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The relevant thermodynamic data are: C-H 338 kJ/mol; C-F 552 kj/mol; C-O 446 kj/mole; and O-F 222 kJ/mol, which are taken from D.R. Lide, ed., in: Handbook of Chemistry and Physics, 72nd Ed. (CRC, Boston, 1991) pp. 9-105 and 9-106.
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2 is yielded and can be used for amine functionalization. For carboxylic functionalization, the relevant data are that all carboxylic groups do not absorb this spectral line but C-Br bonds will be broken by photolysis at 254 nm. All these photolysis characteristics can be found in: H. Okabe, Photochemistry of Small Molecules (Wiley, New York, 1978).
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Lau, W.M.1
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