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Volumn 107, Issue 13, 1997, Pages 4893-4905

Extracting signatures of quantum chaos from the time resolved fluorescence of isolated molecules

Author keywords

[No Author keywords available]

Indexed keywords

COHERENT LIGHT; FLUORESCENCE; LASER PULSES; MATHEMATICAL MODELS; MATRIX ALGEBRA; MOLECULAR VIBRATIONS; PROBABILITY; QUANTUM THEORY; RANDOM PROCESSES;

EID: 0031256451     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.474852     Document Type: Article
Times cited : (3)

References (37)
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    • Indeed, one can show that given a system with energy level repulsion, a chaotic classical spectrum emerges in the correspondence limit if one utilizes the semiclassical theory for hyperbolic systems. See, J. Wilkie and P. Brumer, Phys. Rev. A 55, 27, 43 (1997).
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    • note
    • Insufficient averaging makes us concerned about the correlation holes observed in Ref. 11. Only three of fifteen sets of spectra; with ∼5 spectra in each set, displayed evidence of correlation holes. Our experience (Ref. 14) suggests that such features might well arise from insufficient averaging.
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    • These billiard systems consist of a particle confined to either a circle or stadium shaped region by infinite walls. They are effective examples of regular and chaotic behavior. See, e.g., R. D. Taylor and P. Brumer, Discuss. Faraday Soc. 75, 117 (1983).
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    • ψ(a,b;z) is difficult to compute for the z values in Eq. (58). We found it easier to numerically perform the integral in Eq. (50)
    • ψ(a,b;z) is difficult to compute for the z values in Eq. (58). We found it easier to numerically perform the integral in Eq. (50).
  • 31
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    • N(t) corresponds to using a square envelope for the electric field of the laser
    • N(t) corresponds to using a square envelope for the electric field of the laser.
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    • note
    • 2(t) must be evaluated for the new distribution. The rest of the equations in this paper can easily be modified to include the new damping factors, and the analysis of the fluorescence signal can then be carried out as described.
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    • In the event that a poor fit is obtained, other distributions of the radiative linewidths must be considered (Refs. 25,26)
    • In the event that a poor fit is obtained, other distributions of the radiative linewidths must be considered (Refs. 25,26).
  • 37
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    • Software and references available from William Goffe at (http:// emlab.berkeley.edu/Software/abstracts/goffe895.html).
    • Goffe, W.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.