Stereospecific anionic polymerization of α-(N-tert-butyl aminomethyl)acrylate having unprotected amino group

Polymer Journal

Volumn 29, Issue 10, 1997, Pages 872-874

  Habaue, Shigeki ^a   Baraki, Hideo ^a   Okamoto, Yoshio ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

Anionic Polymerization; Isotactic Polymer; Lithium Amide; Stereospecific Polymerization; (Aminomethyl)acrylate

Indexed keywords

CONFORMATIONS; ESTERS; INITIATORS (CHEMICAL); LITHIUM COMPOUNDS; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; TOLUENE;

ETHYL BUTYLAMINOMETHYLACRYLATE; LITHIUM AMIDE; TETRAHYDROFURAN;

ANIONIC POLYMERIZATION;

EID: 0031339533     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.29.872     Document Type: Article

References (11)

1. (a) S. Habaue, H. Yamada, and Y. Okamoto, Macromolecules, 29, 3326 (1996).
2. (b) S. Habaue, H. Yamada, T. Uno, and Y. Okamoto, J. Polym. Sci., Part A, Polym. Chem., 35, 721 (1997).
3. (a) S. Habaue, T. Uno, and Y. Okamoto, Macromolecules, in press,
4. (b) S. Habaue, T. Uno, H. Baraki, and Y. Okamoto, submitted for publication.
5. The anionic polymerization of a methacrylate having hindered phenol in ester group by alkyllithium with aluminum reagent as an initiator has been reported: T. Kitayama, S. Urbanek, T. Yanagida, and K, Hatada, Polym. J., 28, 827 (1996).
6. J. Villieras and M. Rambaud, Synthesis, 924 (1982).
7. (a) T. Kodaira, T. Fujisawa, Q.-Q. Liu, and M. Urushisaki, Macromolecules, 29, 484 (1996).
8. (b) Q.-Q. Liu, T. Kodaira, M. Urushisaki, and T. Hashimoto, Polym. J., 28, 1000 (1996).
9. (a) H. Yuki and K. Hatada, Adv. Polym. Sci., 31, 1 (1979).
10. (b) H. Yuki, K. Hatada, T. Niinomi, and K. Miyaji, Polym. J., 1, 130 (1970).
11. (c) K. Hatada, S. Kokan, T. Niinomi, K. Miyaji, and H. Yuki, J. Polym. Sci., Polym. Chem. Ed., 13, 2117 (1975).