Synthesis and structure of unprecedented carboxylate-bridged heteronuclear Cr(III)-Nd(III) complex

Chemistry Letters

Volumn , Issue 6, 1997, Pages 575-576

  Sakagami, Narumi ^a   Tsunekawa, Masayuki ^a   Konno, Takumi ^a   Okamoto, Ken Ichi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031518582     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.575     Document Type: Article

References (11)

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5. 20, F.W.=1605.68: C, 8.98; H, 3.36%. 1Br lost two water molecules of crystallization and turned into powder during elemental analysis.
6. -1 for MoKα radiation (λ=0.71069 Å). Measurements were carried out on a Rigaku AFC7S diffractometer. The structure was solved by a direct method and refined by a full-matrix least-square. Final R=0.050 and Rw=0.059 for 4396 observed reflections (I > 3.00σ(I)).
7. a) S. J. Brudenell, S. J. Crimp, J. K.E. Higgs, B. Moubaraki, K. S. Murray, and L. Spiccia, Inorg. Chim. Acta, 247, 35-41(1996);
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10. 2O: Triclinic, P1(#2), Z=1, a=9.018(3), b=9.409(3), c=10.575(5) Å, α=65.43(3), β=66.15(3), γ=61.30(3)°.
11. II I d-d transition region are shifted gradually. After 20 h, formation of polymer with very high charge was detected by column chromatography.