Synthesis of 1-O-(methylthio)thiocarbonyl sugar derivatives bearing acyl protective groups using phase transfer catalysis methods

Journal of Carbohydrate Chemistry

Volumn 16, Issue 9, 1997, Pages 1393-1406

  Endo, Tadatoshi ^a   Araki, Younosuke ^b  

^a TSURUMI UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031323963     PISSN: 07328303     EISSN: None     Source Type: Journal    
DOI: 10.1080/07328309708005757     Document Type: Article

References (41)

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29. Solid - liquid two phase methods are known to be milder than liquid - liquid two phase methods: for examples see M. Fedorynski, K. Wojciechowski, Z. Matacz and M. Makosza, J. Org. Chem., 43, 4682 (1978); V. G. Purohit and R. Subramanian, Chem. Ind., 731 (1978); G. V. Kryshtal, V. V. Kulganek, V. F. Kucherov and L. A. Yanovskaya, Synthesis, 107 (1979).
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33. 1H NMR spectrum.
34. 1H NMR spectrum and thin-layer chromatogram of the mixture indicated the presence only of 2α and 2β.
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40. Recent reinvestigation on the anomeric configuration of the compound 4α using a 270MHz-NMR apparatus revealed that 4α has the a configuration. The corresponding compound 4β in the reference 23 should be read as compound 4α.
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