Degradation of Pulp-Mill Effluent by Oxygen and Na5[PV2Mo10O40], a Multipurpose Delignification and Wet Air Oxidation Catalyst

Industrial and Engineering Chemistry Research

Volumn 36, Issue 10, 1997, Pages 4134-4142

  Sonnen, Daniel M ^a   Reiner, Richard S ^a   Atalla, Rajai H ^a   Weinstock, Ira A ^a  

^a FOREST PRODUCTS LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; LIGNIN; MOLYBDENUM COMPOUNDS; OXIDATION; OXYGEN; PAPER AND PULP MILLS; SALTS; SOLUTIONS; VANADIUM COMPOUNDS;

DELIGNIFICATION; PULP MILL EFFLUENTS; WET OXIDATION;

BLEACHING;

EID: 0031256965     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970150r     Document Type: Article

References (37)

1. American Public Health Association. In Standard Methods for the Examination of Water and Wastewater, 16th ed.; Franson, M. H., Ed.; APHA: Washington, DC, 1985; pp 532-537.
2. Atalla, R. H.; Weinstock, I. A.; Hill, C. L.; Reiner, R. S. Oxidation of Lignin and Polysaccharides Mediated by Polyoxometalate Treatment of Wood Pulp. U.S. Patent 5,549,789, 1996.
3. Baes, C. F., Jr.; Mesmer, R. E. The Hydrolysis of Cations; Wiley: New York, 1976.
4. 40] and Dioxygen. J, Chem. Soc., Chem. Commun. 1989, 825-826.
5. Bioscience Inc. (Bethlehem, PA). Technical Bulletin: Chemical Oxygen Demand Method for accu-TEST Mercury-Free Twist-Cap Vials: Spectrophotometric Method, 1993.
6. Dobbs, R. A.; Williams, R. T. Elimination of Chloride Interference in the Chemical Oxygen Demand Test. Anal. Chem. 1963, 35, 1064-1067.
7. 17O NMR. J. Am. Chem. Soc. 1997, 119, 243-244.
8. EPA Approval of Alternate Water Pollutant Testing Procedure; Chemical Oxygen Demand (COD). Fed. Reg. 1978, 43, 45, Tuesday, March 7.
9. Fengel, D.; Wegener, G. Wood: Chemistry, Ultrastructure, Reactions; Walter de Gruyter: New York, 1984.
10. Foussard, J.-N.; Debellefontaine, H.; Besombes-Vailhe, J. Efficient Elimination of Organic Liquid Wastes: Wet Air Oxidation. J. Environ. Eng. 1989, 115, 367-385.
11. Gellerstedt, G.; Gustafsson, K.; Lindfors, E. L. Structural Changes in Lignin During Oxygen Bleaching. Nord. Pulp Pap. Res. J. 1986, 14-17.
12. Gierer, J. The Chemistry of Delignification. Holzforschung 1982, 36, 55-64.
13. Grate, J. H.; Hamm, D. R.; Mahajan, S. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; p 281.
14. Hamilton, G. A. Chemical Models of Mechanisms for Oxygenases. In Molecular Mechanisms of Oxygen Activation; Hayaishi, O., Ed.; Academic Press: New York, 1974; pp 419-424.
15. Hill, C. L.; Prosser-McCartha, C. M. Homogeneous Catalysis by Transition Metal Oxygen Anion Clusters. Coord. Chem. Rev. 1995, 143, 407-455.
16. Hintz, H. L. Pulp and Paper Mill of the Future - An Information Exchange; U.S. Department of Energy, Office of Industrial Technologies: Orono, ME, 1993.
17. Kozhevnikov, I. V.; Burov, Y. V.; Matveev, K. I. Mechanism of the Oxidation of 12-Molybdovanadophosphate Blues by Oxygen in Aqueous Solution. Izv. Akad. Nauk SSSR 1981, 2428-2435.
18. Leparulo-Loftus, M. A.; Pope, M. T. Vanadium-51 NMR Spectroscopy of Tungstovanadate Polyanions. Chemical Shift and Line-Width Patterns for the Identification of Stereoisomers. Inorg. Chem. 1987, 26, 2112-2120.
19. Levee, J.; Pintar, A. Catalytic Oxidation of Aqueous Solutions of Organics. An Effective Method for Removal of Toxic Pollutants from Waste Water. Catal. Today 1995, 24, 51-58.
20. Li, L.; Chen, P.; Gloyna, E. F. Generalized Kinetic Model for Wet Oxidation of Organic Compounds. AIChE J. 1991, 37, 1687-1697.
21. Lin, S. H.; Ho, S. J.; Wu, C. L. Kinetic and Performance Characteristics of Wet Air Oxidation of High-Concentration Wastewater. Ind. Eng. Chem. Res. 1996, 35, 307-314.
22. Mishra, V. S.; Mahajani, V. V.; Joshi, J. B. Wet Air Oxidation. Ind. Eng. Chem. Res. 1995, 34, 2-48.
23. Mohlman, F. W.; Edwards, G. P. Determination of Carbon in Sewage and Industrial Wastes. Ind. Eng. Chem. 1931, 3, 119-123.
24. Moore, A. W.; Kroner, R. C.; Ruchhoft, C. C. Dichromate Reflux Method for Determination of Oxygen Consumed. Anal. Chem. 1949, 21, 953-957.
25. 5-: A Kinetic and Mechanistic Study. J. Am. Chem. Soc. 1992, 114, 7278-7286.
26. Okuhara, T.; Mizuno, N.; Misono, M. Catalytic chemistry of heteropoly compounds. Adv. Catal. 1996, 41, 113-252.
27. Pope, M. T.; Müller, A. Polyoxometalate chemistry: An old field with new dimensions in several disciplines. Angew. Chem., Int. Ed. Engl. 1991, 30, 34-48.
28. Shende, R. V.; Mahajani, V. V. Kinetics of Wet Air Oxidation of Glyoxalic Acid and Oxalic Acid. Ind. Eng. Chem. Res. 1994, 33, 3125-3130.
29. Singh, R. P., Ed. The Bleaching of Kraft Pulp, 3rd ed.; TAPPI Press: Atlanta, GA, 1979.
30. Sjostrom, E. Wood Chemistry: Fundamentals and Applications, 2nd ed.; Academic Press, Inc.: San Diego, 1992.
31. TAPPI Useful Test Methods 1991, um-246; TAPPI Press: Atlanta, GA, 1991a; p 43.
32. TAPPI Test Methods 1991, T230 om-89; TAPPI Press: Atlanta, GA, 1991b.
33. Teletzke, G. H.; Gitchel, W. B.; Diddams, D. G.; Hoffman, C. A. Components of Sludge and its Wet Air Oxidation Products. Chem. Eng. Prog. 1964, 60, 33-38.
34. Weinstock, I. A.; Hill, C. L. Oxidative Delignification of Wood or Wood Pulp by Transition-Metal Substituted Polyoxometalates. U.S. Patent 5,552,019, 1996.
35. Weinstock, I. A.; Atalla, R. H.; Reiner, R. S.; Moen, M. E.; Hammel, K. E.; Houtman, C. J.; Hill, C. H. A New Environmentally Benign Technology and Approach to Bleaching Kraft Pulp. Polyoxometalates for Selective Delignification and Waste Mineralization. New J. Chem. 1996, 20, 269-275.
36. Weinstock, I. A.; Atalla, R. H.; Reiner, R. S.; Moen, M. E.; Hammel, K. E.; Houtman, C. J.; Hill, C. H.; Harrup, M. K. A New Environmentally Benign Technology for Transforming Wood Pulp into Paper. Engineering Polyoxometalates as Catalysts for Multiple Processes. J. Mol. Catal. 1997, 116, 59-84.
37. Willms, R. S.; Reible, D. D.; Wetzel, D. M.; Harrison, D. P. Aqueous-Phase Oxidation: Rate Enhancement Studies. Ind. Eng. Chem. Res. 1987, 26, 606-612.