Veen-type graphite in jurassic volcanic rocks of the external zone of the Betic Cordillera, Southern Spain

Canadian Mineralogist

Volumn 35, Issue 6, 1997, Pages 1379-1390

  Barrenechea, Jose F ^a   Luque, Francisco Javier ^a   Rodas, Magdalena ^a   Pasteris, Jill D ^b  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^b WASHINGTON UNIVERSITY   (United States)

Author keywords

Betic Cordillera; Fluid deposition; Graphite; Raman spectroscopy; Spain; Volcanic rocks; X ray diffraction

Indexed keywords

GRAPHITE; JURASSIC; RAMAN SPECTROSCOPY; VOLCANIC ROCK; XRD;

SPAIN, BETIC CORDILLERA;

EID: 0031389850     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (41)

1. BOTTINGA, Y. (1969): Calculated fractionation factors for carbon and hydrogen isotope exchange in the system calcite - carbon dioxide - graphite - methane - hydrogen - water vapor. Geochim. Cosmochim. Acta 33, 49-64.
2. 2 and calcite. Geochim. Cosmochim. Acta 55, 2867-2882.
3. COMAS, M.C., PUGA, E., BARGOSSI, G.M., MORTEN, L. & ROSSI, P.L. (1986): Paleogeography, sedimentation and volcanism of the central Subbetic Zone, Betic Cordilleras, southern Spain. Neues Jahrb. Geol. Paläont., Monatsh., 385-404.
4. CRAWFORD, W.A. & VALLEY, J.W. (1990): Origin of graphite in the Pickering gneiss and the Franklin marble, Honey Brook Upland, Pennsylvania Piedmont. Geol. Soc. Am., Bull. 102, 807-811.
5. DÍAZ DE NEIRA, J.A., ENRILE, A. & LÓPEZ OLMEDO, F. (1991): Hoja n. 970 (Huelma) a escala 1:50.000 del Mapa Geológico de Nacional (MAGNA). Instituto Tecnologico Geominero de España, Madrid, Spain.
6. DIESSEL, C.F.K. & OFFLER, R. (1975): Change in physical properties of coalified and graphitised phytoclasts with grade of metamorphism. Neues Jahrb. Mineral., Monatsh., 11-26.
7. DISSANAYAKE, C.B. (1994): Origin of vein graphite in high-grade metamorphic terrains. Role of organic matter and sediment subduction. Mineral. Deposita 29, 57-67.
8. DUKE, E.F. & RUMBLE, D., III (1986): Textural and isotopic variations in graphite from plutonic rocks, south central New Hampshire. Contrib. Mineral. Petrol. 93, 409-419.
9. DUNN, S.R. & VALLEY, J.W. (1992): Calcite-graphite isotope thermometry: a test for polymetamorphism in marble, Tudor gabbro aureole, Ontario, Canada. J. Metamorphic Geol. 10, 487-501.
10. FERRY, J.M. & BAUMGARTNER, L. (1987): Thermodynamic models of molecular fluids at the elevated pressures and temperatures of crustal metamorphism. In Thermodynamic Modeling of Geological Materials: Minerals, Fluids, and Melts (I.S.E. Carmichael & H.P. Eugster, eds.). Rev. Mineral. 17, 323-365.
11. GARCÍA DUEÑAS, V. & COMAS, M.C. (1983): Sobre la evolución mesozoica de la plataforma y margen ibéricos correspondientes a las Zonas Externas Béticas. Actas V Asamb. Nac. Geodesia Geofís., 271 (abstr.).
12. GARCÍA-HERNÁNDEZ, M., LÓPEZ-GARRIDO, A.C., RIVAS, P., SANZ DE GALDEANO, C. & VERA, J.A. (1980): Mesozoic paleogeographic evolution of the External Zones of the Betic Cordillera. Geol. Mijnb. 59(2), 155-168.
13. HAHN-WEINHEIMER, P. & HIRNER, A. (1981): Isotopic evidence for the origin of graphite. Geochem. J. 15, 9-15.
14. JAROSEWICH, E., NELEN, J.A. & NORBERG, J.A. (1980): Reference samples for electron microprobe analysis. Geostandards Newsletters 4, 43-47.
15. JÉBRAK, M. (1992): Les textures intra-filoniennes, marqueurs des conditions hydrauliques et tectoniques. Chronique de la Recherche Minière 506, 25-35.
16. KRAUTHEIM, G. (1993): Kristallinitaetsbestimmungen an Schitchtmineralen Illit und Graphit. Ph.D. thesis, University of Hannover, Hannover, Germany.
17. KWIECINSKA, B. (1980): Mineralogy of natural graphites. Polska Akad. Nauk, Prace Mineralogiczne 67, 5-79.
18. LANDIS, C.A. (1971): Graphitization of dispersed carbonaceous material in metamorphic rocks. Contrib. Mineral. Petrol. 30, 34-45.
19. LUQUE, F.J., BARRENECHEA, J.F. & RODAS, M. (1993): Graphite geothermometry in low and high temperature regimes: two case studies. Geol. Mag. 130, 501-511.
20. _, RODAS, M. & GALÁN, E. (1992): Graphite vein mineralization in the ultramafic rocks of southern Spain: mineralogy and genetic relationships. Mineral. Deposita 27, 226-233.
21. OHMOTO, H. & KERRICK, D.M. (1977): Devolatilization equilibria in graphitic systems. Am. J. Sci. 277, 1013-1044.
22. PASTERIS, J.D. & CHOU, I-MING (1998): Fluid-deposited graphitic inclusions in quartz: comparison between KTB (German Continental Deep Drilling) core samples and artificially re-equilibrated natural inclusions. Geochim. Cosmochim. Acta (in press).
23. _, HARRIS, T.N. & SASSANI, D.C. (1995): Interactions of mixed volatile-brine fluids in rocks of the southwestern footwall of the Duluth Complex, Minnesota: evidence from aqueous fluid inclusions. Am. J. Sci. 295, 125-172.
24. _ & WOPENKA, B. (1991): Raman spectra of graphite as indicators of degree of metamorphism. Can. Mineral. 29, 1-9.
25. PEARSON, D.G., BOYD, F.R. & NIXON, P.H. (1990): Graphite-bearing mantle xenoliths from the Kaapvaal Craton: implications for graphite and diamond genesis. Carnegie Inst. Washington, Yearbook, 11-19.
26. PORTUGAL, M., MORATA, D., PUGA, E., DEMANT, A. & AGUIRRE, L. (1995): Evolución geoquímica y temporal del magmatismo básico mesozoico en las zonas externas de las Cordilleras Béticas. Estudios Geológicos 51, 109-118.
27. PUGA, E. & PORTUGAL, M. (1989): The recrystallization and partial melting of xenoliths of pelitic rocks and their bearing on the contaminated basalts (Subbetic Zone, Spain). In Magma-Crust Interactions and Evolution. Theophrastus Publications, S.A., Athens, Greece (115-159).
28. _, _, DÍAZ DE FEDERICO, A., BARGOSSI, G.M. & MORTEN, L. (1989): The evolution of the magmatism in the external zones of the Betic Cordilleras during the Mesozoic. Geodinamica Acta 3(4), 253-266.
29. RUMBLE, D., III, DUKE, E.F. & HOERING, T.C. (1986): Hydrothermal graphite in New Hampshire: evidence of carbon mobility during regional metamorphism. Geology 14, 452-455.
30. _ & HOERING, T.C. (1986): Carbon isotope geochemistry of graphite vein deposits from New Hampshire, U.S.A. Geochim. Cosmochim. Acta 50, 1239-1247.
31. 2: an experimental study. Contrib. Mineral. Petrol. 112, 35-45.
32. SCHIDLOWSKI, M., HAYES, J.M. & KAPLAN, I.R. (1983): Isotopic inferences of ancient biochemistries: carbon, sulfur, hydrogen, and nitrogen. In Earth's Earliest Biosphere: its Origin and Evolution (J.W. Schopf, ed.). Princeton University Press, Princeton, New Jersey (149-186).
33. SCHREINER, W.N. & JENKINS, R. (1983): Profile fitting for quantitative analysis in X-ray powder diffraction. Advances in X-Ray Analysis 26, 141-147.
34. STRENS, R.G.J. (1965): The graphite deposit of Seathwaite in Borrowdale, Cumberland. Geol. Mag. 102, 393-406.
35. WADA, H., TOMITA, T., MATSUURA, K., IUCHI, K., ITO, M. & MORIKIYO, M. (1994): Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms, Japan. Contrib. Mineral. Petrol. 118, 217-228.
36. WALTHER, J. & ALTHAUS, E. (1993): Graphite deposition in tectonically mobilized fault planes of the KTB-pilot drill hole. In Kontinentales Tiefbohrprogramm der Bundes-republik Deutschland (R. Emmermann, J. Lauterjung & T. Umsonst, eds.). Niedersächsisches Landesamt für Bodenforschung (Hannover, Germany), Rep. 93-2, 493-497.
37. WEIS, P.L., FRIEDMAN, I. & GLEASON, J.P. (1981): The origin of epigenetic graphite: evidence from isotopes. Geochim. Cosmochim. Acta 45, 2325-2332.
38. WOPENKA, B. & PASTERIS, J.D. (1993): Structural characterization of kerogens to granulite-facies graphite: applicability of Raman microprobe spectroscopy. Am. Mineral. 78, 533-557.
39. ZIEGENBEIN, D. & JOHANNES, W. (1980): Graphite in C-H-O fluids: an unsuitable compound to buffer fluid composition at temperatures up to 700°C. Neues Jahrb. Mineral., Monatsh., 289-305.
40. _ & _ (1990): Graphit-Fluid-Wechselwirkungen: Einfluß der Graphit-Kristallinität. In Kontinentales Tiefbohrprogramm der Bundesrepublik Deutschland (R. Emmermann & P. Giese, eds.). Niedersächsisches Landesamt für Bodenforschung (Hannover, Germany), Rep. 90-4, 559.
41. _, SKROTZKI, R., HOEFS, J., MÜLLER, H., REUTEL, C. & EMMERMANN, R. (1989): Fluidtransport und Graphitbildung auf Störungszonen. In Kontinentales Tiefbohrprogramm der Bundesrepublik Deutschland (R. Emmermann & P. Giese, eds.). Niedersächsisches Landesamt für Bodenforschung (Hannover, Germany), Rep. 89-3, 46-53.