Aqueous Si-oxalate complexing, oxalate adsorption onto quartz, and the effect of oxalate upon quartz dissolution rates

Chemical Geology

Volumn 140, Issue 1-2, 1997, Pages 1-7

  Poulson, Simon R ^a   Drever, James I ^a   Stillings, Lisa L ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

Adsorption; Complexing; Dissolution rate; Oxalate; Quartz

Indexed keywords

ADSORPTION; COMPLEXING; DISSOLUTION RATE; OXALATE; QUARTZ;

EID: 0031436605     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(96)00177-5     Document Type: Article

References (29)

1. Allison, J.D., Brown, D.S. and Novo-Gradac, K.J., 1991. MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems. U.S. Environ. Prot. Agency, EPA/600/3-91/021.
2. Bavestrello, G., Arillo, A., Benatti, U., Cerrano, C., Cattaneo-Vietti, R., Cortesogno, L., Gaggero, L., Giovine, M., Tonetti, M. and Sarà, M., 1995. Quartz dissolution by the sponge Chondrosia reniformis (Porifera, Demospongiae). Nature, 378: 374-376.
3. Bennett, P.C., 1991. Quartz dissolution in organic-rich aqueous systems. Geochim. Cosmochim. Acta, 55: 1781-1797.
4. Bennett, P.C. and Siegel, D.I., 1987. Increased solubility of quartz in water due to complexing by organic compounds. Nature, 326: 684-686.
5. Bennett, P.C. and Casey, W.J., 1994. Chemistry and mechanisms of low-temperature dissolution of silicates by organic acids. In: E.D. Pittman and M.D. Lewan (Editors), Organic Acids in Geological Processes. Springer-Verlag, New York, pp. 162-200.
6. Bennett, P.C., Melcer, M.E., Siegel, D.I. and Hassett, J.P., 1988. The dissolution of quartz in dilute aqueous solutions of organic acids at 25°C. Geochim. Cosmochim. Acta, 52: 1521-1530.
7. Bennett, P.C., Siegel, D.I., Hill, B.M. and Glaser, P.H., 1991. Fate of silicate materials in a peat bog. Geology, 19: 328-331.
8. Bennett, P.C., Siegel, D.I., Baedecker, M.J. and Huit, M.F., 1993. Crude oil in a shallow sand and gravel aquifer - I. Hydrogeology and inorganic geochemistry. Appl. Geochem., 8: 529-549.
9. Blum, A.E. and Stillings, L.L., 1995. Feldspar dissolution kinetics. In: A.F. White and S.L. Brantley (Editors), Chemical Weathering Rates of Silicate Minerals. Mineral. Soc. Am., Washington DC, Rev. Mineral. 31, pp. 291-351.
10. Dove, P.M., 1994. The dissolution kinetics of quartz in sodium chloride solutions at 25° to 300°C. Am. J. Sci., 294: 665-712.
11. Dove, P.M. and Crerar, D.A., 1990. Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor. Geochim. Cosmochim. Acta, 54: 955-969.
12. Dove, P.M. and Elston, S.F., 1992. Dissolution kinetics of quartz in sodium chloride solutions: analysis of existing data and a rate model for 25°C. Geochim. Cosmochim. Acta, 56: 4147-4156.
13. Drever, J.I., 1994. The effect of land plants on weathering rates of silicate minerals. Geochim. Cosmochim. Acta, 58: 2325-2332.
14. Drever, J.I. and Vance, G.F., 1994. Role of soil organic acids in mineral weathering processes. In: E.D. Pittman and M.D. Lewan (Editors), Organic Acids in Geological Processes. Springer-Verlag, New York, pp. 138-161.
15. Fein, J.B. and Hestrin, J.E., 1994. Experimental studies of oxalate complexation at 80°C: gibbsite, amorphous silica, and quartz solubilities in oxalate-bearing fluids. Geochim. Cosmochim. Acta, 58: 4817-4829.
16. Franklin, S.P., Hajash, Jr., A., Dewers, T.A. and Tieh, T.T., 1994. The role of carboxylic acids in albite and quartz dissolution: An experimental study under diagenetic conditions. Geochim. Cosmochim. Acta, 58: 4259-4273.
17. Hallbauer, D.K. and Jahns, H.M., 1977. Attack of lichens on quartzitic rock surfaces. Lichenologist, 9: 119-122.
18. Hiebert, F. and Bennett, P.C., 1992. Microbial control of silicate weathering in organic-rich ground water. Science, 258: 278-281.
19. Marley, N.A., Bennett, P., Janecky, D.R. and Gaffney, J.S., 1989. Spectroscopic evidence for organic diacid complexation with dissolved silica in aqueous systems. I. Oxalic acid. Org. Geochem., 14: 525-528.
20. Martell, A.E. and Smith, R.M. 1983. Critical stability constants. Volume 3: Other organic ligands. Plenum Press, New York, 495 pp.
21. Öhman, L.-O., Nordin, A., Sedeh, I.F. and Sjöberg, S., 1991. Equilibrium and structural studies of silicon (IV) and aluminum (III) in aqueous solution. 28. Formation of soluble silicic acid-ligand complexes as studied by potentiometric and solubility measurements. Acta Chem. Scand., 45: 335-341.
22. Schindler, P.W., 1981. Surface complexes at oxide-water interfaces. In: M.A. Anderson and A.J. Rubin (Editors), Adsorption of Inorganics at Solid-Liquid Interfaces. Ann Arbor Science, Ann Arbor, Michigan, pp. 1-49.
23. Smith, R.M. and Martell, A.E., 1989. Critical stability constants. Vol. 6: Second supplement. Plenum Press, New York, 662pp.
24. Stillings, L.L., Drever, J.I., Brantley, S.L., Sun, Y. and Oxburgh, R., 1996. Rates of feldspar dissolution at pH 3-7 with 0-8 mM oxalic acid. Chem. Geol., 132: 79-89.
25. Stumm, W., 1992. Chemistry of the solid-water interface. Wiley-Interscience, New York, 428 pp.
26. Stumm, W. and Morgan, J.J., 1996. Aquatic chemistry: chemical equilibria and rates in natural waters (3rd Edn.) Wiley, New York, 1022 pp.
27. Syers, J.K. and Iskandar, I.K., 1973. Pedogenetic significance of lichens. In: V. Ahmadjian and M.E. Hale (Editors), The Lichens. Academic Press, New York, pp. 225-248.
28. Tait, C.D., Janecky, D.R., Clark, D.L., Ekberg, S.A., Dixon, P.R. and Bennett, P.C., 1997. Experimental evidence against inner-sphere coordination complexes between silica and simple organic acids, in prep.
29. Welch, S.A. and Ullman, W.J., 1996. Feldpar dissolution in acidic and organic solutions: Compositional and pH dependence of dissolution rate. Geochim. Cosmochim. Acta, 60: 2939-2948.