A processable mullite precursor prepared by reacting silica and aluminum hydroxide with triethanolamine in ethylene glycol: Structural evolution on pyrolysis

Journal of the American Ceramic Society

Volumn 80, Issue 10, 1997, Pages 2597-2606

  Kansal, Pallavi ^c   Laine, Richard M ^b   Babonneau, Florence ^a  

^a CNRS   (France)

^b AMERICAN CERAMIC SOCIETY   (United States)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL MICROSTRUCTURE; DIFFERENTIAL THERMAL ANALYSIS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HIGH TEMPERATURE EFFECTS; HYDRATED ALUMINA; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POROSITY; PYROLYSIS; SILICA; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS; X RAY DIFFRACTION ANALYSIS;

BRUNAUER EMMET TELLER ANALYTICAL METHODS; MULLITE; TRIETHANOLAMINE;

CERAMIC MATERIALS;

EID: 0031259038     PISSN: 00027820     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1151-2916.1997.tb03162.x     Document Type: Article

References (42)

1. M. D. Sacks, H.-W. Lee, and J. A. Pask, "A Review of Powder Preparation Methods and Densification Procedures for Fabricating High-Density Mullite"; pp. 167-207 in Ceramic Transactions, Vol. 6, Mullite and Mullite Matrix Composites. Edited by S. Sõmiya, R. F. Davis, and J. A. Pask. American Ceramic Society, Westerville, OH, 1990 and references therein.
2. V. Ramakrishnan, E. Goo, J. M. Roldan, and E. A. Giess, "Microstructure of Mullite Ceramics Used for Substrate and Packaging Applications," J. Mater. Sci., 27, 6127-30 (1992).
3. P. C. Dokko, J. A. Pask, and K. S. Mazdiyasni, "High-Temperature Mechanical Properties of Mullite Under Compression," J. Am. Ceram. Soc., 60 [3-4] 150-55 (1977).
4. D.-Y. Jeng and M. N. Rahaman, "Sintering and Crystallization of Mullite Powder Prepared by Sol-Gel Processing," J. Mater. Sci. 28, 4904-909 (1993).
5. A. G. Williams and L. V. Interrante, "Design of Metal-Organic Precursors to Aluminosilicates," Mater. Res. Soc. Symp. Proc., 32, 151-56 (1984).
6. S. Prochazka and F. J. Klug, "Infrared Transparent Mullite Ceramics," J. Am. Ceram. Soc., 66 [12] 874-80 (1983).
7. M. Ohashi, H. Tabata, O. Abe, S. Kanzaki, S. Mitachi, and T. Kumazawa, "Preparation of Transluscent Ceramics," J. Mater. Sci. Lett., 6, 528-30 (1987).
8. (a) W.-C. Wei and J. W. Halloran, "Phase Transformations of Diphasic Aluminosilicate Gels," J. Am. Ceram. Soc., 71 [3] 166-72 (1988).
9. (b) W.-C. Wei and J. W. Halloran, "Transformation Kinetics of Diphasic Aluminosilicate Gels," J. Am. Ceram. Soc., 71 [7] 581-87 (1988).
10. I. A. Aksay, D. M. Dobbs, and M. Sarikaya, "Mullite for Structural, Electronic, and Optical Applications," J. Am. Ceram. Soc., 74 [10] 2343-58 (1991) and references therein.
11. W. G. Fahrenholtz and D. M. Smith, "Effect of Precursor Particle Size on the Densification and Crystallization Behavior of Mullite," J. Am. Ceram. Soc., 76 [2] 433-37 (1993) and references therein.
12. R. R. Tummala, "Ceramic and Glass-Ceramic Packaging in the 1990s," J. Am. Ceram. Soc., 74 [5] 895-908 (1991).
13. H. Schneider and E. Eberhard, "Thermal Expansion of Mullite," J. Am. Ceram. Soc., 73 [7] 2073-76 (1990).
14. A. J. Skoog and R. E. Moore, "Refractory of the Past for the Future: Mullite and Its Use as a Bonding Phase," Am. Ceram. Soc. Bull., 67 [7] 1180-85 (1988).
15. K. A. Moore, J. Cesarano III, D. M. Smith, and T. T. Kodas, "Synthesis of Submicrometer Mullite Powder via High-Temperature Aerosol Decomposition," J. Am. Ceram. Soc., 75 [1] 213-15 (1992).
16. K. S. Mazdiyasni and L. M. Brown, "Synthesis and Mechanical Properties of Stoichiometric Aluminum Silicate (Mullite)," J. Am. Ceram. Soc., 55 [11] 548-52 (1972).
17. T.-I. Mah and K. S. Mazdiyasni, "Mechanical Properties of Mullite," J. Am. Ceram. Soc., 66 [10] 699-703 (1983).
18. 3," J. Am. Ceram. Soc., 58 [11-12] 507-12 (1957).
19. S. Sõmiya and Y. Hirata, "Mullite Powder Technology and Applications in Japan," Am. Ceram. Soc. Bull., 70 [10] 1624-32 (1991).
20. (a) R. M. Laine, D. R. Treadwell, B. L. Mueller, C. R. Bickmore, K. F. Waldner, and T. Hinklin, "Processable Aluminosilicate Alkoxide Precursors from Metal Oxides and Hydroxides. The Oxide One Pot Synthesis (OOPS) Process," J. Chem. Mater., 6, 1441-43 (1996).
21. 3," Chem. Mater., 8, 2850-57 (1996).
22. R. Baranwal and R. M. Laine, "A Preceramic Polymer Route to Amorphous and Crystalline Potassium Aluminosilicate Powders and Their Electrorheological Properties," J. Am. Ceram. Soc., 80 [6] 1436-46 (1997).
23. (a) P. Kansal and R. M. Laine, "Mullite Coatings on Carbon Fibers: Precursor Synthesis, Coating Processing, Characterization and Oxidation Resistance," manuscript in preparation.
24. (b) P. Kansal, "Novel Chemical Routes to Ceramics from Precursors"; Ph.D. Dissertation, Univesity of Michigan, Ann Arbor, MI, Jan. 1996.
25. R. M. Laine, "Chemicals, Polymers and Ceramics from the Beach. II"; pp. 69-78 in Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials, NATO ASI Series E: Applied Sciences, Vol. 297. Edited by J. F. Harrod and R. M. Laine. Kluwer, Dordrecht, The Netherlands, 1995.
26. T. Heinrich, W. Tappert, W. Lenhard, and J. Fricke, "Synthesis and Properties of Mullite and Cordierite Aerogels," J. Sol-Gel Sci. Technol., 2, 921-24 (1994).
27. C. Gerardin, S. Sundaresan, J. Benzinger, and A. Navrotsky, "Structural Investigation and Energetics of Mullite Formation from Sol-Gel Precursors," Chem. Mater., 6, 160-70 (1994).
28. (a) D. X. Li and W. J. Thomson, "Tetragonal to Orthohombic Transformation during Mullite Formation," J. Mater. Res., 6 [4] 819-24 (1991).
29. (b) D. X. Li and W. J. Thomson, "Effects of Hydrolysis on the Kinetics of High-Temperature Transformations in Aluminosilicate Gels," J. Am. Ceram. Soc., 74 [3] 574-78 (1991).
30. (c) Y. Wong and W. J. Thomson, "Mullite Formation from Nonstoichiometric Slow Hydrolyzed Single Phase Gels," J. Mater. Res., 10 [4] 912-17 (1995).
31. (a) J. C. Huling and G. Messing, "Chemistry-Crystallization Relations in Molecular Mullite Gels," J. Non-Cryst. Solids, 147, 213-21 (1992).
32. (b) J. C. Huling and G. L. Messing, "Hybrid Gels for Homoepitactic Nucleation of Mullite," J. Am. Ceram. Soc., 72 [9] 1725-29 (1989).
33. 29Si Liquid- and Solid-State NMR Spectroscopic Study," J. Am. Ceram. Soc., 78 [10] 2648-54 (1995).
34. A. K. Chakravorty, "Intermediate Si-Al Spinel Phase Formation in Phase Transformation of Diphasic Mullite Gel," J. Mater. Sci., 28, 3839-44 (1993).
35. G. Engelhardt and D. Michel, High Resolution Solid-State NMR of Silicates and Zeolites; pp. 143-57. Wiley, New York, 1987.
36. 29Si Magic-Angle Spinning Nuclear Magnetic Resonance Spectra," J. Am. Ceram. Soc., 76 [10] 2491-96 (1993).
37. 27Al MAS NMR Investigation," J. Am. Ceram. Soc., 74 [10] 2398-403 (1991).
38. 27Al Magic-Angle Spinning NMR," J. Am. Ceram. Soc., 68 [9] C-243-C-245 (1985).
39. H. J. Percival, J. F. Duncan, and P. K. Foster, "Interpretation of the Kaolinite-Mullite Reaction Sequence from Infrared Absorption Spectra," J. Am. Ceram. Soc., 57, 57-61 (1974).
40. P. Tarte, "Infrared Study of Orthosilicates and Orthogermanates: II," Spectrochim. Acta, Part A, 19 [1] 25-47 (1963).
41. 6 Octahedra," Spectrochim. Acta, Part A, 23 [7] 2127-43 (1967).
42. C. R. Bickmore and R. M. Laine, "Processing Oxynitride Powders via Fluidized Bed Ammonolysis of Large, Porous Silica Particles," J. Am. Ceram. Soc., 79 [11] 2865-77 (1996).