Regiocontrolled synthesis of poly((3-hexylthiophene-ylene)ethynylenes): Their characterization and photoluminescent properties

Macromolecules

Volumn 30, Issue 24, 1997, Pages 7487-7492

  Li, Juan ^a   Pang, Yi ^a  

^a CLARK ATLANTA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORESCENCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLUMINESCENCE; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY;

POLYTHIOPHENE; REGIOCONTROLLED SYNTHESIS;

AROMATIC POLYMERS;

EID: 0031384232     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9708297     Document Type: Article

References (26)

1. Trumbo, D. L.; Marvel, C. S. J. Polym. Sci., Part A: Polym. Chem. Ed. 1986, 24, 2231.
2. Cernia, E.; D'Ilario, L.; Ortaggi, G.; Scarsella, M.; Scialis, R.; Sleiter, G. Gazz. Chim. Ital. 1989, 119, 309.
3. Tormos, G. V.; Nugara, P. N.; Lakshmikantham, M. V.; Cava, M. P. Synth. Met. 1993, 53, 271.
4. Tour, J. M.; Schumm, J. S. Polym. Prepr. 1993, 34 (2), 368.
5. Pearson, D. J.; Schumm, J. S.; Tour, J. M. Macromolecules 1994, 27, 2348.
6. Schumm, J. S.; Pearson, D. L.; Tour, J. M. Angew. Chem., Int. Ed. Engl. 1994, 33 (13), 1360.
7. Tour, J. M. Chem. Rev. 1996, 96, 537.
8. Swanson, L. S.; Lane, P. A.; Shinar, J.; Pang, Y.; Barton, T. J. Synth. Met. 1993, 55-57, 293.
9. Yamamoto, T.; Yamada, W.; Takagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620.
10. Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Yamada, W.; Takagi, M.; Yamamoto, T. Jpn. J. Appl. Phys. 1995, 34, 3139.
11. Chen, T.-A.; Wu, X.; Rieke, R. D. J. Am. Chem. Soc. 1995, 117, 233.
12. McCullough, R. D.; Lowe, R. D. J. Chem. Soc., Chem. Commun. 1992, 70.
13. Xu, B.; Holdcroft, S. Macromolecules 1993, 26, 4457.
14. Pang, Y.; Wang, Z.; Barton, T. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37 (2), 333.
15. Tamao, K.; Kodama, S.; Nakajima, I.; Kumada, M.; Minato, A.; Suzuki, K. Tetrahedron 1982, 38 (22), 3347.
16. Mao, H.; Xu, B.; Holdcroft, S. Macromolecules 1993, 26, 1163-1169.
17. Heck, R. F. Palladium Reagents in Organic Synthesis; Academic Press: New York, 1990.
18. Sonogashira, K.; Tohda, Y.; Hagihara, N. Tetrahedron Lett. 1975, 50, 4467.
19. 13C NMR (CPMAS) of the solid indicated that most acetylene carbons had been converted to olefin carbons. Solutions of thienylacetylenes ca. 20% in hexanes, however, can be stored in a refrigerator for a few weeks without significant change.
20. Holdcroft, S. J. Polym. Sci., Part B: Polym. Phys. 1991, 29, 1585.
21. Rutherford, D. R.; Stille, J. K.; Elliott, C. M.; Reichert, V. R. Macromolecules 1992, 25, 2294.
22. Birks, J. B. Photophysics of Aromatic Molecules; Wiley: London, 1970.
23. Krasovitskii, B. M.; Bolotin, B. M. Organic Luminescent Materials; VCH: New York, 1988; Chapter 5 (translated by V. G. Vopian).
24. Demas, J. N.; Crosby, G. A. J. Phys. Chem. 1971, 75, 991.
25. Melhuish, W. H. J. Phys. Chem. 1961, 65, 229.
26. CRC Handbook of Chemistry and Physics, 64th ed.; CRC Press: Boca Raton, FL, 1983-1984.