Cationic homo- and copolymerization of fluorophosphoranimines as an ambient temperature synthetic route to poly(fluorophosphazenes), [N=PF(R)]n, with controlled architectures

Macromolecules

Volumn 30, Issue 11, 1997, Pages 3191-3196

  Nelson, James M ^a   Allcock, Harry R ^a   Manners, Ian ^b  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AGENTS; ATOMS; BLOCK COPOLYMERS; CATIONIC POLYMERIZATION; FLUORINE COMPOUNDS; MOLECULAR ORIENTATION; MOLECULAR WEIGHT; MONOMERS;

CATIONIC COPOLYMERIZATION; FLUOROPHOSPHORANIMINES; GRIGNARD REAGENTS; MONOMER TO INITIATOR RATIO; POLYFLUOROPHOSPHAZENES;

COPOLYMERIZATION;

EID: 0031548747     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961875u     Document Type: Article

References (33)

1. (a) Mark, J. E.; Allcock, H. R.; West, R. Inorganic Polymers; Prentice Hall: Englewood Cliffs, NJ. 1992.
2. (b) Allcock, H. R.; Klingenberg, E. H.; Macromolecules 1895, 28, 4351.
3. (c) Allcock, H. R.; Kim, C. Macromolecules 1991, 24, 2846.
4. (d) Allcock, H. R.; Dembek, A. A.; Kim, C.; Devine. R. L. S.; Shi, Y.; Steier, W. H.; Spangler, C. W. Macromolecules 1991, 24, 1000.
5. (e) Allcock, H. R. In Biodegradable Polymers as Drug Delivery Systems; Langer, R., Chasin. M., Eds.; Marcel Dekker: New York, 1990.
6. Honeyman, C. H.; Manners, I.; Morrissey, C. T.; Allcock, H. R. J. Am. Chem. Soc. 1995, 117, 7035.
7. Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I. Macromolecules 1996, 29, 7740.
8. Allcock, H. R.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I. Macromolecules 1997, 30, 50.
9. Allcock, H. R.; Reeves, S. D.; Nelson, J. M.; Crane, C. A. Macromolecules 1997, 30, 2213.
10. Nelson, J. M.; Allcock, H. R. Macromolecules 1997, 30, 1854.
11. Allcock, H. R.; Moore, G. Y. Macromolecules 1975, 8, 377.
12. Allcock, H. R.; Patterson, D. B.; Evans, T. L. J. Am. Chem. Soc. 1977, 99, 6095.
13. Allcock, H. R.; Patterson, D. B.; Evans, T. L. Macromolecules 1979, 12, 172.
14. Allcock, H. R.; Evans, T. L. J. Macro. Sci.-Chem. 1981, A16, 409.
15. Allcock, H. R.; Chu, C. T.-W. Macromolecules 1979, 12, 551.
16. Harris, P. J.; Desorcie, J. L.; Allcock, H. R. J. Chem. Soc., Chem. Commun. 1981, 852.
17. Allcock, H. R.; Evans, T. L.; Patterson, D. B. Macromolecules 1980, 13, 201.
18. Allcock, H. R.; McDonnell, G. S.; Desorcie, J. L. Macromolecules 1990, 23, 3873.
19. Allcock, H. R.; Desorcie, J. L.; Riding, G. H. Polyhedron 1987, 6, 119.
20. Allcock, H. R.; Lavin, K. D.; Riding, G. H.; Suszko, P. R.; Whittle, R. R. J. Am. Chem. Soc. 1984, 106, 2337.
21. Allcock, H. R.; Lavin, K. D.; Riding, G. H.; Whittle, R. R.; Parvez, M. Organometallics 1986, 5, 1626.
22. Allcock, H. R.; Lavin, K D.; Riding, G. H. Macromolecules 1985, 18, 1340.
23. Allcock, H. R.; Riding, G. H.; Manners, I.; Dodge, J. A.; McDonnell, G. S.; Desorcie, J. L. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1990, 31, 48.
24. Manners, I.; Riding, G. H.; Dodge, J. A.; Allcock, H. R. J. Am. Chem. Soc. 1988, 111, 3067.
25. Honeyman, C. H.; Lough, A. J.; Manners, I. Inorg. Chem. 1994, 33, 2988.
26. Wisian-Neilson, P.; Neilson, R. H.; Cowley, A. H. Inorg. Chem. 1977, 16, 1460.
27. Allcock, H. R.; Chu, C. T.-W. Macromolecules 1979, 12, 551.
28. Allcock, H. R.; Reeves, S. D.; Nelson, J. M. Manuscript in preparation.
29. Matyjaszewski, K.; Moore, M. K.; White, M. L. Macromolecules 1993, 26, 6741.
30. Neilson, R. H.; Hani, R.; Wisian-Neilson, P.; Meister, J. J.; Roy, A. K.; Hagnauer, G. L. Macromolecules 1987, 20, 910.
31. Matyjaszewski, K.; Montague, R.; Dauth, J.; Nuyken, O. J. Polym. Sci. A: Polym. Chem. 1992, 30, 813.
32. Allcock, H. R.; Kugel, R.; Valan, K. J. Inorg. Chem. 1966, 5, 1709.
33. Honeyman, C. H. Ph.D. Thesis; University of Toronto, 1995.