UNSATCHEM: Unsaturated water and solute transport model with equilibrium and kinetic chemistry

Soil Science Society of America Journal

Volumn 61, Issue 6, 1997, Pages 1633-1646

  Suarez, D L ^a   Simunek J ^a  

^a U S SALINITY LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ION CHEMISTRY; KINETICS; MODEL; SOIL CHEMISTRY; SOLUTE TRANSPORT; UNSATCHEM; WATER TRANSPORT;

CARBON DIOXIDE; CARBONATE MINERALS; FLOW OF WATER; GROUNDWATER; HYDRAULIC CONDUCTIVITY; ION EXCHANGE; MASS TRANSFER; MATHEMATICAL MODELS;

PITZER ION INTERACTION EXPRESSIONS; SOLUTE TRANSPORT PROCESSES;

SOILS;

EID: 0031284223     PISSN: 03615995     EISSN: None     Source Type: Journal    
DOI: 10.2136/sssaj1997.03615995006100060014x     Document Type: Conference Paper

References (62)

1. Amrhein, C., and D.L. Suarez. 1988. The use of a surface complexation model to describe the kinetics of ligand-promoted dissolution of anorthite. Geochim. Cosmochim. Acta 52:2785-2793.
2. Baes, A.U., and P.R. Bloom. 1988. Exchange of divalent cations in soil organic matter. Soil Sci. 14:6-14.
3. Ball, J.W., D.K. Nordstrom, and D.W. Zachmann. 1987. WATEQ4F - A personal computer FORTRAN translation of the geochemical model WATEQ2 with revised data base. U.S. Geol. Surv. Open File Rep. 87 50. U.S. Geol. Surv., Menlo Park, CA.
4. Bell, R.P., and J.H.B. George. 1953. Dissociation of thallus and Ca sulfate salts at different temperatures. Trans. Faraday Soc. 49: 619-627.
5. Bresler, E. 1973. Simultaneous transport of solute and water under transient unsaturated flow conditions. Water Resour. Res. 9:975-986.
6. CO2. Am. J. Sci. 282:45-78.
7. Buyanovsky, G.A., and G.H. Wagner. 1983. Annual cycles of carbon dioxide in soil air. Soil Sci. Soc. Am. J. 47:1139-1245.
8. Chou, L., and R. Wollast. 1985. Steady-state kinetics and dissolution mechanisms of albite. Am. J. Sci. 285:963-993.
9. Clesceri, L.S., A.E. Greenberg, and R.R. Trussell (ed.). 1989. Silica. p 4-181 to 4-191. In Standard methods for the examination of water and wastewater. 17th ed. Am. Public Health Assoc., Washington, DC.
10. Dudley, L.M., R.J. Wagenet, and J.J. Jurinak. 1981. Description of soil chemistry during transient solute transport. Water Resour. Res. 17:1498-1504.
11. Felmy, A.R., and J.H. Weare. 1986. The prediction of borate mineral equilibria in natural waters: Application to Searles Lake, California. Geochim. Cosmochim. Acta 50:2771-2783.
12. Förster, R., and H. Gerke. 1988. Integration von Modellen des Wasserund Stofftransports sowie physikochemischer Wechselwirkungen zur Analyse von Agrar-Ökosystemen. Verh. Ges. Oekol. 18: 515-522.
13. Frenkel, H., J. O. Goertzen, and J.D. Rhoades. 1978. Effects of clay type and content, exchangeable sodium percentage and electrolyte concentration on clay dispersion and soil hydraulic conductivity. Soil Sci. Soc. Am. J. 42:32-39.
14. 3 and BeO. Geochim. Cosmochim Acta 50:1847-1860.
15. Goldberg, S. 1993. Chemistry and mineralogy of boron in soils p. 3-44. In U.C. Gupta (ed.) Boron and its role in crop production. CRC Press, Ann Arbor, MI.
16. Goldberg, S., and R.A. Glaubig. 1985. Boron adsorption on aluminum and iron oxide minerals. Soil Sci. Soc. Am. J. 49:1374-1379.
17. Hillel, D., and C.H.M. van Bavel. 1976. Simulation of profile water storage as related to soil hydrologic properties. Soil Sci. Soc. Am. J. 40:807-815.
18. 2 less than 0.01 atm and pH greater than 8. Geochim. Cosmochim. Acta 49:2165-2180.
19. Inskeep, W.P., and P.R. Bloom. 1986. Kinetics of calcite precipitation in the presence of water-soluble organic ligands. Soil Sci. Soc. Am. J. 50:1167-1172.
20. 3 from 0 to 50°C Ph D. diss. Pennsylvania State Univ., University Park (Diss. Abstr. 74-04250).
21. Jennings, A.A., D.J. Kirkner, and T.L. Theis. 1982. Multicomponent equilibrium chemistry in groundwater quality models. Water Resour. Res. 18:1089-1096.
22. Jury, W.A., H. Frenkel, and L.H. Stolzy. 1978. Transient changes in the soil water system from irrigation with saline water: I. Theory. Soil Sci. Soc. Am. J. 42:579-584.
23. Lebron, I., and D.L. Suarez. 1996. Calcite nucleation and precipitation kinetics as affected by dissolved organic matter at 25°C and pH > 7.5. Geochem. Cosmochim Acta 60:2765-2776.
24. McNeal, B.L. 1968. Prediction of the effect of mized-salt solutions on soil hydraulic conductivity. Soil Sci. Soc. Am. Proc. 32:190-193.
25. Miller, C.W., and L.V. Benson. 1983. Simulation of solute transport in a chemically reactive heterogeneous system: Model development and application. Water Resour. Res. 19:381-391.
26. Mualem, Y. 1976. A new model for predicting the hydraulic conductivity of unsaturated porous media. Water Resour. Res 12:513-522.
27. Narasimhan, T.N., A.F. White, and T. Tokunaga. 1986. Groundwater contamination from an inactive uranium mill tailings pile. 2: Application of a dynamic mixing model. Water Resour. Res. 22: 1820-1834.
28. Pratt, P.F. 1957. The effect of fertilizers and organic materials on the cation-exchange capacity of an irrigated soil. Soil Sci. 83:85-89.
29. Pitzer, K.S. 1979. Theory: Ion interaction approach, p. 157-208. In R.M. Pytkowicz (ed.) Activity coefficients in electrolyte solutions. Vol. 1, CRC Press, Boca Raton, FL.
30. 2O Geochim. Cosmochim. Acta 46:1011-1040.
31. 2. Am. J. Sci. 278:179-216.
32. Reardon, E.J. 1974. Thermodynamic properties of some sulfate, carbonate and bicarbonate ion pairs. Ph.D. diss. Pennsylvania State Univ., University Park (Diss. Abstr. 75-09830).
33. 3 from 10 to 50°C. Am. J. Sci. 274:599-612.
34. 4 ion pairs as a function of ionic strength. Geochim. Cosmochim. Acta 40:549-554.
35. Robbins, C.W., R.J. Wagenet, and J.J. Jurinak. 1980a. A combined salt transport-chemical equilibrium model for calcareous and gypsiferous soils. Soil Sci. Soc. Am. J. 44:1191-1194.
36. Robbins, C.W., R.J. Wagenet, and J.J. Jurinak. 1980b. Calculating cation exchange in a salt transport model. Soil Sci. Soc. Am. J. 44:1195-1200.
37. Robinson, R.A., and R.H. Stokes. 1965. Electrolyte solutions. Butterworths, London.
38. Russo, D. 1986. Simulation of leaching of a gypsiferous-sodic desert soil. Water Resour. Res. 22:1341-1349.
39. Schulz, H.D., and E.J. Reardon. 1983. A combined mixing cell/analytical model to describe two-dimensional reactive solute transport for unidirectional groundwater flow. Water Resour. Res. 19:493-502.
40. Šimůnek, J., and D.L. Suarez. 1993. Modeling of carbon dioxide transport and production in soil: 1. Model development. Water Resour. Res. 29:487-497.
41. Šimůnek, J., and D.L. Suarez. 1994. Two-dimensional transport model for variably saturated porous media with major ion chemistry. Water Resour. Res. 30:1115-1133.
42. Stumm, W., and J.J. Morgan. 1981. Aquatic chemistry: An introduction emphasizing chemical equilibria in natural waters. John Wiley & Sons, New York.
43. Suarez, D.L. 1977a. Ion activity products of calcium carbonate in waters below the root zone. Soil Sci. Soc. Am. J. 41:310-315.
44. Suarez, D.L. 1977b. Magnesium, carbonate, and silica interactions in soils. U.S. Salinity Lab. Annual Rep. USDA-ARS, U.S. Salinity Lab., Riverside, CA.
45. Suarez, D.L. 1983. Calcite supersaturation and precipitation kinetics in the lower Colorado River. All-American Canal and Highline Canal. Water Resour. Res. 19:653-661.
46. Suarez, D.L. 1985. Prediction of major ion concentrations in arid land soils using equilibrium and kinetic theories. In D. DeCoursey (ed.) Proc. Nat. Resour. Modeling Symp., Pingree Park, CO. 1983. USDA-ARS-30. U.S. Gov. Print. Office, Washington, DC.
47. Suarez, D.L., A.M. Aboushal, and J.D. Wood. 1994. Predicting Ca-Na exchange selectivities of smetitic soils, p. 258. In Agronomy abstracts. ASA, Madison, WI.
48. Suarez, D.L., J.D. Rhoades, R. Lavado, and C.M. Grieve. 1984. Effect of pH on saturated hydraulic conductivity and soil dispersion. Soil Sci. Soc. Am. J. 48:50-55.
49. Suarez, D.L., and J. Šimůnek. 1993. Modeling of carbon dioxide transport and production in soil: 2. Parameter selection, sensitivity analysis and comparison of model predictions to field data. Water Resour. Res. 29:499-513.
50. Suarez, D.L., and J.D. Wood. 1993. Predicting Ca-Mg exchange selectivities of smetitic soils. p. 236. In Agronomy abstracts. ASA, Madison, WI.
51. Suarez, D.L., and J.D. Wood. 1996. Short-and long-term weathering rates of a feldspar fraction isolated from an arid zone soil. Chem. Geol. 132:143-150.
52. Suarez, D.L., J.D. Wood, and I. Ibrahim. 1992. Reevaluation of calcite supersaturation in soils. Soil Sci. Soc. Am. J. 56:1776-1784.
53. Suarez, D.L., and M. Zahow. 1989. Calcium-magnesium exchange selectivity of Wyoming montmorillonite in chloride, sulfate, and perchlorate solutions. Soil Sci. Soc. Am. J. 53:52-57.
54. Sverdrup, H.U., and P. Warfvinge. 1988. Weathering of primary silicate minerals in the natural soil environment in relation to a chemical weathering model. Water Air Soil Pollut. 38:397-408.
55. Swoboda-Colberg, N.G., and J.I. Drever. 1993. Mineral dissolution rates in plot-scale field and laboratory experiments. Chem. Geol. 105:51-69.
56. Truesdell, A.M., and B.F. Jones. 1974. Wateq, a computer program for calculating chemical equilibria of natural waters. J. Res. U.S. Geol. Surv. 2:233-248.
57. van Genuchten, M.Th. 1980. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Soil Sci. Soc. Am. J. 44:892-898.
58. Wagenet, R.J., and J.L. Hutson. 1987. LEACHM: A finite-difference model for simulating water, salt, and pesticide movement in the plant root zone. Continuum 2. N.Y. State Resour. Inst., Cornell Univ., Ithaca, NY.
59. Walsh, M.P., S.L. Bryant, R.S. Schechter, and L.W. Lake. 1984. Precipitation and dissolution of solids attending flow through porous media. AIChE J. 30:317-328.
60. White, N., and L.W. Zelazny. 1986. Charge properties in soil colloids. p. 39-81. In D.L. Sparks (ed.) Soil physical chemistry. CRC Press, Boca Raton, FL.
61. Yeh, G.T., and V.S. Tripathi. 1989. A critical evaluation of recent developments in hydrogeochemical transport models of reactive multichemical components. Water Resour. Res. 25:93-108.
62. Yeh, G.T., and V.S. Tripathi. 1991. A model for simulating transport of reactive multispecies components: Model development and demonstration. Water Resour. Res. 27:3075-3094.