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Hughes MP, Shang M, Smith BD: High affinity carboxylate binding using neutral urea-based receptors with internal Lewis acid coordination. J Org Chem 1996, 61:4510-4511. The overall affinity of a urea-based host for anions is enhanced by generation of an intramolecular charge separation. A very profitable compromise allowing the combination of efficient charged anchor groups and overall ligand neutrality.
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37049074016
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Beer PD, Drew MGB, Graydon AR, Smith DK, Stokes SE: Quantitative and structural investigations of hydrogen-bonding interactions in anion binding of mono- and 1,1′-bis-substituted aryl cobaltocenium receptors. J Chem Soc Dalton Trans 1995: 403-408.
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Beer PD, Drew MGB, Hodacova J, Stokes SE: Synthesis, structure and anion co-ordination chemistry of a novel macrocyclic cobaltocenium receptor. J Chem Soc Dalton Trans 1995:3447-3453.
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Selective electrochemical recognition of bidentate anionic guests in competitive solvents using novel ferrocenyl thiourea and guanidinium receptors
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J Organometall Chem
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Neutral ferrocenoyl receptors for the selective recognition and sensing of anionic guests
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Beer PD, Graydon AR, Johnson AOM, Smith DK: Neutral ferrocenoyl receptors for the selective recognition and sensing of anionic guests, Inorg Chem 1997, 36:2112-2118. Offers an overview of several ferrocene-based neutral receptors and introduces the concept of 'chemical selectivity'.
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37049083199
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Beer PD, Chen Z, Goulden AJ, Grieve A, Hesek D, Szemes F, Wear T: Anion recognition by novel ruthenium(II) bipyridyl calix[4]arene receptor molecules. J Chem Soc Chem Commun 1994: 1269-1271.
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Beer PD, Drew MGB, Hesek D, Nam KC: A new carboxylate anion selective cobaltocenium calix[4larene receptor. J Chem Soc Chem Commun 1997: 107-108. The technical achievement of bridging a calix[4]arene with a redox-active cobaltocenium group in a very strained conformation confers a very high degree of rigidity and preorganization in this new host.
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J Chem Soc Chem Commun
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Morzherin Y, Rudkevich DM, Verboom W, Reinhoudt DN: Chlorosulfonated calix[4]arenes: precursors for neutral anion receptors with a selectivity for hydrogen sulfate. J Org Chem 1993, 58:7602-7605.
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Anion recognition properties of new upper-rim bis[rhenium(I)bipyridyl, ruthenium(II)bis(bipyridyl), cobaltocenium]calix[4]arene receptors dictated by lower-rim substituents
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Beer PD, Drew MGB, Hesek D, Shade M, Szemes F: Anion recognition properties of new upper-rim bis[rhenium(I)bipyridyl, ruthenium(II)bis(bipyridyl), cobaltocenium]calix[4]arene receptors dictated by lower-rim substituents. J Chem Soc Chem Commun 1996:2161-2162. A good illustration of hoave the triggering of one ligand binding capabilities can be induced by long-range topological perturbations.
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33748505651
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Selective anion recognition by novel 5,10,15,20-tetrakis(o-ferrocenyl-carbonylaminophenyl-substituted) zinc metalloporphyrin receptors
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Beer PD, Drew MGB, Jagessar R: Selective anion recognition by novel 5,10,15,20-tetrakis(o-ferrocenyl-carbonylaminophenyl-substituted) zinc metalloporphyrin receptors. J Chem Soc Dalton Trans 1997:881-886.
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J Chem Soc Dalton Trans
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36
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0008040175
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Chloride anion recognition by neutral platinum(II) and palladium(II)5,5′-bis-amide substituted bipyridyl receptor molecules
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Beer PD, Fletcher NC, Drew MGB, Wear TJ: Chloride anion recognition by neutral platinum(II) and palladium(II)5,5′-bis-amide substituted bipyridyl receptor molecules. Polyhedron 1997, 16:815-823.
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Polyhedron
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37
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0000152104
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Luminescent anion recognition: Selective induced emission by binding of dihydrogenphosphate
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Beer PD, Graydon AR, Sutton LR: Luminescent anion recognition: selective induced emission by binding of dihydrogenphosphate. Polyhedron 1996, 15:2457-2461.
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Polyhedron
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33749306615
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Spectral and electrochemical recognition halide anions by acyclic mononuclear ruthenium(II)bipyridyl receptor molecules
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Beer PD, Dent SW, Wear TJ: Spectral and electrochemical recognition halide anions by acyclic mononuclear ruthenium(II)bipyridyl receptor molecules. J Chem Soc Dalton Trans 1996:2341-2346.
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J Chem Soc Dalton Trans
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Szemes F, Hesek D, Chen Z, Dent SW, Drew MGB, Goulden AJ, Graydon AR, Grieve A, Mortimer RJ, Wear T et al.: Synthesis and characterization of novel acyclic, macrocyclic, and calix[4]arene ruthenium(II)bipyridyl receptor molecules that recognize and sense anions. Inorg Chem 1996, 35:5868-5879. The authors present a family of anion receptors based on ruthenium(ll) bipyridyl units exhibiting dual optical and electrochemical sensing capabilities.
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1542712821
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Novel anion binding selectivity trends exhibited by new dinuclear rhenium(I), ruthenium(II) and osmium(II)bipyridyl cleft-type receptors
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Beer PD, Dent SW, Hobbs GS, Wear TJ: Novel anion binding selectivity trends exhibited by new dinuclear rhenium(I), ruthenium(II) and osmium(II)bipyridyl cleft-type receptors. J Chem Soc Chem Commun 1997:99-100.
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J Chem Soc Chem Commun
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0012469593
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Selective fluorimetric recognition of dihydrogen phosphate over chloride anions by a novel ruthenium(II) bipyridyl receptor complex
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Beer PD, Mortimer RJ, Szemes F, Weightman JS: Selective fluorimetric recognition of dihydrogen phosphate over chloride anions by a novel ruthenium(II) bipyridyl receptor complex. Anal Commun 1996, 33:365-366.
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Anal Commun
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1842509219
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Laying traps for elusive preys: Recent advances in the non-covalent binding of anions
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Atwood JL, Holman KT, Steed JW: Laying traps for elusive preys: recent advances in the non-covalent binding of anions. J Chem Soc Chem Commun 1996:1401-1407. By using the outer aromatic surfaces of concave building blocks to anchor organometallic charged centers, the authors built very original rigid receptors which perform shape and size selective anion recognition with remarkable efficiency.
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J Chem Soc Chem Commun
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Holman KT, Haliban MM, Jurisson SS, Atwood JL, Burkhalter RS, Mitchell AR, Steed JW: Inclusion of neutral and anionic guests within the cavity of p-metalated cyclotriveratrylene. J Am Chem Soc 1996, 118:9567-9576. The authors showed that even aromatic concave surfaces can be used to bind anions selectively provided that their electron density is partially withdrawn by yexternally complexed metal centers.
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Molecular recognition of carboxylate ions based on the metal-ligand interaction and signaled through fluorescence quenching
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De Santis G, Fabbrizzi L, Licchelli M, Poggi A, Taglietti A: Molecular recognition of carboxylate ions based on the metal-ligand interaction and signaled through fluorescence quenching. Angew Chem Int Ed 1996, 35:202-204.
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