The formation of dithionate during the iron(III)-catalysed autoxidation of sulfur(IV)-oxides

Atmospheric Environment

Volumn 31, Issue 24, 1997, Pages 4247-4249

  Brandt, Christian ^a   Van Eldik, Rudi ^b  

^a LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Dithionate; Sulfur(IV) oxidation; Transition metal ion catalysis

Indexed keywords

CATALYSIS; OXIDATION; OXIDES; PH;

DITHIONATE; IRON CATALYSED AUTOXIDATION; SULFUR OXIDATION; SULFUR OXIDES; TRANSITION METAL ION CATALYSIS;

ATMOSPHERIC CHEMISTRY;

CHROMIUM; COBALT; COPPER; DITHIONITE; FERRIC ION; MANGANESE; NICKEL; OXYGEN; SULFATE; SULFUR OXIDE;

AUTOXIDATION; DITHIONATE; PH; SULPHUR OXIDE;

ARTICLE; AUTOOXIDATION; CHEMICAL REACTION; PH; PRIORITY JOURNAL;

SIMIAN IMMUNODEFICIENCY VIRUS;

EID: 0031539274     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(97)00284-7     Document Type: Article

References (19)

1. Brandt, Ch., Fábián, I. and van Eldik, R. (1994) Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV)-oxides. Evidence for the redox cycling of iron in the presence of oxygen and modelling of the overall reaction mechanism. Inorganic Chemistry 33, 687-701.
2. Brandt, Ch. and van Eldik, R. (1995) Transition metalcatalyzed oxidation of sulfur(IV)-oxides. Atmospheric-relevant processes and mechanisms. Chemical Review 95, 119-190.
3. Brandt, Ch. and van Eldik, R. (1997) Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV)-oxides in aqueous solution. The influecne of pH, medium and aging, submitted.
4. Buxton, G. V., Salmon, G. A. and Wood, N. D. (1989) A pulse radiolysis study of the chemistry of oxysulfur radicals in aqueous solution. In Proceedings of the 5th European Symposium on Physico-Chemical Behaviour of Atmospheric Pollutants, eds. G. Restelli and Angeletti, pp. 245-250. Kluwer, Dordrecht. The Netherlands, 1989.
5. Buxton, G. V., McGowan, S., Salmon, G. A., Williams, J. E. and Wood, N. D. (1996) A study of spectra and reactivity of oxysulphur-radical anions involved in the chain oxidation of S(IV): a pulse and γ-radiolysis study. Atmospheric Environment 30, 2483-2493.
6. Carlyle, D. W. and King, E. L. (1970) The influence of sulfite ion upon the rate of aquation of various complexes of chromium(III) ion. The stability of sulfito-chromium(III) ion. Inorganic Chemistry 9, 2333-2339.
7. Dasgupta, P. K., Mitchell, P. A. and West, P. W. (1979) Study of transition metal ion-S(IV) systems. Atmospheric Environment 13, 775-782.
8. 3 in aqueous solution. Journal of Physical Chemistry 94, 2191-2198.
9. Eriksen, T. E. (1974) pH effects on the pulse radiolysis of deoxygenated aqueous solutions of sulphur dioxide. Journal of Chemical Society, Faraday Transactions I 70, 208-215.
10. 3. Journal of Physical Chemistry 93, 6371-6381.
11. 5 radicals in aqueous solutions. Journal Physical Chemistry 88, 5665-5669.
12. 5. Radiation Physics and Chemistry 33, 361-370.
13. Kraft, J. (1987) Mechanistische Untersuchungen zur katalytischen Oxidation von Schwefel(IV)-oxiden durch Fe(II)/Fe(III)-Komplexe in wässerigem Medium. Ph.D. thesis, University of Frankfurt/Main, Germany.
14. Littlejohn, D., Wang, Y., Chang, S.-G. (1993) Oxidation of aqueous sulfite ion by nitrogen dioxide. Environmental Science and Technology 27, 2162-2167.
15. Meyer, J. (1901) Ueber die Bildung der Dithionsäure. Ber. Deutsch. Chem. Gesellschaft 34, 3606-3610.
16. Pollard, F. H., Hanson, P. and Nickless, G. (1961) Chromatographic studies on the oxidation of sulphurous acid by ferric iron in aqueous acidic solution. Journal of Chromatography 5, 68-73.
17. Sato, T. and Okabe, T. (1977) Study on the formation and decomposition of dithionate. I. Formation of dithionate by the reaction of oxygen and sulfite in aqueous solution. Nippon Kagaku Kaishi (8), 1124-1130; cited after: Chemical Abstracts 87, 141906h.
18. Waygood, S. J. and McElroy, W. J. (1992) Spectroscopy and decay kinetics of the sulfite radical anion in aqueous solution. Journal of Chemical Society, Faraday Transactions 88, 1525-1530.
19. Zeck, O. F. and Carlyle, D. W. (1974) Electron transfer between sulfur(IV) and chloroiron(III) and chlorocopper(II) ions in aqueous chloride media. Formation of a sulfur dioxide complex with chlorocopper(I). Inorganic Chemistry 13, 34-38.