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Volumn 13, Issue 24, 1997, Pages 6366-6369

Wetting-induced reconstruction in molecular surfaces

Author keywords

[No Author keywords available]

Indexed keywords

CONTACT ANGLE; MOLECULAR DYNAMICS; MONOLAYERS; PHASE TRANSITIONS; SURFACE TREATMENT; WETTING;

EID: 0031275322     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la970917k     Document Type: Article
Times cited : (20)

References (37)
  • 10
    • 0026865919 scopus 로고
    • Folkers, J. P.; Laibinis, P. E.; Whitesides, G. M. Langmuir 1992, 8, 1330-1341. Folkers, J. P.; Laibinis, P. E.; Whitesides, G. M. J. Adhes. Sci. Technol. 1992, 6, 1397-1410.
    • (1992) Langmuir , vol.8 , pp. 1330-1341
    • Folkers, J.P.1    Laibinis, P.E.2    Whitesides, G.M.3
  • 16
    • 0001275772 scopus 로고
    • Good, R. J.; Kotsidas, E. D. J. Adhes. 1979, 10, 17; J. Colloid Interface Sci. 1978, 66, 360.
    • (1978) J. Colloid Interface Sci. , vol.66 , pp. 360
  • 24
    • 5244338764 scopus 로고    scopus 로고
    • note
    • For convenience, we have modeled the -O- moiety in our simulations by employing the parameters for -S- (using model II) from ref 21.
  • 31
    • 5244230783 scopus 로고    scopus 로고
    • note
    • In past work, Klein (see ref 20) had suggested that solvents which had high contact angles would spontaneously self-assemble into drops on the solid surface. The contact angle of the drop of liquid with the substrate could then be determined through standard geometry. In our simulations we do observe the solvent self-assembling into a drop in all cases where non-zero contact angles are predicted. However, the drop shapes show fluctuations too large to allow accurate estimates of contact angles. Consequently, this methodology (ref 20) does not appear to be appropriate in the context where one deals with relatively small contact angles.
  • 32
    • 0001194138 scopus 로고
    • Harris, J. G. J. Phys. Chem. 1992, 96, 5077. Chen, L.-J. J. Chem. Phys. 1995, 103, 10214.
    • (1992) J. Phys. Chem. , vol.96 , pp. 5077
    • Harris, J.G.1
  • 33
    • 0001643694 scopus 로고
    • Harris, J. G. J. Phys. Chem. 1992, 96, 5077. Chen, L.-J. J. Chem. Phys. 1995, 103, 10214.
    • (1995) J. Chem. Phys. , vol.103 , pp. 10214
    • Chen, L.-J.1
  • 34
    • 33746012315 scopus 로고
    • Cahn, J. W.; Hilliard, J. E. J. Chem. Phys. 1955, 28, 258. We have utilized a variety of K values ranging from 0.4 to 0.6 and found that the n value where S for HD changed sign was relatively unaffected. Consequently, our results are not significantly sensitive to the precise value of this parameter.
    • (1955) J. Chem. Phys. , vol.28 , pp. 258
    • Cahn, J.W.1    Hilliard, J.E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.