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Sovish, R.C. (1959). J. Org. Chem. 24, 1345-1347. 4-Hydroxystyrene was prepared here in 40% yield by the decarboxylation of 4-hydroxycinnamic acid, the quinoline solution of which was dropped into an evacuated, heated (225°C) vessel containing copper catalyst, while the product was immediately distilled out. 4-Hydroxystyrene readily polymerizes on standing even at 0°C.
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3342911029
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note
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sat are chemical shifts of measured sample, pure calixarene and saturated sample (100% complexation), respectively.
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21
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3343025156
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note
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Complexation constant for 7 has been computed using only first 5 experimental points from the titration curves of aromatic hydrogens. The authors are aware of likely uncorrect stoichiometric model for this calculation (Ag: 7 = 1:1).
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3342893647
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note
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The chemical shifts of calixarene hydrogens were scarcely changed by the concentration of AgTf.
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24
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25
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