Statistical-thermodynamic framework to model nonionic micellar solutions

Langmuir

Volumn 13, Issue 20, 1997, Pages 5258-5275

  Zoeller, Nancy ^a   Lue, Leo ^a,b   Blankschtein, Daniel ^a  

^a USA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRITICAL MICELLE CONCENTRATION; GIBBS FREE ENERGY; MATHEMATICAL MODELS; MONOMERS; PHASE SEPARATION; SOLUTIONS; STATISTICAL MECHANICS; SURFACE ACTIVE AGENTS;

ATTRACTIVE INTERACTIONS; EXCLUDED VOLUME INTERACTIONS; NONIONIC MICELLAR SOLUTIONS; REPULSIVE INTERACTIONS;

MICELLES;

EID: 0031256972     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la970308c     Document Type: Article

References (69)

1. For an introduction to the field of micellar solutions see: Mittal, K. L., Ed. Micellization, Solubilization, and Microemulsions; Plenum: New York, 1977; Vols. 1 and 2. Gelbart, W. M., Ben-Shaul, A., Roux, D., Eds. Micelles, Membranes, Microemulsions, and Monolayers; Springer: Berlin, 1994.
2. For an introduction to the field of micellar solutions see: Mittal, K. L., Ed. Micellization, Solubilization, and Microemulsions; Plenum: New York, 1977; Vols. 1 and 2. Gelbart, W. M., Ben-Shaul, A., Roux, D., Eds. Micelles, Membranes, Microemulsions, and Monolayers; Springer: Berlin, 1994.
3. Tanford, C. The Hydrophobic Effect, 2nd ed.; John Wiley and Sons: New York, 1980
4. Israelachvili, J. Intermolecular and Surface Forces, 2nd ed.; Academic Press: New York, 1992.
5. Carale, T. R.; Blankschtein, D. J. Phys. Chem. 1992, 96, 459.
6. Blankschtein, D.; Thurston, G. M.; Benedek, G. B. J. Chem. Phys. 1986, 85, 7268 and references cited therein.
7. For a comprehensive account of theoretical developments in the field of micellization see: Mittal, K. L., Lindman, B., Eds. Surfactants in Solution; Plenum: New York, 1984; Vois. 1, 2, and 3.
8. Puvvada, S.; Blankschtein, D. J. Chem. Phys. 1990, 92, 3710 and references cited therein.
9. Puvvada, S.; Blankschtein, D. MRS Symp. Proc. 1990, 177, 129. Puvvada, S.; Blankschtein, D. In Proceedings of the 8th International Symposium on Surfactants in Solution; Mittal, K. L., Shah, D. O., Eds.; Plenum: New York, 1991; Vol. 11, p 95 and references cited therein.
10. Puvvada, S.; Blankschtein, D. MRS Symp. Proc. 1990, 177, 129. Puvvada, S.; Blankschtein, D. In Proceedings of the 8th International Symposium on Surfactants in Solution; Mittal, K. L., Shah, D. O., Eds.; Plenum: New York, 1991; Vol. 11, p 95 and references cited therein.
11. Zoeller, N.; Blankschtein, D. Ind. Eng. Chem. Res. 1995, 34, 4150.
12. Zoeller, N.; Shiloach, A.; Blankschtein, D. CHEMTECH 1996, 26 (3), 24.
13. Nagarajan, R.; Ruckenstein, E. J. Colloid. Interface Sci. 1979, 71, 580.
14. Nagarajan, R.; Ruckenstein, E. Langmuir 1991, 7, 2934 and references cited therein.
15. Israelachvili, J. N.; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc., Faraday Trans. 2 1976, 72, 1525.
16. Eriksson, J. C.; Ljunggren, S. Prog. Colloid Polym. Sci. 1988, 76, 188.
17. Blankschtein, D.; Thurston, G. M.; Benedek, G. B. Phys. Rev. Lett. 1985, 54, 955.
18. Reatto, L.; Tau, M. Chem. Phys. Lett. 1984, 108, 292. Tau, M.; Reatto, L. J. Chem. Phys. 1985, 83, 1921.
19. Reatto, L.; Tau, M. Chem. Phys. Lett. 1984, 108, 292. Tau, M.; Reatto, L. J. Chem. Phys. 1985, 83, 1921.
20. Leng, C. A. J. Chem. Soc., Faraday Trans. 2 1985, 84, 145. Evans, H.; Tildesley, D. J.; Leng, C. A. J. Chem. Soc., Faraday Trans. 2 1987, 83, 1525.
21. Leng, C. A. J. Chem. Soc., Faraday Trans. 2 1985, 84, 145. Evans, H.; Tildesley, D. J.; Leng, C. A. J. Chem. Soc., Faraday Trans. 2 1987, 83, 1525.
22. Odijk, T. J. Phys. 1987, 48, 125.
23. Gelbart, W. M.; McMullen, W. E.; Ben-Shaul, A. J. Phys. 1985, 46, 1137.
24. See, for example: (a) Kjellander, R. J. Chem. Soc., Faraday Trans. 2 1982, 78, 2025. (b) Goldstein, R. E. J. Chem. Phys. 1986, 84, 3367.
25. See, for example: (a) Kjellander, R. J. Chem. Soc., Faraday Trans. 2 1982, 78, 2025. (b) Goldstein, R. E. J. Chem. Phys. 1986, 84, 3367.
26. Nagarajan, R. Colloids Surf., A: Physicochem. Eng. Aspects 1993, 71, 39.
27. Israelachvili, J. N.; Sornette, D. J. Phys. 1985, 46, 2125.
28. Ljunggren, S.; Eriksson, J. C. J. Chem. Soc., Faraday Trans. 2 1984, 80, 489.
29. Bergström, M. J. Colloid Interface Sci. 1996, 181, 208 and references cited therein.
30. Corti, M.; Degiorgio, V. J. Phys. Chem. 1981, 85, 711.
31. Gelbart, W. M.; Ben-Shaul, A.; McMullen, W. E.; Masters, A. J. Phys. Chem. 1984, 88, 861.
32. Dorshow, R.; Briggs, J.; Bunton, C. A.; Nicoli, D. F. J. Phys. Chem. 1982, 86, 2388. Dorshow, R.; Bunton, C. A.; Nicoli, D. F. J. Phys. Chem. 1983, 87, 1409.
33. Dorshow, R.; Briggs, J.; Bunton, C. A.; Nicoli, D. F. J. Phys. Chem. 1982, 86, 2388. Dorshow, R.; Bunton, C. A.; Nicoli, D. F. J. Phys. Chem. 1983, 87, 1409.
34. Appell, J.; Porte, G. J. Colloid Interface Sci. 1981, 81, 85. Porte, G.; Appell, J. J. Phys. Chem. 1981, 85, 2511.
35. Appell, J.; Porte, G. J. Colloid Interface Sci. 1981, 81, 85. Porte, G.; Appell, J. J. Phys. Chem. 1981, 85, 2511.
36. Kato, T.; Anzai, S.; Takano, S.; Seimiya, T. J. Chem. Soc., Faraday Trans. 1 1989, 85, 2499.
37. Sheu, E. Y.; Wu, C.-F.; Chen, S.-H. J. Phys. Chem. 1986, 90, 4179. Lin, T.-L.; Chen, S.-H.; Gabriel, N. E.; Roberts, M. F. J. Phys. Chem. 1990, 94, 855.
38. Sheu, E. Y.; Wu, C.-F.; Chen, S.-H. J. Phys. Chem. 1986, 90, 4179. Lin, T.-L.; Chen, S.-H.; Gabriel, N. E.; Roberts, M. F. J. Phys. Chem. 1990, 94, 855.
39. Zulauf, M.; Weckstrm̈, K.; Hayter, J. B.; Degiorgio, V.; Corti, M. J. Phys. Chem. 1985, 89, 3411.
40. Huang, J. S.; Safran, S. A.; Kim, M. W.; Grest, G. S.; Kotlarchyk, M.; Quirke, N. Phys. Rev. Lett. 1984, 53, 592.
41. Taylor, M. P.; Berger, A. E.; Herzfeld, J. Mol. Cryst. Liq. Cryst. 1988, 157, 489.
42. Safran, S. A.; Pincus, P. A.; Cates, M. E.; MacKintosh, F. C. J. Phys. (Paris) 1990, 51, 503.
43. Lue, L.; Blankschtein, D. Ind. Eng. Chem. Res. 1996, 35, 3032.
44. McMillan, W. G., Jr.; Mayer, J. E. J. Chem. Phys. 1945, 13, 276.
45. Mansoori, G. A.; Carnahan, N. F.; Starling, K. E.; Leland, T. W., Jr. J. Chem. Phys. 1971, 54, 1523.
46. Maitland, G. C.; Rigby, M.; Smith, E. B.; Wakeham, W. A. Intermolecular Forces: Their Origin and Determination; Clarendon Press: Oxford, 1981.
47. Friedman, H. L. J. Solution Chem. 1971, 1, 387.
48. Tester, J. W.; Modell, M. Thermodynamics and Its Applications, 3rd ed.; Prentice-Hall: Upper Saddle River, NJ, 1996.
49. o.
50. Atkins, P. W. Physical Chemistry, 3rd ed.; Freeman: New York, 1986.
51. Ben-Shaul, A.; Gelbart, W. M. J. Phys. Chem. 1982, 86, 316.
52. Onsager, L. Ann. N. Y. Acad. Sci. 1949, 51, 627.
53. Missel, P. J.; Mazer, N. A.; Benedek, G. B.; Young, C. Y.; Carey, M. C. J. Phys. Chem. 1980, 84, 1044.
54. 59 which rescales the virial expansion in terms of a new concentration variable, thus incorporating the effect of higher-order terms. For the relatively dilute surfactant solutions of interest in this paper, the two approaches yield similar results.
55. T,p,Nw = 0.
56. Balmbra, R. R.; Clunie, J. S.; Corkill, J. M.; Goodman, J. F. Trans Faraday Soc. 1962, 58, 1661.
57. Corti, M.; Minero, C.; Degiorgio, V. J. Phys. Chem. 1984, 88, 309. Corti, M.; Degiorgio, V. J. Phys. Chem. 1981, 85, 1442.
58. Corti, M.; Minero, C.; Degiorgio, V. J. Phys. Chem. 1984, 88, 309. Corti, M.; Degiorgio, V. J. Phys. Chem. 1981, 85, 1442.
59. Mukherjee, P.; Mysels, K. J. Critical Micelle Concentration of Aqueous Surfactant Systems; National Standard Reference Data Series (U. S., National Bureau of Standards) No. 36; U. S. Department of Commerce: Washington, DC, 1971.
60. Becher, P. In Nonionic Surfactants; Shick, M. J., Ed.; Arnold: London, 1967; p 478.
61. Brown, W.; Rymden, R. J. Phys. Chem. 1987, 91, 3565.
62. Fujimatsu, H.; Ogasawara, S.; Kuroiwa, S. Colloid Polym. Sci. 1988, 266, 594.
63. Zana, R.; Weill, C. J. Phys., Lett. 1986, 46, L953.
64. Lang, J. C.; Morgan, R. D. J. Chem. Phys. 1980, 73, 5849.
65. Mulley, B. A.; Metcalf, A. D. J. Colloid Sci. 1962, 17, 523.
66. Strey, R.; Pakusch, A. In Surfactants in Solutions; Mittal, K. L., Bothorel, P., Eds.; Plenum: New York, 1986; p 465.
67. See, for example: Boublik, T. Mol. Phys. 1974, 27, 1415. Boublik, T.; Vega, C.; Diaz-Pena, M. J. Chem. Phys. 1990, 93, 730.
68. See, for example: Boublik, T. Mol. Phys. 1974, 27, 1415. Boublik, T.; Vega, C.; Diaz-Pena, M. J. Chem. Phys. 1990, 93, 730.
69. Barboy, B.; Gelbart, W. M. J. Chem. Phys. 1979, 71, 3053.