The influence of chemical surroundings on the properties of α-nitronyl nitroxide radicals in solution. Its relation with the magnetic properties in solid state

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 305, Issue , 1997, Pages 367-384

  Cirujeda, Joan ^a   Jürgens, Oriol ^a   Vidal Gancedo, José ^a   Rovira, Concepció ^a   Turek, Philippe ^b   Veciana, Jaume ^a  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; MAGNETIC MATERIALS; MAGNETIC PROPERTIES; MOLECULES; SOLUTIONS;

MOLECULAR MAGNETIC MATERIALS; NITRONYL NITROXIDE; SPIN DENSITY DISTRIBUTION;

ORGANIC COMPOUNDS;

EID: 0031375190     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259708045073     Document Type: Article

References (35)

1. For recent overviews, see: a) Gatteschi, D., Kahn, O., Miller, S., Palacio, F. (eds) (1991) Molecular Magnetic Materials, Kluwer Academic, Dordrecht, The Netherlands, b) Iwamura, H., Miller, J.S (eds) Proceedings of the International Symposium on Chemistry and Physics of Molecular Based Magnetic Materials, Tokyo, Japan 25-30 October 1992, in Mol. Cryst. Liq. Cryst. (1993), 232. c) Kahn, O, (1993) Molecular Magnetism, VCH Publishers , Weinheim. d) Miller, J. S., Epstein, A. J. (1994) Angew. Chem. Int. Ed. Engl., 33, 385.
2. For recent overviews, see: a) Gatteschi, D., Kahn, O., Miller, S., Palacio, F. (eds) (1991) Molecular Magnetic Materials, Kluwer Academic, Dordrecht, The Netherlands, b) Iwamura, H., Miller, J.S (eds) Proceedings of the International Symposium on Chemistry and Physics of Molecular Based Magnetic Materials, Tokyo, Japan 25-30 October 1992, in Mol. Cryst. Liq. Cryst. (1993), 232. c) Kahn, O, (1993) Molecular Magnetism, VCH Publishers, Weinheim. d) Miller, J. S., Epstein, A. J. (1994) Angew. Chem. Int. Ed. Engl., 33, 385.
3. For recent overviews, see: a) Gatteschi, D., Kahn, O., Miller, S., Palacio, F. (eds) (1991) Molecular Magnetic Materials, Kluwer Academic, Dordrecht, The Netherlands, b) Iwamura, H., Miller, J.S (eds) Proceedings of the International Symposium on Chemistry and Physics of Molecular Based Magnetic Materials, Tokyo, Japan 25-30 October 1992, in Mol. Cryst. Liq. Cryst. (1993), 232. c) Kahn, O, (1993) Molecular Magnetism, VCH Publishers , Weinheim. d) Miller, J. S., Epstein, A. J. (1994) Angew. Chem. Int. Ed. Engl., 33, 385.
4. For recent overviews, see: a) Gatteschi, D., Kahn, O., Miller, S., Palacio, F. (eds) (1991) Molecular Magnetic Materials, Kluwer Academic, Dordrecht, The Netherlands, b) Iwamura, H., Miller, J.S (eds) Proceedings of the International Symposium on Chemistry and Physics of Molecular Based Magnetic Materials, Tokyo, Japan 25-30 October 1992, in Mol. Cryst. Liq. Cryst. (1993), 232. c) Kahn, O, (1993) Molecular Magnetism, VCH Publishers , Weinheim. d) Miller, J. S., Epstein, A. J. (1994) Angew. Chem. Int. Ed. Engl., 33, 385.
5. Tamura, M., Nakazawa, Y., Shiomi, D., Nozawa, K., Hosokoshi, Y., Ishikawa, M., Takahashi, M., Kinoshita, M. (1991) Chem. Phys. Letters, 186, 401.
6. Zheludev, A., Barone, V., Bonnet, M., Delley, B., Grand, A., Ressouche, E., Rey, P., Subra, R., Schweizer, J. (1994) J. Am. Chem. Soc., 116, 2019.
7. Neely, J. W., Hatch, G. F., Kreilick, R. W. (1974) J. Am. Chem. Soc., 96, 652. Davis, M. S., Morokuma, K., Kreilick, R. W. (1972) J. Am. Chem. Soc., 94, 5588.
8. Neely, J. W., Hatch, G. F., Kreilick, R. W. (1974) J. Am. Chem. Soc., 96, 652. Davis, M. S., Morokuma, K., Kreilick, R. W. (1972) J. Am. Chem. Soc., 94, 5588.
9. For example see: a) Awaga, K., Inabe, T., Maruyama, Y., Nakamura, T., Matsumoto, M. (1992) Chem. Phys. Letters, 195, 21. b) Awaga, K., Okuno, T., Yamaguchi, A., Hasegawa, M., Inabe, T., Maruyama, Y., Wada, N. (1994) Phys. Rev. B, 49, 3975. c) Akita, T., Mazaki, Y., Kobayashi, K., Koga, N., Iwamura, H.(1995) J. Org. Chem., 60, 2092.
10. For example see: a) Awaga, K., Inabe, T., Maruyama, Y., Nakamura, T., Matsumoto, M. (1992) Chem. Phys. Letters, 195, 21. b) Awaga, K., Okuno, T., Yamaguchi, A., Hasegawa, M., Inabe, T., Maruyama, Y., Wada, N. (1994) Phys. Rev. B, 49, 3975. c) Akita, T., Mazaki, Y., Kobayashi, K., Koga, N., Iwamura, H.(1995) J. Org. Chem., 60, 2092.
11. For example see: a) Awaga, K., Inabe, T., Maruyama, Y., Nakamura, T., Matsumoto, M. (1992) Chem. Phys. Letters, 195, 21. b) Awaga, K., Okuno, T., Yamaguchi, A., Hasegawa, M., Inabe, T., Maruyama, Y., Wada, N. (1994) Phys. Rev. B, 49, 3975. c) Akita, T., Mazaki, Y., Kobayashi, K., Koga, N., Iwamura, H.(1995) J. Org. Chem., 60, 2092.
12. a) Desiraju, G. R. (1995) Angew. Chem. Int. Ed. Engl.,34, 2311.
13. b) Cirujeda, J., Mas, M., Molins, E., Lanfranc de Panthou, F., Laugier, J., Geun Park, J., Paulsen, C., Rey, P., Rovira, C., Veciana, J. (1995) J. Chem. Soc., Chem. Comm., 709.
14. c) Hernàndez, E., Mas, M., Molins, E., Rovira, C., Veciana, J. (1993) Angew. Chem. Int. Ed. Engl.,32, 882.
15. Shetty, AS., Zhang, J., Moore, JS. (1996) J. Am. Chem. Soc. 118, 1019.
16. Gavezzotti, A. (1994) Acc. Chem. Res., 27, 309.
17. Haggin, J. (1995) Chem. Eng. News, 21. Wang, X., Simard, M., Wuest, J. D. (1994) J. Am. Chem. Soc., 116, 12119. Whitesides, G. M., Simanek, E. E., Mathias, J. P., Seto, C. T., Chin, D., Mammen, M., Gordon, D. M. (1995) Acc. Chem. Res., 28, 37.
18. Haggin, J. (1995) Chem. Eng. News, 21. Wang, X., Simard, M., Wuest, J. D. (1994) J. Am. Chem. Soc., 116, 12119. Whitesides, G. M., Simanek, E. E., Mathias, J. P., Seto, C. T., Chin, D., Mammen, M., Gordon, D. M. (1995) Acc. Chem. Res., 28, 37.
19. Haggin, J. (1995) Chem. Eng. News, 21. Wang, X., Simard, M., Wuest, J. D. (1994) J. Am. Chem. Soc., 116, 12119. Whitesides, G. M., Simanek, E. E., Mathias, J. P., Seto, C. T., Chin, D., Mammen, M., Gordon, D. M. (1995) Acc. Chem. Res., 28, 37.
20. J. Cirujeda., C. Rovira., J.L. Stanger., P. Turek., J. Veciana. in Kahn, O. (ed) Magnetism: A Supramolecular Function, Kluwer Academic, Dordrecht, The Netherlands, in press.
21. J-L. M. Abboud, M. J. Kamlet, R. W. Taft. (1977) J.Am.Chem.Soc., 99, 8325. M. J. Kamlet, R. W. Taft, M. H. Abraham, R. M. Doherty. (1984) J.Am.Chem.Soc., 106, 464. M. J. Kamlet, R. W. Taft, M. H. Abraham, J-L. M. Abboud. (1985). J.Sol.Chem., 14, 153.
22. J-L. M. Abboud, M. J. Kamlet, R. W. Taft. (1977) J.Am.Chem.Soc., 99, 8325. M. J. Kamlet, R. W. Taft, M. H. Abraham, R. M. Doherty. (1984) J.Am.Chem.Soc., 106, 464. M. J. Kamlet, R. W. Taft, M. H. Abraham, J-L. M. Abboud. (1985). J.Sol.Chem., 14, 153.
23. J-L. M. Abboud, M. J. Kamlet, R. W. Taft. (1977) J.Am.Chem.Soc., 99, 8325. M. J. Kamlet, R. W. Taft, M. H. Abraham, R. M. Doherty. (1984) J.Am.Chem.Soc., 106, 464. M. J. Kamlet, R. W. Taft, M. H. Abraham, J-L. M. Abboud. (1985). J.Sol.Chem., 14, 153.
24. Taft, R. W.; Abboud, J. L. M.; Kamlet, M. J. J. Am. Chem. Soc. (1981), 103, 1080-1086. Kamlet, M. J.; Taft, R. W. J. Chem. Soc. Perkin. Trans. II (1979), 349-356. Knauer, B. R.; Napier, J. J. J. Am. Chem. Soc. (1976), 98, 4395-4400.
25. Taft, R. W.; Abboud, J. L. M.; Kamlet, M. J. J. Am. Chem. Soc. (1981), 103, 1080-1086. Kamlet, M. J.; Taft, R. W. J. Chem. Soc. Perkin. Trans. II (1979), 349-356. Knauer, B. R.; Napier, J. J. J. Am. Chem. Soc. (1976), 98, 4395-4400.
26. Taft, R. W.; Abboud, J. L. M.; Kamlet, M. J. J. Am. Chem. Soc. (1981), 103, 1080-1086. Kamlet, M. J.; Taft, R. W. J. Chem. Soc. Perkin. Trans. II (1979), 349-356. Knauer, B. R.; Napier, J. J. J. Am. Chem. Soc. (1976), 98, 4395-4400.
27. The used solvents are: 1.-water, 2,-methanol, 3,-ethanol, 4.-benzilic alcohol, 5.-diethyl ether, 6.-isopropilic ether, 7.-dioxane, 8.-tetrahydrofurane, 9.-acetonitrile, 10.-acetic acid, 11.-ethyl acetate, 12.-acetone, 13.-pyridine, 14.-triethylamine, 15.-dimethylsulfoxide, 16.-dimethylformamide, 17.-nitromethane, 18.-nitrobenzene, 19.-carbon disulfide, 20.-methylene chloride, 21.-chloroform, 22,-carbon tetrachloride, 23.-chlorobenzene, 24,-toluene, 25.-n-hexane, 26.-n-pentane.
28. Atherton, N.M., (1993), Principles of Electron Spin Resonance, Ellis Horwood LPR Prentice Hall, New York. Weil, J.A., Bolton, J.R., Wertz, J.E., (1994) Electron Paramagnetic Resonance. Elementary Theory and Practical Applications, John Wiley and Sons, New York.
29. Atherton, N.M., (1993), Principles of Electron Spin Resonance, Ellis Horwood LPR Prentice Hall, New York. Weil, J.A., Bolton, J.R., Wertz, J.E., (1994) Electron Paramagnetic Resonance. Elementary Theory and Practical Applications, John Wiley and Sons, New York.
30. Briere, R., Dupeyre, R. M., Lemaire, H., Morat, C., Rassat, A., Rey, P. (1965) Bull. Soc. Chim. Fr.,3290.
31. D'Anna, J. A., Wharton, J. H. (1970) J. Chem. Phys., 53, 4047.
32. SimFonia program, Bruker, 1995.
33. For example see: Kinoshita, M., (1994) Jpn. J. Appl. Phys., 33, 5718.
34. 2 software from BIOSYM/Molecular Simulations.
35. Hernàndez, E., Mas, M., Molins, E., Rovira, C., Veciana, J., Borrás-Almenar, J., Coronado, E. (1994) Chem. Mater., 6, 2398. see also ref 15.