IR spectroscopy of hemimorphite between 82 and 373 K and optical evidence for a low-temperature phase transition

European Journal of Mineralogy

Volumn 9, Issue 4, 1997, Pages 793-802

  Libowitzky, Eugen ^a,b   Rossman, George R ^b  

^a UNIVERSITY OF VIENNA   (Austria)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Hemimorphite; Hydroxide; Infrared spectroscopy; Phase transition; Water

Indexed keywords

CRYSTAL ORIENTATION; INFRARED SPECTROSCOPY; PHASE TRANSITIONS; TEMPERATURE; WATER;

FACTOR GROUP ANALYSIS; HEMIMORPHITE; HYDROXIDE; LOW TEMPERATURE PHASE TRANSITIONS; O-H STRETCHING BANDS; POLARIZED IR ABSORPTION; SECOND-ORDER PHASE TRANSITION; STRUCTURE REFINEMENTS;

MOLECULES;

HEMIMORPHITE; INFRARED SPECTROSCOPY; PHASE TRANSITION;

EID: 0031443104     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/ejm/9/4/0793     Document Type: Article

References (33)

1. Adams. D.M. & Newton, D.C. (1970): Tables for factor group and point group analysis, Beckman-RIIC Limited, Croydon, England.
2. 2 in the structural cavities of cordierite. an optical and X-ray single-crystal study. Phys. Chem. Minerals, 12, 233-245.
3. Armbruster, T., Libowiuky, E., Diamond, L., Auernhammer, M., Bauerhansl, P., Hoffmann, C., Irran, E., Kurka, A., Rosenstingl, H. (1994): Crystal chemistry and optics of bazzite from Furkabasistunnel (Switzerland). Mineral. Petrol., 52, 113-126.
4. Barclay, G.A. & Cox, E.G. (1960): The structure of hemimorphite. Z. Krist., 113, 23-29.
5. Child. M.S. & Halonen L. (1984): Overtone frequencies and intensities in the local mode picture. Adv. Chem. Phys., 57, 1-58.
6. Cooper, B.J., Gibbs, G.V., Ross, F.K. (1981): The effects of heating and dehydration on the crystal structure of hemimorphite up to 600°C. Z Krist.. 156, 305-321.
7. Cotton, F.A. (1990): Chemical applications of group theory (3rd ed.). Wiley, New York.
8. Faust. G.T. (1951): Thermal analysis and X-ray studies of sauconite and some zinc minerals of the same paragenetic association. Am. Mineral., 36, 795-822.
9. Franks, F. (ed.) (1973): Water - A Comprehensive Treatise, Vol. 2. Plenum Press, New York.
10. Goldman, D.S., Rossman, G.R., Dollase, W.A. (1977): Channel constituents in cordierite. Am. Mineral., 62, 1144-1157.
11. Graener, H. (1991): Anharmonicity and overtone spectra of OH stretching vibrations. J. Phys. Chem., 95, 3450-3453.
12. Hill, R.J., Gibbs, G.V., Craig, J.R., Ross, F.K., Williams, J.M. (1977): A neutron-diffraction study of hemimorphite. Z. Krist., 146, 241-259.
13. 5). Z. Krist., 83, 1-8.
14. Klein, C. & Hurlbut, C.S. (1993): Manual of mineralogy, (21st ed.). Wiley, New York.
15. 3. Am. Mineral., 72, 756-765.
16. Libowitzky, E. & Armbruster, T. (1995): Low-temperature phase transitions and the role of hydrogen bonds in lawsonite. Am. Mineral., 80, 1277-1285.
17. Libowitzky, E. & Rossman, G.R. (1996): FTIR spectroscopy of lawsonite between 82 and 325 K. Am. Mineral., 81, 1080-1091.
18. Lutz, H.D. (1995): Hydroxide ions in condensed materials - correlation of spectroscopic and structural data. Struct. Bond., 82, 85-103.
19. McDonald, W.S. & Cruickshank, D.W.J. (1967): Refinement of the structure of hemimorphite. Z. Krist., 124, 180-191.
20. Mikenda, W. (1986): Stretching frequency versus bond distance correlation of O-D(H)⋯Y (Y = N, O, S, Se, Cl, Br, I) hydrogen bonds in solid hydrates. J. Molec. Struct., 147, 1-15.
21. Mills, I.M. & Robiette, A.G. (1985): On the relationship of normal-modes to local modes in molecular vibrations. Molec. Phys., 56, 743-765.
22. Nakamoto, K., Margoshes, M., Rundle, R.E. (1955) Stretching frequencies as a function of distances in hydrogen bonds. J. Am. Chem. Soc., 77, 6480-6486.
23. Novak, A. (1974): Hydrogen bonding in solids. Correlation of spectroscopic and crystallographic data. Struct. Bond., 18, 177-216.
24. Paterson, M.S. (1982): The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials. Bull. Minéral., 105, 20-29.
25. Rossman, G.R. (1988): Vibrational spectroscopy of hydrous components. In Hawthorne, F.C. (ed.): Spectroscopic methods in mineralogy and geology. Reviews in Mineralogy, 18, 193-206.
26. 2O. Econ. Geol., 51, 432-443.
27. Sandorfy, C. (1976): Anharmonicity and hydrogen bonding. In Schuster, P. et al. (eds.): The hydrogen bond - Recent developments in theory and experiments, Vol. II, Structure and spectroscopy, 613-645 North-Holland, Amsterdam.
28. Schiffer, J., Intenzo, M., Hayward, P., Calabrese, C. (1976): The FS correlation and a systematic analysis of the stretching absorptions of water in the condensed state. J. Chem. Phys., 64, 3014-3020.
29. Takeuchi, Y, Sasaki, S., Joswig, W., Fuess, H. (1978): X-ray and neutron diffraction study of hemimorphite. Proc. Japan Acad., Ser. B, 54, 577-582.
30. Taylor, H.F. (1962): The dehydration of hemimorphite. Am. Mineral, 47, 932-944.
31. Wilson, E.B., Decius, J.C., Cross, P.C. (1980): Molecular vibrations. Dover Publications Inc., New York.
32. 2O in cordierite observed with quasi-elastic neutron-scattering. Am. Mineral.. 79, 801-808.
33. Wood, D.L. & Nassau, K. (1967): Infrared spectrum of foreign molecules in beryl. J. Chem. Phys., 47, 2220-2228.