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g. Photobleaching experiments, however, seem to be feasible at higher temperatures (see Ref. 24).
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85033172581
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note
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It cannot be excluded that the relevant effective energy barrier depends on the index i, nevertheless in the following we will neglect any such dependence.
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60
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The circuit we use is similar to the one described by F. I. Mopsik, Rev. Sci. Instrum. 55, 79 (1984).
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85033181502
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note
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0), solely due the periodic motion of the capacitor plates. This (unwanted) contribution to the third harmonic signal is often comparable in magnitude to the nonlinear effects caused by the sample itself.
-
-
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65
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20644438312
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and references cited therein
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85033184813
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note
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It should be noted that for propylene carbonate small deviations from linearity are seen for pump voltages in excess of 1 kV. We were unable to observe corresponding effects in glycerol which is presumably due to its smaller dipole moment.
-
-
-
-
67
-
-
85033189767
-
-
note
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g).
-
-
-
-
68
-
-
85033176812
-
-
note
-
Only for g(τ)=const would the variation of Ω and that of the frequency of the inflection point in Δε″ be equally large.
-
-
-
-
69
-
-
85033187525
-
-
note
-
r cannot be ruled out, cf. Ref. 33.
-
-
-
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73
-
-
85033183160
-
-
note
-
Sometimes this statement applies to the mean time scales only, see Ref. 62.
-
-
-
-
74
-
-
85033189034
-
-
note
-
One is tempted to conclude that T-jump experiments are intrinsically nonlinear because for all ΔT≠0 (typically ΔT>0.5 K) the measured enthalpy response is significantly different from that extrapolated to ΔT=0. Within a given experimental uncertainty linearity can be operationally defined for sufficiently small ΔT even under these conditions.
-
-
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79
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0030217476
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as well as Ref. 4 and the literature cited in these reviews
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See, M. D. Ediger, C. A. Angell, and S. R. Nagel, J. Phys. Chem. 100, 13200 (1996) as well as Ref. 4 and the literature cited in these reviews.
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Potential candidates if suitably developed further appear to be x-ray-photon correlation spectroscopy, see e.g., S. B. Dierker, R. Pindak, R. M. Fleming, I. K. Robinson, and L. Berman, Phys. Rev. Lett. 75, 449 (1995) and some NMR experiments employing the spin-diffusion tool; see e.g., K.-L. Li, A. A. Jones, P. T. Inglefield, and A. D. English, Macromolecules 22, 4198 (1988); K. Schmidt-Rohr and H. W. Spiess, Multidimensional Solid-State NMR and Polymers (Academic, London, 1994), Ch. 13.
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Potential candidates if suitably developed further appear to be x-ray-photon correlation spectroscopy, see e.g., S. B. Dierker, R. Pindak, R. M. Fleming, I. K. Robinson, and L. Berman, Phys. Rev. Lett. 75, 449 (1995) and some NMR experiments employing the spin-diffusion tool; see e.g., K.-L. Li, A. A. Jones, P. T. Inglefield, and A. D. English, Macromolecules 22, 4198 (1988); K. Schmidt-Rohr and H. W. Spiess, Multidimensional Solid-State NMR and Polymers (Academic, London, 1994), Ch. 13.
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