Synthesis and reactivity of S-sulfiliminothiazynes

Chemistry Letters

Volumn , Issue 2, 1997, Pages 153-154

  Ohkubo, Masanori ^a   Fujii, Takayoshi ^a   Ono, Shin ^a   Morita, Hiroyuki ^a   Yoshimura, Toshiaki ^a   Horn, Ernst ^b   Sato, Soichi ^b  

^a UNIVERSITY OF TOYAMA   (Japan)

^b UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031504070     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.153     Document Type: Article

References (14)

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9. 10 and S,S-diphenyl-N-bromosulfonediimine was prepared by treatment of the corresponding sulfonediimine with NBS.
10. N. Furukawa, K. Akutagawa, T. Yoshimura, T. Akasaka, and S. Oae, Synthesis, 1979, 289.
11. +.
12. -1, R=0.048 (Rw=0.044), unique reflections=4935. Selected bond lengths (Å) and angles (deg) : S(1)-N(1), 1.638(3); S(1)-C(1), 1.790(4); S(1)-C(7), 1.782(4); S(2)-N(1), 1.599(3); S(2)-N(2), 1.510(4); S(2)-C(13), 1.797(4); S(2)-C(15), 1.773(5); N(1)-S(1)-C(1), 102.5(2); N(1)-S(1)-C(7), 103.5(2); C(1)-S(1)-C(7), 100.2(2); N(1)-S(2)-N(2), 122.8(2); N(1)-S(2)-C(13), 96.3(2); N(1)-S(2)-C(15), 109.3(2); N(2)-S(2)-C(13), 117.8(2); N(2)-S(2)-C(15), 104.3(2); C(13)-S(2)-C(15), 105.1(2); S(1)-N(1)-S(2), 116.0(2)
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14. D. E. Zuccaro and J. D. McCullough, Z. Kristalligr., 112, 401 (1959).