Se-substitution and cation effects on the high-pressure molecular superconductor, β-Me4N[Pd(dmit)2]2 -A unique two-band system

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 296, Issue , 1997, Pages 217-244

  Kato, Reizo ^a   Liu, You Liang ^a   Hosokoshi, Yuko ^a,c   Aonuma, Shuji ^a   Sawa, Hiroshi ^b  

^a UNIVERSITY OF TOKYO   (Japan)

^b CHIBA UNIVERSITY   (Japan)

^c INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

Band calculation; Crystal structure; Magnetic susceptibility; Metal dithiolene complex; Metal insulator transition; Molecular conductor; Pressure effect; Resistivity

Indexed keywords

BAND STRUCTURE; CRYSTAL STRUCTURE; ELECTRIC CONDUCTIVITY OF SOLIDS; HIGH PRESSURE EFFECTS; MAGNETIC PERMEABILITY; SUBSTITUTION REACTIONS; TRANSITION METALS;

METAL DITHIOLENE COMPLEX; METAL INSULATOR TRANSITION; MOLECULAR CONDUCTORS;

SUPERCONDUCTING MATERIALS;

EID: 0031349838     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (16)

1. a) A. Kobayashi, H. Kim, Y. Sasaki, K. Murata, R. Kato, and H. Kobayashi, J. Chem, Soc. Faraday Trans., 86, 361 (1990).
2. b) A. Kobayashi, H. Kobayashi, A. Miyamoto, R. Kato, R. A. Clark, and A. E. Underhill, Chem. Lett, 2163 (1991).
3. c) A. Kobayashi, R. Kato, R. A. Clark, A. E. Underbill, A. Miyamoto, K. Bun, T. Naito and H. Kobayashi, Synth. Metals, 34 2927 (1993).
4. d) K. Seya, Y. Kobayashi, T. Nakamura, T. Takahashi, Y. Osako, H. Kobayashi, R. Kato, A. Kobayashi, and H. Iguchi, Synth. Metals, 70, 1043 (1995).
5. J. P. Cornelissen, B. Pomarède, A. L. Spek, D. Reefman, J. G. Haasnoot, and Reedijk, Inorg. Chem., 32, 3720 (1993).
6. a) C. Faulmann, J-P. Legros, P. Cassoux, J. Cornelissen, L. Brossard, M. Inokuchi, H. Tajima, and M. Tokumoto, J. Chem. Soc. Dalton Trans., 249 (1994).
7. b) T. Naito, Doctor thesis (the University of Tokyo, 1995).
8. Y. Tsuchiya, T. Nakamura, T. Takahashi, Y. -L. Liu, H. Sawa and R. Kato, Synth, Metals, in press.
9. a) A. Kobayashi, T. Naito, and H. Kobayashi, Synth, Met., 70, 1047 (1995).
10. b) H. Tajima, S. Ikeda, M. Inokuchi, T. Ohta, A. Kobayashi, T. Sasaki, N. Toyota, R. Kato, H. Kobayashi, and H. Kuroda, Synth, Met., 70, 1051 (1995).
11. a) E. Canadell, S. Ravy, J. P. Pouget, and L. Brossard, Solid State Commun., 75, 633 (1990).
12. b) E. Canadell, I. E. -I. Rachidi, S. Ravy, J. P. Pouget, L. Brossard, and J. P. Legros, J. Phys. France, 10, 2967 (1989).
13. c) H. Tajima, T. Naito, M. Tamura, A. Kobayashi, H. Kuroda, R. Kato, H. Kobayashi, R. A. Clark, and A. E. Underbill, Solid State Commun., 79, 337 (1991).
14. 2g symmetries for HOMO and LUMO respectively. This assumption compensates experimental errors in the X-ray structure analysis.
15. A. Ugawa, K. Yakushi, and H. Kuroda, Mol. Cryst. Liq. Cryst., 181, 269 (1990).
16. A. Kobayashi, H. Kim, Y. Sasaki, R. Kato, and H. Kobayashi, Solid State Commun., 62, 57 (1987).