Crystal and molecular structure of [Cu(pyrimidine)4]2BF4

Journal of Chemical Crystallography

Volumn 27, Issue 5, 1997, Pages 279-282

  Novak, Brook ^a   Keller, Steven W ^b  

^a HARVEY MUDD COLLEGE   (United States)

^b UNIVERSITY OF MISSOURI   (United States)

Author keywords

Copper(II) compounds; Jahn Teller distortions; Weakly coordinating ligands

Indexed keywords

EID: 0031475473     PISSN: 10741542     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02575974     Document Type: Article

References (12)

1. Keller, S.W. Angew. Chem. Int. Ed. Engl. 1997, 36, 247.
2. Kubas, G. Inorg. Synth. 1979, 19, 90.
3. We assume that these needles are crystals of the extended solid reported in ref. 1.
4. There has been a recent report of a 1:2 complex of Cu(II) and 2-aminopyrimidine, but no structural data was given. Yao, X.; Zheng, L.; Xin, X. J. Sol. State. Chem. 1995, 117, 333.
5. Sheldrick, G.M. SHELXS-90; Program for Structure Solution; University of Goettingen: Germany, 1991.
6. (a). Sheldrick, G.M. SHELXL-93; Program for Structure Refinement; University of Goettingen: Germany, 1994.
7. (b). Barbour, L. RESZINS; Graphical Interface for SHELXL; University of Missouri-Columbia, 1996.
8. These carbons would correspond to the two "ortho" positions and the "para" position from the nitrogen bound to copper.
9. Haynes, S.S.; Rettig, S.J.; Sams, J.R.; Trotter, J.; Thompson, R. C. Inorg. Chem. 1988, 27, 1237.
10. Bondi, A. J. Phys. Chem. 1964, 68, 441.
11. Keller, S.W.; Carlson, V.A.; Sanford, D.S.; Stacy, A.M.; Alario-Franco, M; Kwei, G.H. J. Am. Chem. Soc. 1994, 116, 8070.
12. Kramer, G.; Jansen, M. J. Sol. St. Chem. 1995, 114, 206.