Large third-order nonlinear optical susceptibilities of multiply-bonded M2(pyphos)4 and M2Pd2Cl2(pyphos)4 (M = Cr, Mo; pyphos = 6-diphenylphosphino-2-pyridonate) by picosecond degenerate four-wave mixing method

Chemistry Letters

Volumn , Issue 5, 1997, Pages 411-412

  Mashima, Kazushi ^a   Tanaka, Mitsuhiro ^a   Kaneda, Yutaka ^a   Fukumoto, Atsushi ^a   Mizomoto, Hitoshi ^a   Tani, Kazuhide ^a   Nakano, Hiroshi ^a   Nakamura, Akira ^a   Sakaguchi, Toru ^b   Kamada, Kenji ^b   Ohta, Koji ^b  

^a OSAKA UNIVERSITY   (Japan)

^b OSAKA NATIONAL RESEARCH INSTITUTE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031514660     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.411     Document Type: Article

References (23)

1. J. L. Brédas, C. Adant, P. Tackx, and A. Persoons, Chem. Rev., 94, 243 and References cited therein (1994).
2. S. A. Jenekhe, W.-C. Chen, S. Lo, and S. R. Flom, Appl. Phys. Lett., 57, 126 (1990).
3. Y. Wang, J. Opt. Sci. Am., B8, 981 (1991).
4. D. F. Eaton, Science, 253, 281 (1991).
5. H. S. Nalwa, Advan. Mater., 5, 341 (1993).
6. S. Guha, C. C. Frazier, P. L. Porter, K. Kang, and S. E. Finberg, Optics Letters, 14, 952 (1989).
7. P. L. Porter, S. Guha, K. Kang, and C. C. Frazier, Polymer, 32, 1756 (1991).
8. N. J. Long, Angew. Chem., Int. Ed. Engl., 34, 21 and References cited therein (1995).
9. I. R. Whittall, M. G. Humphrey, D. C. R. Hockless, B. W. Skelton, and A. H. White, Organometallics, 14, 3970 (1995).
10. I. R. Whittall, M. G. Humphrey, M. Samoc, J. Swiatkiewicz, and B. Luther-Davies, Organometallics, 14, 5493 (1995).
11. Y. Wada and M. Yamashita, Jpn. J. Appl. Phys., 29, 2744 (1990).
12. Y. Iwasa, E. Funatsu, T. Hasegawa, T. Koda, and M. Yamashita,Appl. Phys. Lett., 59, 2219 (1991).
13. Y. Iwasa, E. Funatsu, T. Koda, M. Yamashita, H. Kobayashi, and K. Kubodera, Mol. Cryst. Liq. Cryst., 217, 37 (1992).
14. T. Kamata, T. Fukaya, H. Mizuno, H. Matsuda, and F. Mizukami, Chem. Phys. Lett., 221, 194 (1994).
15. K. Mashima, H. Nakano, and A. Nakamura, J. Am. Chem. Soc., 115, 11632 (1993).
16. K. Mashima, H. Nakano, and A. Nakamura, J. Am. Chem. Soc., 118, 9083 (1996).
17. -2. A streak camera (Hamamatsu C1587) was used as a photodetector. The vertically polarized output was split into three beams, which were temporally and spatially overlapped in a 1 mm thick cell filled with a sample. The data were obtained using the first single pulse to exclude any possible hysterisis.
18. b) T. Sakaguchi, Y. Shimizu, M. Miya, T. Fukumi, K. Ohta, and A. Nagata, Chem. Lett., 1992, 281.
19. 2+2)/3.
20. -31 esu) of the hyperpolarizability measured with picosecond pulses at 532 nm. For isotropic solution, the hyperpolarizability measured by OKE experiment can be directly compared with that by DFWM method. This result suggests that the major part of the hyperpolarizability measured at 532 nm should originate from non-resonant nonlinearity.
21. M. Nakano, I. Shigemoto, S. Yamada, and K. Yamaguchi, J. Chem. Phys., 103, 4175 (1995).
22. C. C. Frazier, S. Guha, W. P. Chen, M. Cockerham, P. L. Porter, E. A. Chauchard, and C. H. Lee, Polymer, 28, 553 (1987).
23. D. V. G. L. N. Rao, F. J. Aranda, J. F. Roach, and D. E. Remy, Appl. Phys. Lett., 58, 1241 (1991).