Formation of carbonyl sulfide (OCS) from carbon monoxide and sulfur vapor and applications to venus

Icarus

Volumn 130, Issue 2, 1997, Pages 495-504

  Hong, Yong ^a   Fegley Jr , Bruce ^a  

^a WASHINGTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031537436     PISSN: 00191035     EISSN: None     Source Type: Journal    
DOI: 10.1006/icar.1997.5824     Document Type: Article

References (36)

1. Bézard B., DeBergh C., Crisp D., Maillard J. P. The deep atmosphere of Venus revealed by high-resolution nightside spectra. Nature. 345:1990;508-511.
2. 2. Comm. Lunar Planet. Lab. 6:1967;199-200.
3. Deer W. A., Howie R. A., Zussman J. Rock-Forming Minerals. 1963;Wiley, New York.
4. Fegley B. Jr. Why pyrite is unstable on the surface of Venus. Icarus. 128:1997;474-479.
5. Fegley B. Jr., Treiman A. H. Chemistry of atmosphere-surface interactions on Venus and Mars. Venus and Mars: Atmospheres, Ionospheres, and Solar Wind Interactions. 1992;AGU, Washington. p. 7-71.
6. Fegley B. Jr., Lodders K., Treiman A. H., Klingelhöfer G. The rate of pyrite decomposition on the surface of Venus. Icarus. 115:1995;159-180.
7. Fegley B. Jr., Zolotov M. Yu., Lodders K. The oxidation state of the lower atmosphere and surface of Venus. Icarus. 125:1997;416-439.
8. Ferguson J. B. The equilibrium between carbon monoxide, carbon dioxide, sulfur dioxide and free sulfur. J. Amer. Chem. Soc. 40:1918;1626-1644.
9. Ferm R. J. The chemistry of carbonyl sulfide. Chem. Rev. 57:1957;621-640.
10. Ford P. G., Pettengill G. H. Venus topography and kilometer-scale slopes. J. Geophys. Res. 97:1992;13,103-13,114.
11. Gurvich L. V., Veyts I. V., Alcock C. B. Thermodynamic Properties of Individual Substances. 1989-1994;Hemisphere Publishing, New York.
12. Haber F. Thermodynamics of Technical Gas Reactions. 1908;Longmans, Green and Co. London.
13. Hong Y., Fegley B. Jr., Lodders K. Further Experimental Studies of Pyrite Chemical Weathering and Implications for the Venus Sulfur Cycle. EOS Trans AGU. 77:1996;F439-440.
14. Hong Y., Fegley B. Jr. The sulfur vapor pressure over pyrite on the surface of Venus. Planet. Space Sci. 1997a.
15. Hong Y., Fegley B. Jr. The formation of carbonyl sulfide (OCS) in Venus' lower atmosphere. Meteoritics Planet. Sci. 32:1997b;A61-9.
16. Krasnopolsky V. A. Photochemistry of the Atmospheres of Mars and Venus. 1986;Springer-Verlag, Berlin.
17. 22424. Icarus. 109:1994;58-78.
18. Lauretta D. S., Kremser D. T., Fegley B. Jr. The rate of iron sulfide formation in the solar nebula. Icarus. 122:1996;288-315.
19. Lewis G. N., Lacey W. N. The equilibrium between carbon oxysulfide, carbon monoxide and sulfur. J. Amer. Chem. Soc. 37:1915;1976-1983.
20. Lewis J. S. Venus: Atmospheric and lithospheric composition. Earth Planet. Sci. Lett. 10:1970;73-80.
21. Merten U., Bell W. E. The transpiration method. Margrave J. W. The Characterization of High Temperature Vapors. 1967;91-114 Wiley, New York.
22. Mukhin L. M., Gel'man B. G., Lamanov N. I., Mel'nikov V. V., Nenarokov D. F., Okhotnikov B. P., Rotin V. A., Khokhlov V. N. Gas chromatograph analysis of the chemical composition of the atmosphere of Venus by the landers of the Venera 13 and Venera 14 spacecraft. Cosmic. Res. 21:1983;168-172.
23. Pollack J. B., Dalton B., Grinspoon D. H., Wattson R. B., Freedman R., Crisp D., Allen D. A., Bézard B., DeBergh C., Giver L., Ma Q., Tipping R. Near-infrared light from Venus' nightside: A spectroscopic analysis. Icarus. 103:1993;1-42.
24. Prinn R. G. Venus: Composition and structure of the visible clouds. Science. 182:1973;1132-1135.
25. Prinn R. G. On the possible roles of gaseous sulfur and sulfanes in the atmosphere of Venus. Geophys. Res. Lett. 6:1979;807-810.
26. Prinn R. G. The photochemistry of the atmosphere of Venus. Levine J. S. The Photochemistry of Atmospheres. 1985;281-336 Academic Press, New York.
27. San'ko N. F. Gaseous sulfur in the venusian atmosphere. Cosmic Res. 18:1980;437-443.
28. Schwab G. M., Philinis J. Reactions of iron pyrite: Its thermal decomposition, reduction by hydrogen and air oxidation. J. Amer. Chem. Soc. 69:1947;2588-2596.
29. Seiff A., Schofield J. T., Klikore A. J., Taylor F. W., Limaye S. S., Revercomb H. E., Sromovsky L. A., Kerzhanovich V. I., Moroz V. I., Marov M. Ya. Models of the structure of the atmosphere of Venus from the surface to 100 km altitude. Kliore A. J., Moroz V. I., Keating G. M. The Venus International Reference Atmosphere. 1986;3-58 Pergamon, Oxford.
30. Stølen S., Grønvold F. Thermodynamics of point defects in monochalcogenides of iron, cobalt and nickel with NiAs-type structure. J. Phys. Chem. Solids. 48:1987;1213-1225.
31. Symonds R. B., Rose W. I., Bluth G. J. S., Gerlach T. M. Volcanic-gas studies: Methods, results, and applications. Carroll M. R., Holloway J. R. Volatiles in Magmas. 1994;1-66 Mineralogical Society of America, Washington.
32. Thompson F. C., Tilling N. The desulphurisation of iron pyrites. J. Soc. Chem. Ind. 43:1924;37T-46T.
33. Toulmin P. III, Barton P. B. Jr. A thermodynamic study of pyrite and pyrrhotite. Geochim. Cosmochim. Acta. 28:1964;641-671.
34. Von Zahn U., Kumar S., Prinn R. G. Composition of the Venus atmosphere. Hunten D. M., Colin L., Donahue T. M., Moroz V. I. Venus. 1983;299-430 Univ. of Arizona Press, Tucson.
35. Zolotov M. Yu. Sulfur-containing gases in the Venus atmosphere and stability of carbonates. Lunar Planet. Sci. 16:1985;942-943.
36. Zolotov M. Yu. A model for the thermal equilibrium of the surface Venusian atmosphere. Geochem. Intl. 11:1996;80-100.