88
- 4043177791
- note
- Further work investigating the effect of the electronegativity of the ancillary ligand L on the reactivity of the CpML systems is underway.

89
- 0542395456
- Angelici, R. J. Acc. Chem. Res. 1995, 28, 51.
- (1995) Acc. Chem. Res. , vol.28 , pp. 51
- Angelici, R.J.¹

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