Synthesis of a new Pd(II) complex with one hfac-O, O' and one hfac-monoxime-C, N as ligands; unexpected C-O bond formation between C3-bonded hfac and N-bonded monoxime

Chemistry Letters

Volumn , Issue 11, 1997, Pages 1095-1096

  Okeya, Seichi ^a   Taniguchi, Kayo ^a   Nishimura, Jyunko ^a   Kusuyama, Yoshiaki ^a   Nagasawa, Isoroku ^b   Kushi, Yoshihiko ^b  

^a WAKAYAMA UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031314970     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.1095     Document Type: Article

References (10)

1. "Comprehensive Coordination Chemistry," ed by G. Wilkinson, Vol. 2, Pergamon Press (1987), pp 269-270.
2. V. Y. Kukushkin, D. Tudela, Y. A. Izotova, V. K. Belsky, and A. I. Stash, Inorg. Chem., 35, 4926(1996) and references cited therein.
3. 12Pd: C, 24.87; H, 1.22; N, 2.42%.
4. -3, Mo-Kα (λ = 0.7107 Å) radiation, room temperature. All crystallographic measurements were made using a MAC science MXC3 diftractometer. Lattice parameters were determined by application of the automatic diffractometer indexing routine to the positions of 22 reflections. Data were measured in the range 3≤2θ≤50° in the ω-2θ scan with three check reflections being measured every 100 data. The structure was solved by direct methods (SIR92) and refined by full-matrix least squares analysis using 4740 unique reflections resulting in final R factor = 0.062, Rw = 0.077. Refinement was anisotropic for all non-hydrogen atoms.
5. For Example, A. R. Siedle, R. A. Newmark, and L. H. Pignolet, Inorg. Chem., 22, 2281 (1983); S. Okeya, T. Miyamoto, S. Ooi, Y. Nakamura, and S. Kawaguchi, Bull. Chem. Soc. Jpn., 57, 395(1984).
6. For Example, A. R. Siedle, R. A. Newmark, and L. H. Pignolet, Inorg. Chem., 22, 2281 (1983); S. Okeya, T. Miyamoto, S. Ooi, Y. Nakamura, and S. Kawaguchi, Bull. Chem. Soc. Jpn., 57, 395(1984).
7. S. Okeya, S. Koshino, M. Namie, I. Nagasawa, and Y. Kushi, J. Chem. Soc., Chem. Commun., 1995, 2123.
8. 3).
9. S. Okeya, H. Sazaki, M. Ogita, T. Takemoto, Y. Onuki, Y. Nakamura, B. K. Mohapatra, and S. Kawaguchi, Bull. Chem. Soc. Jpn., 54, 1978(1981); S. Matsumoto and S. Kawaguchi, Bull. Chem. Soc. Jpn., 53, 1577 (1980).
10. S. Okeya, H. Sazaki, M. Ogita, T. Takemoto, Y. Onuki, Y. Nakamura, B. K. Mohapatra, and S. Kawaguchi, Bull. Chem. Soc. Jpn., 54, 1978(1981); S. Matsumoto and S. Kawaguchi, Bull. Chem. Soc. Jpn., 53, 1577 (1980).