Molecular weight distribution in interfacial polymerization - Model development and verification

Chemical Engineering Science

Volumn 52, Issue 19, 1997, Pages 3243-3255

  Karode, S K ^a   Kulkarni, S S ^a   Suresh, A K ^b   Mashelkar, R A ^c  

^a NATIONAL CHEMICAL LABORATORY   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

^c NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Interfacial polymerization; Mathematical model; Molecular weight distribution; Spinodal decomposition

Indexed keywords

DECOMPOSITION; MATHEMATICAL MODELS; MOLECULAR WEIGHT DISTRIBUTION; NYLON POLYMERS; OLIGOMERS; PLASTIC FILMS; POLYMERIC MEMBRANES; PRECIPITATION (CHEMICAL); REACTION KINETICS; VISCOSITY;

INTERFACIAL POLYMERIZATION;

POLYMERIZATION;

EID: 0031259962     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(97)00138-3     Document Type: Article

References (23)

1. Blanks, R. F. and Prausnitz, J. M. (1964) Thermodynamics of polymer solubility in polar and nonpolar systems. IEC Fundam. 3(1), 1-8.
2. Bradbury, J. H., Crawford, P. J. and Hambly, A. N. (1968) Kinetics of an interfacial polycondensation reaction part 2 - Reaction of Terephthaloyl Chloride and Piperazine. Trans. Faraday Soc. 65, 1337-1347.
3. Brandrup, J. and Immergut, E. H. (1989) Polymer Handbook. Wiley, New York, U.S.A.
4. Danckwerts, P. V. (1970) Gas-Liquid Reactions. McGraw-Hill, New York, U.S.A.
5. Enkelmann, V. and Wegner, G. (1975) Mechanism of interfacial polycondensation and the direct synthesis of polyamide membranes. Appl Polym. Symp. 26, 365-372.
6. Enkelmann, V. and Wegner, G. (1976) Mechanism of interfacial polycondensation and the direct synthesis of polyamide membranes. Macromol. Chem. 177, 3177-3189.
7. Flory, P. J. (1953) Principles of Polymer Chemistry. Cornell University Press, Ithaca.
8. Johnson, E. D. (1985) A study of the kinetics and mechanism of interfacial polymerization. Ph.D. dissertation, Carnegie-Mellon University, Pittsburgh.
9. Khilar, K. C. (1987) Encapsulation. State of Art Report. Department of Science and Technology, Government of India.
10. Koestler, R. C. (1980) Microencapsulation using interfacial polymerization techniques - agricultural application. In Controlled Release Technology, Vol. 11, ed. A. F. Kydonieus, CRC Press, U.S.A.
11. Kondo, T. (1978) Microencapsulation. In Surface and Colloid Science, Vol. 10, ed. E. Matijevis, Plenum Press, New York, U.S.A.
12. MacRitchie, F. (1969) Mechanism of interfacial polymerization. Trans. Faraday. Soc. 65, 2503-2507.
13. Millich, F. and Carraher, C. E. Jr., eds. (1977) Interfacial Synthesis, Vol. 1, Dekker, New York, U.S.A.
14. Morgan, P. W. (1965) Condensation Polymers: by Interfacial and Solution Methods. Wiley, New York.
15. Morgan, P. W. and Kwolek, S. L. (1959) Interfacial polycondensation. II. Fundamentals of polymer formation at liquid interfaces. J. Polym. Sci. XL, 299-327.
16. Pearson, R. G. and Williams, H. L. (1985) Interfacial polymerization of an isocyanate and a diol. J. Polym. Sci. Part A, 23, 9-18.
17. Petersen, R. J. (1993) Composite reverse osmosis and nanofiltration membranes. J. Membrane Sci. 83, 81-150.
18. Press, W. H., Flannery, B. P., Teukolsky, S. A. and Vetterling, W. T. (1990) Numerical Recipes, The Art of Scientific Computing (FORTRAN version). Cambridge University Press, Cambridge.
19. Sirdesai, M. and Khilar, K. C. (1988) A model for microencapsulation in polyurea shell by interfacial polycondensation. Can. J. Chem. Engng 66, 509-513.
20. Tompa, H. (1956) Polymer Solutions. Butterworths Scientific Publications, London.
21. Wilke, C. R. and Chang, P. (1955) Correlation of diffusion coefficients in dilute solutions. A.I.Ch.E. J. 1, 264.
22. Yadav, S. K., Suresh, A. K. and Khilar, K. C. (1990) Microencapsulation in polyurea shell by interfacial polycondensation. A.I.Ch.E. J. 36(3), 431-438.
23. Yadav, S. K., Khilar, K. C. and Suresh, A. K. (1996) Microencapsulation in polyurea shell - kinetics and film structure. A.I.Ch.E. J. 42(9), 2616-2626.