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Volumn 107, Issue 19, 1997, Pages 7746-7761

Nonresonant dielectric hole burning spectroscopy of supercooled liquids

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; CARBONATES; COMPUTER SIMULATION; DIELECTRIC RELAXATION; ELECTRIC FIELDS; GLASS TRANSITION; GLYCEROL; LIQUIDS; MATHEMATICAL MODELS; MOLECULES; REACTION KINETICS;

EID: 0031269003     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475089     Document Type: Article
Times cited : (152)

References (98)
  • 11
    • 0001098050 scopus 로고
    • R. V. Chamberlin, Phys. Rev. B 48, 15638 (1993); R. V. Chamberlin and D. W. Kingsbury, J. Non-Cryst. Solids 172-174, 318 (1994).
    • (1993) Phys. Rev. B , vol.48 , pp. 15638
    • Chamberlin, R.V.1
  • 28
  • 29
    • 85033177341 scopus 로고    scopus 로고
    • in press
    • R. Böhmer, G. Hinze, G. Diezemann, B. Geil, and H. Sillescu, Europhys. Lett. 36, 55 (1996); R. Böhmer, G. Diezemann, G. Hinze, and H. Sillescu, J. Chem. Phys. (submitted); R. Böhmer, Phase Trans. (in press).
    • Phase Trans.
    • Böhmer, R.1
  • 33
    • 85033179800 scopus 로고    scopus 로고
    • note
    • g. Photobleaching experiments, however, seem to be feasible at higher temperatures (see Ref. 24).
  • 34
    • 29744443730 scopus 로고
    • -3) it is possible albeit not easy to study the α-process of orthoterphenyl using dielectric methods,' see G. P. Johari and M. Goldstein, J. Chem. Phys. 53, 2372 (1970); R. Riehert, Rev. Sci. Instrum. 67, 3217 (1996).
    • (1970) J. Chem. Phys. , vol.53 , pp. 2372
    • Johari, G.P.1    Goldstein, M.2
  • 35
    • 0030247492 scopus 로고    scopus 로고
    • -3) it is possible albeit not easy to study the α-process of orthoterphenyl using dielectric methods,' see G. P. Johari and M. Goldstein, J. Chem. Phys. 53, 2372 (1970); R. Riehert, Rev. Sci. Instrum. 67, 3217 (1996).
    • (1996) Rev. Sci. Instrum. , vol.67 , pp. 3217
    • Riehert, R.1
  • 41
    • 0028499301 scopus 로고
    • M. M. Santore, R. S. Duran, and G. B. McKenna, Polymer 32, 2377 (1991); G. B. McKenna, J. Non-Cryst. Solids 172-174, 756 (1994).
    • (1994) J. Non-Cryst. Solids , vol.172-174 , pp. 756
    • McKenna, G.B.1
  • 43
    • 0022739150 scopus 로고
    • G. B. McKenna and L. J. Zapas, J. Polym. Sci., Polym. Phys. Ed. 23, 1647 (1985); Polymer Eng. Sci. 26, 725 (1986); W. K. Waldron, Jr., and G. B. McKenna, J. Rheol. 39, 471 (1995).
    • (1986) Polymer Eng. Sci. , vol.26 , pp. 725
  • 44
    • 0029271972 scopus 로고
    • G. B. McKenna and L. J. Zapas, J. Polym. Sci., Polym. Phys. Ed. 23, 1647 (1985); Polymer Eng. Sci. 26, 725 (1986); W. K. Waldron, Jr., and G. B. McKenna, J. Rheol. 39, 471 (1995).
    • (1995) J. Rheol. , vol.39 , pp. 471
    • Waldron Jr., W.K.1    McKenna, G.B.2
  • 46
    • 0029274708 scopus 로고
    • I. M. Hodge, Science 267, 1945 (1995).
    • (1995) Science , vol.267 , pp. 1945
    • Hodge, I.M.1
  • 50
    • 51649144432 scopus 로고    scopus 로고
    • R. Böhmer, B. Schiener, J. Hemberger, and R. V. Chamberlin, Z. Phys. B 99, 91 (1995); ibid. 99, 624 (1996).
    • (1996) Z. Phys. B , vol.99 , pp. 624
  • 53
    • 0028416385 scopus 로고
    • and references cited therein
    • I. M. Hodge, J. Non-Cryst. Solids 169, 211 (1994) and references cited therein.
    • (1994) J. Non-Cryst. Solids , vol.169 , pp. 211
    • Hodge, I.M.1
  • 55
    • 85033172581 scopus 로고    scopus 로고
    • note
    • It cannot be excluded that the relevant effective energy barrier depends on the index i, nevertheless in the following we will neglect any such dependence.
  • 56
    • 0020252103 scopus 로고    scopus 로고
    • E. Donth, J. Non-Cryst. Solids 53, 325 (1982); J. Polym. Sci., Polym. Phys. Ed. 34, 2881 (1996).
    • (1982) J. Non-Cryst. Solids , vol.53 , pp. 325
    • Donth, E.1
  • 57
    • 0020252103 scopus 로고    scopus 로고
    • E. Donth, J. Non-Cryst. Solids 53, 325 (1982); J. Polym. Sci., Polym. Phys. Ed. 34, 2881 (1996).
    • (1996) J. Polym. Sci., Polym. Phys. Ed. , vol.34 , pp. 2881
  • 60
    • 0021202720 scopus 로고
    • The circuit we use is similar to the one described by F. I. Mopsik, Rev. Sci. Instrum. 55, 79 (1984).
    • (1984) Rev. Sci. Instrum. , vol.55 , pp. 79
    • Mopsik, F.I.1
  • 62
    • 85033181502 scopus 로고    scopus 로고
    • note
    • 0), solely due the periodic motion of the capacitor plates. This (unwanted) contribution to the third harmonic signal is often comparable in magnitude to the nonlinear effects caused by the sample itself.
  • 66
    • 85033184813 scopus 로고    scopus 로고
    • note
    • It should be noted that for propylene carbonate small deviations from linearity are seen for pump voltages in excess of 1 kV. We were unable to observe corresponding effects in glycerol which is presumably due to its smaller dipole moment.
  • 67
    • 85033189767 scopus 로고    scopus 로고
    • note
    • g).
  • 68
    • 85033176812 scopus 로고    scopus 로고
    • note
    • Only for g(τ)=const would the variation of Ω and that of the frequency of the inflection point in Δε″ be equally large.
  • 69
    • 85033187525 scopus 로고    scopus 로고
    • note
    • r cannot be ruled out, cf. Ref. 33.
  • 73
    • 85033183160 scopus 로고    scopus 로고
    • note
    • Sometimes this statement applies to the mean time scales only, see Ref. 62.
  • 74
    • 85033189034 scopus 로고    scopus 로고
    • note
    • One is tempted to conclude that T-jump experiments are intrinsically nonlinear because for all ΔT≠0 (typically ΔT>0.5 K) the measured enthalpy response is significantly different from that extrapolated to ΔT=0. Within a given experimental uncertainty linearity can be operationally defined for sufficiently small ΔT even under these conditions.
  • 79
    • 0030217476 scopus 로고    scopus 로고
    • as well as Ref. 4 and the literature cited in these reviews
    • See, M. D. Ediger, C. A. Angell, and S. R. Nagel, J. Phys. Chem. 100, 13200 (1996) as well as Ref. 4 and the literature cited in these reviews.
    • (1996) J. Phys. Chem. , vol.100 , pp. 13200
    • Ediger, M.D.1    Angell, C.A.2    Nagel, S.R.3
  • 80
    • 0001475683 scopus 로고
    • Potential candidates if suitably developed further appear to be x-ray-photon correlation spectroscopy, see e.g., S. B. Dierker, R. Pindak, R. M. Fleming, I. K. Robinson, and L. Berman, Phys. Rev. Lett. 75, 449 (1995) and some NMR experiments employing the spin-diffusion tool; see e.g., K.-L. Li, A. A. Jones, P. T. Inglefield, and A. D. English, Macromolecules 22, 4198 (1988); K. Schmidt-Rohr and H. W. Spiess, Multidimensional Solid-State NMR and Polymers (Academic, London, 1994), Ch. 13.
    • (1995) Phys. Rev. Lett. , vol.75 , pp. 449
    • Dierker, S.B.1    Pindak, R.2    Fleming, R.M.3    Robinson, I.K.4    Berman, L.5
  • 81
    • 0024767779 scopus 로고
    • Potential candidates if suitably developed further appear to be x-ray-photon correlation spectroscopy, see e.g., S. B. Dierker, R. Pindak, R. M. Fleming, I. K. Robinson, and L. Berman, Phys. Rev. Lett. 75, 449 (1995) and some NMR experiments employing the spin-diffusion tool; see e.g., K.-L. Li, A. A. Jones, P. T. Inglefield, and A. D. English, Macromolecules 22, 4198 (1988); K. Schmidt-Rohr and H. W. Spiess, Multidimensional Solid-State NMR and Polymers (Academic, London, 1994), Ch. 13.
    • (1988) Macromolecules , vol.22 , pp. 4198
    • Li, K.-L.1    Jones, A.A.2    Inglefield, P.T.3    English, A.D.4
  • 82
    • 0001475683 scopus 로고
    • Academic, London, Ch. 13
    • Potential candidates if suitably developed further appear to be x-ray-photon correlation spectroscopy, see e.g., S. B. Dierker, R. Pindak, R. M. Fleming, I. K. Robinson, and L. Berman, Phys. Rev. Lett. 75, 449 (1995) and some NMR experiments employing the spin-diffusion tool; see e.g., K.-L. Li, A. A. Jones, P. T. Inglefield, and A. D. English, Macromolecules 22, 4198 (1988); K. Schmidt-Rohr and H. W. Spiess, Multidimensional Solid-State NMR and Polymers (Academic, London, 1994), Ch. 13.
    • (1994) Multidimensional Solid-State NMR and Polymers
    • Schmidt-Rohr, K.1    Spiess, H.W.2
  • 83
    • 3743138150 scopus 로고
    • D. J. Salvino, S. Rogge, B. Tigner, and D. D. Osheroff, Phys. Rev. Lett. 73, 268 (1994). This article is remarkable since it reports on the formation of "holes" not under the action of ac-fields, but using dc voltages applied during cool-down.
    • (1994) Phys. Rev. Lett. , vol.73 , pp. 268
    • Salvino, D.J.1    Rogge, S.2    Tigner, B.3    Osheroff, D.D.4
  • 85
    • 3743048866 scopus 로고
    • C. Laermans, W. Arnold, and S. Hunklinger, J. Phys. C 10, L161 (1977); M. v. Schickfus and S. Hunklinger, Phys. Lett. 64A, 144 (1977).
    • (1977) Phys. Lett. , vol.64 A , pp. 144
    • Schickfus, M.V.1    Hunklinger, S.2
  • 87
    • 3743067950 scopus 로고
    • J. Friedrich and D. Haarer, Angew. Chem. 96, 96 (1984) [Angew. Chem. Int. Ed. Engl. 23, 113 (1984)].
    • (1984) Angew. Chem. Int. Ed. Engl. , vol.23 , pp. 113
  • 91
    • 0001766388 scopus 로고
    • P. Jones, P. Darcy, G. S. Attard, W. J. Jones, and G. Williams, Mol. Phys. 67, 1053 (1989); A. Kozak and G. Williams, ibid. 67, 1065 (1989); P. Jones, W. J. Jones, and G. Williams, J. Chem. Soc. Faraday Trans. 86, 1013 (1990).
    • (1989) Mol. Phys. , vol.67 , pp. 1053
    • Jones, P.1    Darcy, P.2    Attard, G.S.3    Jones, W.J.4    Williams, G.5
  • 92
    • 0000877303 scopus 로고
    • P. Jones, P. Darcy, G. S. Attard, W. J. Jones, and G. Williams, Mol. Phys. 67, 1053 (1989); A. Kozak and G. Williams, ibid. 67, 1065 (1989); P. Jones, W. J. Jones, and G. Williams, J. Chem. Soc. Faraday Trans. 86, 1013 (1990).
    • (1989) Mol. Phys. , vol.67 , pp. 1065
    • Kozak, A.1    Williams, G.2
  • 93
    • 0000996013 scopus 로고
    • P. Jones, P. Darcy, G. S. Attard, W. J. Jones, and G. Williams, Mol. Phys. 67, 1053 (1989); A. Kozak and G. Williams, ibid. 67, 1065 (1989); P. Jones, W. J. Jones, and G. Williams, J. Chem. Soc. Faraday Trans. 86, 1013 (1990).
    • (1990) J. Chem. Soc. Faraday Trans. , vol.86 , pp. 1013
    • Jones, P.1    Jones, W.J.2    Williams, G.3
  • 94
    • 0001604312 scopus 로고
    • M. T. Cicerone and M. D. Ediger, J. Phys. Chem. 97, 10489 (1993). Note that through a clever handling of the bleach depth not only orientational but also spectral selection is possible, see Ref. 24.
    • (1993) J. Phys. Chem. , vol.97 , pp. 10489
    • Cicerone, M.T.1    Ediger, M.D.2
  • 97
    • 0000369191 scopus 로고
    • This does not imply that the molecules themselves are not able to perform anisotropic motions, see e.g., G. Hinze, H. Sillescu, and F. Fujara, Chem. Phys. Lett. 232, 154 (1995).
    • (1995) Chem. Phys. Lett. , vol.232 , pp. 154
    • Hinze, G.1    Sillescu, H.2    Fujara, F.3
  • 98
    • 0023962284 scopus 로고
    • See, e.g., T. Furukawa, M. Tada, K. Nakajima, and I. Seo, Jpn. J. Appl. Phys. 27, 200 (1988). In this article large amplitude electrical fields were used to probe nonlinear susceptibilities. Effects of an inhomogeneous input of energy were not discussed.
    • (1988) Jpn. J. Appl. Phys. , vol.27 , pp. 200
    • Furukawa, T.1    Tada, M.2    Nakajima, K.3    Seo, I.4


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