Synthesis of novel polynuclear iron carbonyl complexes using the reactions of methylidenecarbenes with Fe3(CO)12

Chemistry Letters

Volumn , Issue 1, 1997, Pages 39-40

  Iyoda, Masahiko ^a   Yada, Tamiko ^a   Tashiro, Shin Ichiro ^a   Maeda, Hironori ^a   Yoshida, Masato ^a   Kuwatani, Yoshiyuki ^a  

^a TOKYO METROPOLITAN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031491527     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.39     Document Type: Article

References (10)

1. J. L. Davidson, in "Comprehensive Organometallic Chemistry," ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon Press, Oxford (1982), Vol. 4, Chap. 31.5, p. 615.
2. For a review, see: P. J. Stang, Acc. Chem. Res., 15, 348 (1982).
3. For mercury-carbenoids, see: D. Seyferth and D. Dagani, J. Organomet. Chem., 104, 145 (1976).
4. 3) δ 7.35-7.32 (m, 4H), 7.28-7.22 (m, 6H). 10b: red cryst. mp 119.5-120.5°C. 11b: black cryst., mp 158-159°C. 13b: dark red solid. 10c: red cryst., mp 92.5-93°C. 11c: black cryst., mp 168-169.5°C. 12c: orange cryst., mp 154.5-155°C. 15: red cryst., mp 104.5-105.5°C. 16: black cryst., 164.5-165.5°C. 17: orange cryst., mp 154.5-155°C.
5. Only the X-ray analysis of 13a together with short comments on the properties were reported: O. S. Mills and A. D. Redhouse, J. Chem. Soc. (A), 1968, 1282.
6. K. K. Joshi, J. Chem. Soc. (A), 1966, 594.
7. W. Hübel and E. H. Braye, J. Inorg. Nucl. Chem., 10, 250 (1959); P. Y. Degrève, J. Meunier-Piret, M. Van Meerssche, and P. Piret, Acta Cryst., 23, 119 (1967).
8. W. Hübel and E. H. Braye, J. Inorg. Nucl. Chem., 10, 250 (1959); P. Y. Degrève, J. Meunier-Piret, M. Van Meerssche, and P. Piret, Acta Cryst., 23, 119 (1967).
9. X-ray analysis of 10b and 11b: Y. Kuwatani, M. Yoshida, T. Yada, and M. Iyoda, to be published.
10. w = 0.025).