Adsorption of benzyltrimethylammonium and benzyltriethylammonium on montmorillonite: Experimental studies and model calculations

Clays and Clay Minerals

Volumn 45, Issue 6, 1997, Pages 834-841

  Polubesova, Tamara ^a   Rytwo, Giora ^a,b   Nir, Shlomo ^a   Serban, Carina ^a   Margulies, Leon ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^b MIGAL GALILEE TECHNOLOGY CENTER   (Israel)

Author keywords

Basal Spacing; Benzylalkylammonium Adsorption; Cation Adsorption Model; Ionic Strength; Montmorillonite

Indexed keywords

ADSORPTION; AMMONIUM COMPOUNDS; COMPOSITION EFFECTS; ELECTROLYTES; ELECTROSTATICS; ION EXCHANGE; IONIC STRENGTH; MATHEMATICAL MODELS;

BENZYLTRIETHYLAMMONIUM; BENZYLTRIMETHYLAMMONIUM; CATIONS; GOUY CHAPMAN EQUATIONS; MONTMORILLONITE;

CLAY MINERALS;

ADSORPTION; BENZYLTRIETHYLAMMONIUM; BENZYLTRIMETHYLAMMONIUM; MONTMORILLONITE;

EID: 0031412756     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.1997.0450607     Document Type: Article

References (31)

1. Boyd SA, Jaynes FW. 1992. Role of layer charge in organic contaminant sorption by organo-clays. In: Layer charge characteristics of clays. Pre-Meeting Workshop CMS and SSSA; Minneapolis, MN. Saskatchewan: Univ of Saskatchewan. p 89-120.
2. Boyd SA, Lee J-F, Mortland MM. 1988. Attenuating organic contaminant mobility by soil modification. Nature 333: 345-347.
3. Boyd SA, Shaobai S, Lee J-F, Mortland MM. 1988. Pentachlorophenol sorption by organo-clays. Clays Clay Miner 36:125-130.
4. Cornejo J, Hermosin MC. 1995. Organoclays as sorbents for organic contaminants: Herbicide adsorption. In: Proc Israeli-Spanish Workshop; Organoclays: Structure, properties and uses; Ein Gedi, Israel. p 32-33.
5. Gerstl Z, Mingelgrin U. 1979. A note of the adsorption of organic molecules on clays. Clays Clay Miner 27:285-290.
6. Hermosin MC, Cornejo J. 1993. Binding mechanism of 2,4-dichlorophenoxyacetic acid by organo-clays. J Environ Qual 22:325-331.
7. Jaynes WF, Boyd SA. 1991. Hydrophobicity of syloxane surfaces in smectites as revealed by aromatic hydrocarbon adsorption from water. Clays Clay Miner 39:428-436.
8. Lagaly G. 1987. Clay-organic interaction: Problems and recent results. In: Shultz LG, van Olphen H, Mumpton FA, editors. Proc Int Clay Conf; Denver; 1985. Bloomington, In: Clay Miner Soc. p 343-351.
9. Lagaly G. 1992. Layer charge determination by alkylammonium ions. In: Layer charge characteristics of clays. Pre-Meeting Workshop CMS and SSSA; Minneapolis, MN. Saskatchewan: Univ of Saskatchewan. p 1-54.
10. Lee J-F, Mortland MM, Boyd SA. 1989. Shape-selective adsorption of aromatic molecules from water by tetramethyl-ammonium-smectite. J Chem Soc, Faraday Trans 1 85: 2953-2962.
11. MacImdad Program. Version 5,0. 1994. Molecular Application Group: Stanford Univ and Yeda.
12. Margulies L, Rozen H, Nir S. 1988. Model for competitive adsorption of organic cations on clays. Clays and Clay Miner 36:270-276.
13. Margulies L, Rozen H, Rytwo G, Rubin B, Ruzo LO, Nir S, Cohen E. 1993. Photostabilization of pesticides by clays and chromophores. Arch Insect Biochem Physiol 22:467-486.
14. Margulies L, Stern T, Rubin B. 1994. Slow release of s-ethyl dipropylcarbamothiate from clay surfaces. J Agric Food Chem 42:1223-1227.
15. Margulies L, Stern T, Rubin B, Ruzo LO. 1992. Photostabilization of trifluralin adsorbed on a clay matrix. J Agric Food Chem 40:152-155.
16. Mortland MM. 1970. Clay-organic complexes and interactions. Adv Agron 22:75-117.
17. Mortland MM, Shaobai S, Boyd SA. 1986. Clay-organic complexes as adsorbents for phenol and chlorophenols. Clays Clay Miner 34:581-585.
18. Nir S. 1986. Specific and nonspecific cation adsorption to clays: Solution concentrations and surface potentials. Soil Sci Soc Am J 50:52-57.
19. Nir S, Hirsch D, Navrot J, Banin A. 1986. Specific adsorption of Li, Na, K, Cs and Sr to montmorillonite. Soil Sci Soc Am J 50:40-45.
20. Nir S, Rytwo G, Yermiyahu U, Margulies L. 1994. A model for cation adsorption to clays and membranes. Colloid Polym Sci 272:619-632.
21. Rytwo G, Banin A, Nir S. 1996. Ionic adsorption in the Ca-Mg-Na-montmorillonite system. Clays Clay Miner 44:276-285.
22. Rytwo G. Nir S, Margulies L. 1995. Interaction of monovalent organic cations with montmorillonite: Adsorption studies and model calculations. Soil Sci Soc Am J 59:554-564.
23. Rytwo G, Nir S, Margulies L. 1996. Adsorption and interaction of diquat and paraquat with montmorillonite. Soil Sci Soc Am J 60:601-610.
24. Rytwo G, Serban C, Nir S, Margulies L. 1991. Use of methylene blue and crystal violet for determination of exchangeable cations in montmorillonite. Clays Clay Miner 39:551-555.
25. Sanchez-Camazano M, Sanchez-Martin MJ. 1994. Organoclays as adsorbents for azinphosmethyl and dichlorvos in aqueous medium. Water, Air, Soil Pollut 74:19-28.
26. Serratosa JM. 1979. Surface properties of fibrous clay minerals (palygorskyte and sepiolite). In: Mortland MM, Farmer VC, editors. Proc Int Clay Conf; Oxford, England; 1978. Amsterdam: Elsevier, p 99-109.
27. Smith JA, Jaffe PR. 1994. Adsorptive selectivity of organiccation-modified bentonite for nonionic organic contaminants. Water, Air, Soil Pollut 72:205-211.
28. Smith JA, Jaffe PR, Chiou CT. 1990. Effect of ten quaternarty ammonium cations on tetrachloromethane sorption to clay from water. Environ Sci Technol 24:1167-1172.
29. Theng BKG. 1974. The chemistry of clay organic reactions. London: Adam Hilgar. 343 p.
30. Wolfe TA, Demiriel T, Bauman ER. 1985. Interaction of aliphatic amines with montmorillonite to enhance adsorption of organic pollutants. Clays Clay Miner 33:301-311.
31. Zhang Z, Sparks DL, Scrivner NC. 1993. Sorption and desorption of quaternary amine cations on clays. Environ Sci Technol 27:1625-1631.