Synthesis of uniform microspheres with higher content of 2-hydroxyethyl methacrylate by employing SPG (Shirasu porous glass) emulsification technique followed by swelling process of droplets

Journal of Applied Polymer Science

Volumn 66, Issue 7, 1997, Pages 1325-1341

  Ma, Guang Hui ^a   Nagai, Masatoshi ^a   Omi, Shinzo ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

2 hydroxyethyl methacrylate; Emulsification; Hydrophilic monomer; Shirasu porous glass; Swelling of droplets

Indexed keywords

COMPOSITION EFFECTS; EMULSIFICATION; GLASS; MORPHOLOGY; PHASE COMPOSITION; POROUS MATERIALS; SWELLING; SYNTHESIS (CHEMICAL);

MICROSPHERES; SHIRASU POROUS GLASS; UNIFORM SEED DROPLETS METHOD;

MONOMERS;

EID: 0031281236     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4628(19971114)66:7<1325::AID-APP11>3.0.CO;2-1     Document Type: Article

References (29)

1. H. J. Sanders, Chem. Eng. News, Apr. 1, 31 (1985).
2. K. M. Scholsky and R. M. Fitch, J. Control. Release, 3, 87 (1986).
3. H. Kawaguchi, H. Amagasa, T. Hagiya, N. Kimura, and Y. Ohtsuka, Colloids Surf., 13, 295 (1985).
4. S. Omi, K. Kaneko, M. Takesue, H. Tsujimura, A. Sato, and M. Iso, J. Appl. Polym. Sci., 51, 1239 (1994).
5. T. Imai, Y. Sumi, M. Hatakeyama, K. Fujimoto, H. Kawaguchi, N. Hayashida, K. Shiozaki, K. Terada, H. Hajima, and H. Handa, J. Colloid Interf. Sci., 177, 245 (1996).
6. Y. Kasuya, K. Fujimoto, H. Kawaguchi and M. Miyamoto, Biomaterials, 15, 570 (1994).
7. Y. Nakao, M. Yabuta, and A. Tominaga, Prog. Org. Coat., 20, 369 (1992).
8. E. G. Bobalek, E. R. Moore, S. S. Kevy, and C. C. Lee, J. Appl. Polym. Sci., 8, 625 (1964).
9. J. Kumano, H. Hironori, and Hisakazu, Polym. Prepr. Jpn., 29(6), 1081 (1980).
10. K. Makuuchi, A. Katakai, and N. Nakayama, Radiat. Phys. Chem., 18, 623 (1980).
11. K. Makuuchi, A. Katakai, and N. Nakayama, J. Coat. Tech., 55, 28 (1983).
12. T. Shiraishi, T. Ishiguro, T. Yoneda, T. Kagiya, and T. Nomura, Polym. Prepr. Jpn., 29(3), 406 (1980).
13. C. M. Miller, J. Venkatesan, C. A. Sibeli, E. D. Sudol, and M. S. El-Aasser, J. Colloid Interf. Sci., 162, 11 (1994).
14. W. D. Harkins, J. Chem. Phys., 13, 381 (1945).
15. F. Hoshino, H. Kawaguchi, and Y. Ohtsuka, Polym. J., 19, 1157 (1987).
16. J. Ugelstad, P. C. Mork, K. H. Kaggerud, T. Ellingsen, and A. Berge, Adv. Colloid Interf. Sci., 13, 101 (1980).
17. M. Okubo, M. Shiozaki, M. Tsujihiro, and Y. Tsukuda, Colloid Polym. Sci., 269, 222 (1991).
18. M. Okubo, K. Kanaida, and M. Fujimura, Colloid Polym. Sci., 269, 1257 (1991).
19. S. Omi, K. Katami, A. Yamamoto, and M. Iso, J. Appl. Polym. Sci., 51, 1 (1994).
20. S. Omi, K. Katami, T. Taguchi, K. Kaneko, and M. Iso, J. Appl. Polym. Sci., 57, 1013 (1995).
21. S. Omi, K. Katami, T. Taguchi, K. Kaneko, and M. Iso, Makromol. Symp., 92, 309 (1995).
22. S. Omi, T. Taguchi, M. Nagai, and G.-H. Ma, J. Appl. Polym. Sci., 63, 931 (1997).
23. S. Omi, Colloids Surf. A Physicochem. Eng. Aspects, 109, 97 (1996).
24. K. Kataoka, T. Okano, N. Yui, and Y. Sakurai, in Bio-compatible Polymer, The Society of Polymer Science, Japan, Ed., Kyoritushuppan, Tokyo, 1988.
25. M. Okubo, H. Hattori, and I. Azuma, in 6th Polymeric Microspheres Symposium (Japan), Nov. 8-10, 1990, pp. 143-146.
26. M. Sakagawa, K. Fujimoto, and H. Kawaguchi, in 8th Polymeric Microspheres Symposium (Japan), Nov. 9-11, 1994, pp. 79-82.
27. H. R. Sheu, M. S. El-Aasser, and J. W. Vanderhoff, J. Polym. Sci. Polym. Chem. Ed., 28, 629 (1990).
28. K. Arai, G.-H. Ma, and T. Hirata, J. Appl. Polym. Sci., 42, 1125 (1991).
29. G.-H. Ma and T. Fukutomi, J. Appl. Polym. Sci., 43, 1451 (1991).