Reactivity of CO2 during Thermal Cracking of Heavy Paraffins under Supercritical Conditions

Industrial and Engineering Chemistry Research

Volumn 36, Issue 11, 1997, Pages 4445-4451

  Karakas, Gurkan ^a,b   Dogu, Timur ^a   Somer, Tarik G ^a  

^a MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

^b OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; FATTY ACIDS; OLEFINS; PRESSURE EFFECTS; REACTION KINETICS; STEAM CRACKING; THERMAL EFFECTS;

SUPERCRITICAL CONDITIONS; THERMAL CRACKING;

PARAFFINS;

EID: 0031270831     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970128y     Document Type: Article

References (25)

1. Albright, L. F.; Crynes, B. L.; Corcoran, W. H. Pyrolysis: Theory and Industrial Practice; Academic Press: New York, 1983.
2. Behr, A. Catalytic Reductions of Carbon Dioxide with Hydrocarbons. NATO ASI Ser. 1987, C206, 295.
3. Depeyre, D.; Flicteaux, C. Modeling of Thermal Steam Cracking of n-Hexadecane. Ind. Eng. Chem. Res. 1991, 30, 1116-1130.
4. Depeyre, D.; Flicoteaux, C.; Chardaire, C. Pure n-Hexadecane Thermal Steam Cracking. Ind. Eng. Chem. Process Des. Dev. 1985, 24, 1251-1258.
5. Fabuss, B. M.; Smith, J. O.; Lait, R. I.; Borsanyi, A. S.; Satterfield, C. N. Rapid Thermal Cracking of n-Hexadecane at Elevated Pressures. Ind. Eng. Chem. Process Des. Dev. 1962, 1 (4), 293-299.
6. Fabuss, B. M.; Smith, J. O.; Satterfield, C. N. Thermal Cracking of Pure Saturated Hydrocarbons. Adv. Pet. Chem. Refin. 1964, 9, 157-201.
7. Ford, T. J. Liquid Phase Thermal Decomposition of Hexadecane: Reaction Mechanisms. Ind. Eng. Chem. Fundam. 1986, 25, 240-243.
8. Greensfelder, B. S.; Voge, H. H. Catalytic and Thermal Cracking of Pure Paraffins. Ind. Eng. Chem. 1949, 41, 2573.
9. Karakas, G. Thermal Cracking Kinetics of the Heavy Paraffins in the Presence of Carbon Dioxide Under Subcritical and Supercritical Conditions. Ph.D. Dissertation, Chemical Enginnering Department Middle East Technical University, Ankara, Turkey, 1995.
10. Khorasheh, F.; Gray, M. R. High Pressure Thermal Cracking of n-Hexadecane. Ind. Eng Chem. Process Des. Dev. 1993, 32, 1853-1864.
11. Kissin, Y. V. Free Radical Reactions of High Molecular Weight Isoalkanes. Ind. Eng. Chem. Res. 1987, 26, 1633-1638.
12. Kossiakoff, A.; Rice, F. O. Thermal Decomposition of Hydrocarbons Resonance Stabilization and Isomerization of Free Radicals. J. Am. Chem. Soc. 1934, 56, 284.
13. Krylov, O. V.; Mamedov, A. Kh.; Mirzabekova, S. R. Catalytic Oxidation of Hydrocarbons and Alcohols by Carbon Dioxide on Oxide Catalyst. Ind. Eng. Chem. Res. 1995, 34 (2), 474.
14. Mushrush, G. W.; Hazlett, R. N. Pyrolysis of Organic Compounds Containing Long Unbranched Alkyl Groups. Ind. Eng. Chem. Fundam. 1984, 23, 288-294.
15. Peng, D. Y.; Robinson, D. B. A Rigorous Method for Predicting the Critical Properties of Multicomponent Systems from an Equation of State. AIChE J. 1977, 23 (2), 137.
16. Rebick, C. Pyrolysis of Heavy Hydrocarbons. Pyrolysis: Theory and Industrial Practice; Academic Press: New York, 1983; pp 69-87.
17. Spee, M.; Schnieder, G. M. Fluid Phase Equilibrium Studies on Binary and Ternary Mixtures of Carbon Dioxide with Hexadecane, 1-Dodecanol, 1,8-Octanediol and Dotriacontane at 393.2 K and at Pressures up to 100 MPa. Fluid Phase Equilib. 1991, 65, 263.
18. 22). Ind. Eng. Chem. Res. 1987, 26, 846.
19. 2 as an Oxidant over PbO-MgO. J. Catal. 1990, 122, 346.
20. Tiltscher, H.; Wolf, H.; Schelchshorn, J. Utilization of Supercritical Fluid Solvent Effects in Heterogeneous Catalysis. Ber. Bunsen-Ges. Phys. Chem. 1984, 88, 897.
21. Tsai, C. H.; Albright, L. F. Surface Reactions Occuring During Pyrolysis of Light Paraffins. ACS Symp. Ser. 1976, 32, 274.
22. Voge, H. H.; Good, G. M. Thermal Cracking of Higher Paraffins. J. Am. Chem. Soc. 1949, 71, 593-597.
23. Wilkes, J. B. Production of Carboxylic Acids from Paraffins and Carbon Dioxide. U.S. Patent 4,016,185, 1977.
24. Wu, G.; Katsumura, Y.; Matsuura, C.; Ishigure, K.; Kubo, J. Comparison of Liquid-Phase and Gas-Phase Pure Thermal Cracking of n-Hexadecane. Ind. Eng. Chem. Res. 1996, 35, 4747-4754.
25. Zhou, P.; Hoolis, O. L.; Crynes, B. L. Thermolysis of Higher Molecular Weight Straight-Chain Alkanes. Ind. Eng. Chem. Res. 1987, 26, 846-852.