Strength of solid acids and acids in solution. Enhancement of acidity of centers on solid surfaces by anion stabilizing solvents and its consequence for catalysis

Journal of the American Chemical Society

Volumn 119, Issue 49, 1997, Pages 11826-11831

  Fǎrcaşiu, Dan ^a,e   Ghenciu, Anca ^b   Marino, Gaye ^c   Rose, Kenneth D ^b,d  

^a University of Pittsburgh   (United States)

^b EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

^c UNIVERSITY OF PITTSBURGH   (United States)

^d UNION CARBIDE CORPORATION   (United States)

^e MERCK RESEARCH LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION STABILIZING SOLVENTS; CARBOCATIONIC REACTIONS; HEXAMETHYLBENZENE; TRIFLUOROMETHANESULFONIC ACID;

BENZENE; CATALYSIS; ION EXCHANGE; PH; POLYMERS; SOLUTIONS; SOLVENTS; SULFURIC ACID; SURFACES;

ORGANIC ACIDS;

ACID; POLYMER; POLYSTYRENESULFONIC ACID;

ARTICLE; CATALYST; CRYSTAL; ION EXCHANGE; LIQUID; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; PHASE SEPARATION;

EID: 0031452398     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9716158     Document Type: Article

References (4)

1. Fǎrcaşiu, D.; Marino, G.; Hsu, C. S. J. Org. Chem. 1994, 59, 163.
2. (a) Cristol, S. J.; Morrill, T. C.; Sanchez, R. A. J. Org. Chem. 1966, 31, 2719, 2733.
3. (b) Fahey, R. C. Top. Stereochem. 1969, 3, 253.
4. Deno, N. C. In Carbonium Ions; Olah, G. A., Schleyer, P v. R., Eds.; Wiley-Interscience: New York, 1970; Vol. 2, Chapter 18.